Natural convection effects in electrochemical systems

[1]  M. Free,et al.  A Comparative Study of Electrolyte Flow and Slime Particle Transport in a Newly Designed Copper Electrolytic Cell and a Laboratory-Scale Conventional Electrolytic Cell , 2017 .

[2]  Seongpil Hwang,et al.  Influence of an active vibration isolator and electrochemical cell design on electrochemical measurements to minimize natural convection , 2017 .

[3]  R. Compton,et al.  Thermal convection in electrochemical cells. Boundaries with heterogeneous thermal conductivity and implications for scanning electrochemical microscopy. , 2017, Physical chemistry chemical physics : PCCP.

[4]  M. Free,et al.  Design and analysis of direct side inflows in copper electrolytic cells by a computational method , 2017 .

[5]  R. Compton,et al.  Convective heat transfer in a measurement cell for scanning electrochemical microscopy. , 2016, Physical chemistry chemical physics : PCCP.

[6]  Ling Chao,et al.  The flow patterning capability of localized natural convection. , 2016, Physical chemistry chemical physics : PCCP.

[7]  Zhiling Zhao,et al.  First principles of hot-tip scanning electrochemical microscopy: Differentiating substrates according to their thermal conductivities , 2016 .

[8]  R. Compton,et al.  Influence of Reaction-Induced Thermal Convection on the Electrical Currents Measured in Chronoamperometry and Cyclic Voltammetry , 2016 .

[9]  P. Apel,et al.  Chronopotentiometric Response of an Electrically Heterogeneous Permselective Surface: 3D Modeling of Transition Time and Experiment , 2016 .

[10]  N. M. Contento,et al.  Thermal characteristics of temperature-controlled electrochemical microdevices , 2016 .

[11]  H. Vogt.  Single‐phase free convective mass transfer in electrochemical reactors , 2016 .

[12]  K. Eckert,et al.  On the Electrolyte Convection around a Hydrogen Bubble Evolving at a Microelectrode under the Influence of a Magnetic Field , 2016 .

[13]  M. Free,et al.  Experimental and simulation studies of electrolyte flow and slime particle transport in a pilot scale copper electrorefining cell , 2016 .

[14]  Foysal Z. Khan,et al.  Visualization and Measurement of Natural Convection from Electrochemically-Generated Density Gradients at Concentric Microdisk and Ring Electrodes in a Microfluidic System , 2016 .

[15]  S. Feldberg,et al.  Concentration and Density Changes at an Electrode Surface and the Principle of Unchanging Total Concentration , 2016 .

[16]  X. Gong,et al.  Progress toward Electrochemistry Intensified by using Supergravity Fields , 2015 .

[17]  M. Vlasenko,et al.  Heat transfer and thermohydrodynamic fluctuations in aluminum–air fuel cell , 2015 .

[18]  T. Weier,et al.  Near-wall measurements of the bubble- and Lorentz-force-driven convection at gas-evolving electrodes , 2015 .

[19]  D. Funfschilling,et al.  Electrogenerated bubbles induced convection in narrow vertical cells: A review , 2015 .

[20]  R. Compton,et al.  Advancing from Rules of Thumb: Quantifying the Effects of Small Density Changes in Mass Transport to Electrodes. Understanding Natural Convection. , 2015, Analytical chemistry.

[21]  J. Deseure,et al.  Modeling of electrochemically generated bubbly flow under buoyancy-driven and forced convection , 2015 .

[22]  Zhi Wang,et al.  Deposit structure and kinetic behavior of metal electrodeposition under enhanced gravity-induced convection , 2015 .

[23]  M. Skrzypkiewicz,et al.  Chronoamperometric investigations of electro-oxidation of lignite in direct carbon bed solid oxide fuel cell , 2015 .

[24]  A. Mohebbi,et al.  CFD simulation of an industrial copper electrowinning cell , 2015 .

[25]  Hosuk Kang,et al.  Electrochemical Characterization of the Hydrophobic Interaction and the Natural Convection within Agarose Gel , 2015 .

[26]  H. Terryn,et al.  Simulated and measured response of oxygen SECM-measurements in presence of a corrosion process , 2014 .

[27]  V. Mujica,et al.  The amplifying effect of natural convection on power generation of thermogalvanic cells , 2014 .

[28]  B. Chung,et al.  Influence of a center anode in analogy experiments of long flow ducts , 2014 .

[29]  B. Chung,et al.  Time-dependent Rayleigh–Benard convection: Cell formation and Nusselt number , 2014 .

[30]  H. Matsushima,et al.  Nucleation and growth of electrolytic gas bubbles under microgravity , 2014 .

[31]  P. Mandin,et al.  Bubble Over-Potential During Two-Phase Alkaline Water Electrolysis , 2014 .

[32]  V. Topa,et al.  Multi-ion transport and reaction model used to improve the understanding of local current density measurements in presence of concentration gradients around a point current source , 2014 .

[33]  J. Coey,et al.  Magnetic fields in electrochemistry: The Kelvin force. A mini-review , 2014 .

[34]  A. C. Hegde,et al.  Effect of Induced Magnetic Field on Electrocrystallization of Zn-Ni Alloy and Their Corrosion Study , 2014, Journal of Materials Engineering and Performance.

[35]  K. Eckert,et al.  Magnetic fields in electrochemistry : the Lorentz force . A mini-review , 2014 .

[36]  Satish Kumar,et al.  Design and optimization of thermo-electrochemical cells , 2014, Journal of Applied Electrochemistry.

[37]  C. Amatore,et al.  Mass transport at infinite regular arrays of microband electrodes submitted to natural convection: theory and experiments. , 2013, Analytical chemistry.

[38]  V. Topa,et al.  A practical way to model convection in non-agitated electrolytes , 2013 .

[39]  Kristopher R. Ward,et al.  Understanding Voltammetry: Simulation of Electrode Processes , 2013 .

[40]  M. Jönsson‐Niedziółka,et al.  Enzymatic oxygen reduction under quiescent conditions — the importance of convection , 2013 .

[41]  R. Wüthrich,et al.  Experimental investigation of two-phase electrolysis processes: comparison with or without gravity , 2013, Journal of Applied Electrochemistry.

[42]  C. Amatore,et al.  A new approach for the simulation of electrochemiluminescence (ECL). , 2013, Chemphyschem : a European journal of chemical physics and physical chemistry.

[43]  K. Aoki,et al.  Slow scan voltammetry for diffusion-controlled currents in sodium alginate solutions , 2013 .

[44]  P. Nikrityuk,et al.  The initial transient of natural convection during copper electrolysis in the presence of an opposing Lorentz force: Current dependence , 2013 .

[45]  Wolfgang A. Wall,et al.  A computational approach for the simulation of natural convection in electrochemical cells , 2013, J. Comput. Phys..

[46]  B. Chung,et al.  Influences of vertical and horizontal pitches on the natural convection of two staggered cylinders , 2013 .

[47]  C. Amatore,et al.  New theoretical insights into the competitive roles of electron transfers involving adsorbed and homogeneous phases , 2013 .

[48]  K. Aoki,et al.  Diffusion coefficients in viscous sodium alginate solutions , 2012 .

[49]  Zhanyu Sun,et al.  Numerical modeling of a four-electrode electrochemical accelerometer based on natural convection: The boussinesq flow model vs. The compressible flow model , 2012, Russian Journal of Electrochemistry.

[50]  A. Bund,et al.  Numerical simulation of the onset of mass transfer and convection in copper electrolysis subjected to a magnetic field , 2012, Russian Journal of Electrochemistry.

[51]  V. Nikonenko,et al.  Model and experimental studies of gravitational convection in an electromembrane cell , 2012, Russian Journal of Electrochemistry.

[52]  W. Wall,et al.  A stabilized finite element method for the numerical simulation of multi-ion transport in electrochemical systems , 2012 .

[53]  Christian Amatore,et al.  Mass transport at microband electrodes: transient, quasi-steady-state, and convective regimes. , 2012, Chemphyschem : a European journal of chemical physics and physical chemistry.

[54]  C. Amatore,et al.  Importance of correct prediction of initial concentrations in voltammetric scans: contrasting roles of thermodynamics, kinetics, and natural convection. , 2012, Analytical chemistry.

[55]  S. Rodríguez-Romo,et al.  LBM for cyclic voltammetry of electrochemically mediated enzyme reactions and Rayleigh-Bénard convection in electrochemical reactors , 2012 .

[56]  R. Compton,et al.  The electroneutrality approximation in electrochemistry , 2011 .

[57]  C. Amatore,et al.  Difference between ultramicroelectrodes and microelectrodes: influence of natural convection. , 2010, Analytical chemistry.

[58]  C. Amatore,et al.  Cyclic voltammetry at microelectrodes. Influence of natural convection on diffusion layers as characterized by in situ mapping of concentration profiles , 2009 .

[59]  K. Knobloch,et al.  Alteration of diffusional transport by migration and natural convection. Theoretical and direct experimental evidences upon monitoring steady-state concentration profiles at planar electrodes , 2007 .

[60]  K. Knobloch,et al.  First direct experimental evidence of migration contributions through monitoring of concentration profiles at low supporting electrolyte concentration , 2004 .

[61]  J. Heinze,et al.  Imaging concentration profiles of redox-active species with nanometric amperometric probes: effect of natural convection on transport at microdisk electrodes. , 2004, Angewandte Chemie.

[62]  G. Eigenberger,et al.  Simulation of Buoyancy Driven Bubbly Flow: Established Simplifications and Open Questions (Journal Review) , 2004 .

[63]  Chao Sun,et al.  Particle image velocimetry measurement of the velocity field in turbulent thermal convection. , 2003, Physical review. E, Statistical, nonlinear, and soft matter physics.

[64]  S. Szunerits,et al.  Monitoring Concentration Profiles In Situ with an Ultramicroelectrode Probe , 2001 .

[65]  S. Szunerits,et al.  The real meaning of Nernst's steady diffusion layer concept under non-forced hydrodynamic conditions. A simple model based on Levich's seminal view of convection , 2001 .

[66]  Jeonghee Lee,et al.  Natural convection at microelectrodes , 1995 .

[67]  Allen J. Bard,et al.  Electrochemical Methods: Fundamentals and Applications , 1980 .

[68]  J. Selman,et al.  Free‐Convection Mass Transfer with a Supporting Electrolyte , 1971 .

[69]  J. Szablya.  On the Lorentz force , 1965 .

[70]  Geoffrey Ingram Taylor,et al.  A Mechanical Method for Solving Problems of Flow in Compressible Fluids , 1928 .