Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions

We have developed a simple, one-step hydrothermal method for the synthesis of highly fluorescent carbon nanoparticles (F-CNPs) with a high quantum yield (68%) and good photostability. The method requires less reaction time and a lower reaction temperature as compared with the previous reported methods. The as-prepared F-CNPs exhibit excellent emission property and high stability, as well as excitation-independent emission behavior. Moreover, it is attractive that F-CNPs can be used as an effective fluorescent probe for the detection of mercury ions with good selectivity and sensitivity in an aqueous solution. (C) 2012 Elsevier Ltd. All rights reserved.

[1]  Yi Lu,et al.  Highly sensitive and selective colorimetric sensors for uranyl (UO2(2+)): development and comparison of labeled and label-free DNAzyme-gold nanoparticle systems. , 2008, Journal of the American Chemical Society.

[2]  Sheila N. Baker,et al.  Luminescent carbon nanodots: emergent nanolights. , 2010, Angewandte Chemie.

[3]  Xiaoyun Qin,et al.  Hydrothermal Treatment of Grass: A Low‐Cost, Green Route to Nitrogen‐Doped, Carbon‐Rich, Photoluminescent Polymer Nanodots as an Effective Fluorescent Sensing Platform for Label‐Free Detection of Cu(II) Ions , 2012, Advanced materials.

[4]  Hui Peng,et al.  Simple Aqueous Solution Route to Luminescent Carbogenic Dots from Carbohydrates , 2009 .

[5]  A. Fletcher,et al.  Fluorescence quantum yields of some rhodamine dyes , 1982 .

[6]  E. Giannelis,et al.  Surface functionalized carbogenic quantum dots. , 2008, Small.

[7]  Robert M Dickson,et al.  Developing luminescent silver nanodots for biological applications. , 2012, Chemical Society reviews.

[8]  Xingyu Jiang,et al.  Colorimetric detection of mercury, lead and copper ions simultaneously using protein-functionalized gold nanoparticles. , 2011, Biosensors & bioelectronics.

[9]  S. Bhatia,et al.  Probing the Cytotoxicity Of Semiconductor Quantum Dots. , 2004, Nano letters.

[10]  C. Fan,et al.  The cytotoxicity of cadmium based, aqueous phase - synthesized, quantum dots and its modulation by surface coating. , 2009, Biomaterials.

[11]  Huixiang Li,et al.  Label-free colorimetric detection of specific sequences in genomic DNA amplified by the polymerase chain reaction. , 2004, Journal of the American Chemical Society.

[12]  Chunzhong Li,et al.  Synthesis of photoluminescent carbogenic dots using mesoporous silica spheres as nanoreactors. , 2011, Chemical communications.

[13]  G. Nienhaus,et al.  Ultra-small fluorescent metal nanoclusters: Synthesis and biological applications , 2011 .

[14]  X. Shao,et al.  Development of a carbon quantum dots-based fluorescent Cu2+ probe suitable for living cell imaging. , 2012, Chemical communications.

[15]  D. Sheehan,et al.  Oxidative stress and toxicity of gold nanoparticles in Mytilus edulis. , 2010, Aquatic toxicology.

[16]  H. Ming,et al.  Fluorescent carbon nanoparticles: electrochemical synthesis and their pH sensitive photoluminescence properties , 2011 .

[17]  Xingyu Jiang,et al.  Stable fluorescent gold nanoparticles for detection of Cu2+ with good sensitivity and selectivity. , 2012, The Analyst.

[18]  Hui Huang,et al.  One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties , 2011 .

[19]  N. Jana,et al.  Fluorescent Carbon Nanoparticles: Synthesis, Characterization, and Bioimaging Application , 2009 .

[20]  Minghong Wu,et al.  Observation of pH-, solvent-, spin-, and excitation-dependent blue photoluminescence from carbon nanoparticles. , 2010, Chemical communications.

[21]  Guonan Chen,et al.  Polyamine-functionalized carbon quantum dots for chemical sensing , 2012 .

[22]  S. Gambhir,et al.  Quantum Dots for Live Cells, in Vivo Imaging, and Diagnostics , 2005, Science.

[23]  John Aurie Dean,et al.  Lange's Handbook of Chemistry , 1978 .

[24]  Zheng Xie,et al.  Highly Luminescent Organosilane‐Functionalized Carbon Dots , 2011 .

[25]  Lei Wang,et al.  Chemically tailoring graphene oxides into fluorescent nanosheets for Fe3+ ion detection , 2012 .

[26]  X. Qu,et al.  Carbon nanodots as fluorescence probes for rapid, sensitive, and label-free detection of Hg2+ and biothiols in complex matrices. , 2012, Chemical communications.

[27]  Chunhai Fan,et al.  Target-responsive structural switching for nucleic acid-based sensors. , 2010, Accounts of chemical research.

[28]  S. Klaine,et al.  Toxicity and fate of silver in the environment , 1998 .

[29]  Amit Jaiswal,et al.  One step synthesis of C-dots by microwave mediated caramelization of poly(ethylene glycol). , 2012, Chemical communications.

[30]  Ron C. Hardman A Toxicologic Review of Quantum Dots: Toxicity Depends on Physicochemical and Environmental Factors , 2005, Environmental health perspectives.

[31]  Huzhi Zheng,et al.  Enhancing the luminescence of carbon dots with a reduction pathway. , 2011, Chemical communications.

[32]  J. C. D. Silva,et al.  Analytical and bioanalytical applications of carbon dots , 2011 .

[33]  G. De,et al.  Magic sized ZnS quantum dots as a highly sensitive and selective fluorescence sensor probe for Ag+ ions. , 2012, The Analyst.

[34]  S. Pang,et al.  Synthesis of direct white-light emitting carbogenic quantum dots. , 2010, Chemical communications.

[35]  Chunhai Fan,et al.  Design of a gold nanoprobe for rapid and portable mercury detection with the naked eye. , 2008, Chemical communications.

[36]  Fan Yang,et al.  Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties. , 2009, Chemical communications.

[37]  Huzhi Zheng,et al.  Microwave–hydrothermal synthesis of fluorescent carbon dots from graphite oxide , 2011 .

[38]  S. M. Babu,et al.  Growth and optical characterization of colloidal CdTe nanoparticles capped by a bifunctional molecule , 2010 .