Layer‐by‐Layer Growth of CH3NH3PbI3−xClx for Highly Efficient Planar Heterojunction Perovskite Solar Cells

A layer-by-layer approach is developed to prepare uniform and compact CH₃NH₃PbI(3-x)Clx perovskite films for perovskite solar cells with a high efficiency up to 15.12% and an improved stability. Moreover, a record high efficiency of 12.25% is achieved for these flexible perovskite solar cells. This study represents an important step forward in developing high-performance and stable perovskite solar cells.

[1]  Bert Conings,et al.  Perovskite‐Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach , 2014, Advanced materials.

[2]  J. Noh,et al.  Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells. , 2013, Nano letters.

[3]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[4]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[5]  Sang Il Seok,et al.  Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells. , 2014, Nature materials.

[6]  J. Noh,et al.  Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors , 2013, Nature Photonics.

[7]  Fan Zuo,et al.  Additive Enhanced Crystallization of Solution‐Processed Perovskite for Highly Efficient Planar‐Heterojunction Solar Cells , 2014, Advanced materials.

[8]  Sandeep Kumar Pathak,et al.  Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells , 2013, Nature Communications.

[9]  Yang Yang,et al.  Interface engineering of highly efficient perovskite solar cells , 2014, Science.

[10]  Eric T. Hoke,et al.  Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells , 2014 .

[11]  Jeffrey A. Christians,et al.  An inorganic hole conductor for organo-lead halide perovskite solar cells. Improved hole conductivity with copper iodide. , 2014, Journal of the American Chemical Society.

[12]  Alain Goriely,et al.  Neutral color semitransparent microstructured perovskite solar cells. , 2014, ACS nano.

[13]  Robert P. H. Chang,et al.  Lead-free solid-state organic–inorganic halide perovskite solar cells , 2014, Nature Photonics.

[14]  Guglielmo Lanzani,et al.  Excitons versus free charges in organo-lead tri-halide perovskites , 2014, Nature Communications.

[15]  Alain Goriely,et al.  Morphological Control for High Performance, Solution‐Processed Planar Heterojunction Perovskite Solar Cells , 2014 .

[16]  Henry J. Snaith,et al.  Solution Deposition‐Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells , 2014 .

[17]  Qingfeng Dong,et al.  Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers , 2014 .

[18]  Henk J. Bolink,et al.  Perovskite solar cells employing organic charge-transport layers , 2013, Nature Photonics.

[19]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[20]  Henry J Snaith,et al.  Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates , 2013, Nature Communications.

[21]  J. Teuscher,et al.  Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells , 2014, Nature Photonics.

[22]  M. Johnston,et al.  Charge-carrier dynamics in vapour-deposited films of the organolead halide perovskite CH3NH3PbI3-xClx , 2014 .

[23]  Kai Zhu,et al.  Efficient planar perovskite solar cells based on 1.8 eV band gap CH3NH3PbI2Br nanosheets via thermal decomposition. , 2014, Journal of the American Chemical Society.

[24]  Juan Bisquert,et al.  Low-temperature processed electron collection layers of graphene/TiO2 nanocomposites in thin film perovskite solar cells. , 2013, Nano letters.

[25]  Jinsong Huang,et al.  Solvent Annealing of Perovskite‐Induced Crystal Growth for Photovoltaic‐Device Efficiency Enhancement , 2014, Advanced materials.

[26]  Nakita K. Noel,et al.  Anomalous Hysteresis in Perovskite Solar Cells. , 2014, The journal of physical chemistry letters.

[27]  Qi Chen,et al.  Low-temperature solution-processed perovskite solar cells with high efficiency and flexibility. , 2014, ACS nano.

[28]  Laura M Herz,et al.  High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites , 2013, Advanced materials.

[29]  Kangning Liang,et al.  Synthesis and Characterization of Organic−Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique , 1998 .

[30]  B. Lotsch New light on an old story: perovskites go solar. , 2014, Angewandte Chemie.

[31]  Bin Hu,et al.  In-situ investigation of interfacial effects on charge accumulation and extraction in organic solar cells based on transient photocurrent studies , 2014 .

[32]  M. Grätzel,et al.  A hole-conductor–free, fully printable mesoscopic perovskite solar cell with high stability , 2014, Science.

[33]  Peng Gao,et al.  Impedance spectroscopic analysis of lead iodide perovskite-sensitized solid-state solar cells. , 2014, ACS nano.

[34]  David Cahen,et al.  High Open-Circuit Voltage Solar Cells Based on Organic-Inorganic Lead Bromide Perovskite. , 2013, The journal of physical chemistry letters.

[35]  Timothy L. Kelly,et al.  Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques , 2013, Nature Photonics.

[36]  M. Grätzel,et al.  Sequential deposition as a route to high-performance perovskite-sensitized solar cells , 2013, Nature.

[37]  Henry J. Snaith,et al.  Efficient planar heterojunction perovskite solar cells by vapour deposition , 2013, Nature.

[38]  M. Johnston,et al.  Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells , 2014 .