Coherent excitation transport in metal-nanoparticle chains

Electromagnetic energy transport in chains of noncontacting metal nanoparticles is studied within an exactly solvable model. The transport is mediated by the retarded electromagnetic interactions between plasmons confined to the individual nanoparticles and therefore self-consistently accounts for spontaneous emission on the same footing as the transport; the propagating hybrid plasmonic-electromagnetic modes of the chain are known as plasmon polaritons. Dark modes are found in the first Brillouin zone when the excitation wavelength is greater than the resonant optical wavelength, suggesting the possibility of the suppression of radiative losses. Nearest-neighbor tight-binding models are shown to be of limited validity.