Extended time scales of carbonaceous chondrite aqueous alteration evidenced by a xenolith in LaPaz Icefield 02239 (CM2)

LaPaz Icefield (LAP) 02239 is a mildly aqueously altered CM2 carbonaceous chondrite that hosts a xenolith from a primitive chondritic parent body. The xenolith contains chondrules and calcium‐ and aluminum‐rich inclusions (CAIs) in a very fine‐grained matrix. The chondrules are comparable in mineralogy and oxygen isotopic composition with those in the CMs, and its CAIs are also mineralogically similar to the CM population apart for being unusually small and abundant. The presence of serpentine demonstrates that the xenolith has been aqueously altered, and its phyllosilicate‐rich matrix has a comparable oxygen isotopic composition to the matrices of CM meteorites. The xenolith's chondrules lack fine‐grained rims, whereas the xenolith itself has a fine‐grained rim that is petrographically and chemically comparable with the rims on coarse grained objects in LAP 02239 and other CM meteorites. These properties show that the xenolith's parent body was formed from similar materials to the CM parent body(ies). Following its lithification by aqueous alteration, a piece of the xenolith's parent body was impact‐ejected, acquired a fine‐grained rim while free‐floating in the protoplanetary disc, then was accreted along with rimmed chondrules and other materials to make the LAP 02239 parent body. Subsequent aqueous processing of the LAP 02239 parent body altered the fine‐grained rims on the xenolith, chondrules, and CAIs. The xenolith shows that the timespan of geological evolution of carbonaceous chondrite parent bodies was sufficiently long for some of them to have been aqueously altered before others had formed.

[1]  A. Davis,et al.  A record of post-accretion asteroid surface mixing preserved in the Aguas Zarcas meteorite , 2022, Nature Astronomy.

[2]  S. Russell,et al.  Abundance and importance of petrological type 1 chondritic material , 2021, Meteoritics & Planetary Science.

[3]  M. Elvis Asteroids , 2021 .

[4]  M. Zolensky,et al.  The polymict carbonaceous breccia Aguas Zarcas: A potential analog to samples being returned by the OSIRIS‐REx and Hayabusa2 missions , 2021, Meteoritics & Planetary Science.

[5]  L. Daly,et al.  CM carbonaceous chondrite falls and their terrestrial alteration , 2021, Meteoritics & Planetary Science.

[6]  M. Trieloff,et al.  The old, unique C1 chondrite Flensburg – Insight into the first processes of aqueous alteration, brecciation, and the diversity of water-bearing parent bodies and lithologies , 2021, Geochimica et Cosmochimica Acta.

[7]  M. Whitehouse,et al.  A short-lived 26Al induced hydrothermal alteration event in the outer solar system: Constraints from Mn/Cr ages of carbonates , 2020 .

[8]  A. Bischoff,et al.  Classification of CM chondrite breccias—Implications for the evaluation of samples from the OSIRIS‐REx and Hayabusa 2 missions , 2020, Meteoritics & Planetary Science.

[9]  A. Brearley,et al.  Altered primary iron sulfides in CM2 and CR2 carbonaceous chondrites: Insights into parent body processes , 2020, Meteoritics & Planetary Science.

[10]  M. Zolensky,et al.  A light, chondritic xenolith in the Murchison (CM) chondrite – Formation by fluid-assisted percolation during metasomatism? , 2019, Geochemistry.

[11]  A. Bischoff,et al.  Accretion of differentiated achondritic and aqueously altered chondritic materials in the early solar system—Significance of an igneous fragment in the CM chondrite NWA 12651 , 2019, Meteoritics & Planetary Science.

[12]  L. Nittler,et al.  A cometary building block in a primitive asteroidal meteorite , 2019, Nature Astronomy.

[13]  J. Trigo-Rodríguez,et al.  Accretion of Water in Carbonaceous Chondrites: Current Evidence and Implications for the Delivery of Water to Early Earth , 2019, Space Science Reviews.

[14]  J. Gattacceca,et al.  Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite , 2018, Meteoritics & Planetary Science.

[15]  A. Brearley,et al.  Primary iron sulfides in CM and CR carbonaceous chondrites: Insights into nebular processes , 2018 .

[16]  J. Hermann,et al.  In Situ Oxygen Isotope Determination in Serpentine Minerals by Ion Microprobe: Reference Materials and Applications to Ultrahigh‐Pressure Serpentinites , 2018, Geostandards and Geoanalytical Research.

[17]  N. Kita,et al.  Oxygen isotope systematics of chondrules in the Murchison CM2 chondrite and implications for the CO-CM relationship. , 2018, Geochimica et cosmochimica acta.

[18]  R. Ketcham,et al.  Evidence for accretion of fine-grained rims in a turbulent nebula for CM Murchison , 2017 .

[19]  A. Rubin An American on Paris: Extent of aqueous alteration of a CM chondrite and the petrography of its refractory and amoeboid olivine inclusions , 2015 .

[20]  K. A. Dyl,et al.  Classification of hydrous meteorites (CR, CM and C2 ungrouped) by phyllosilicate fraction: PSD-XRD modal mineralogy and planetesimal environments , 2015 .

[21]  Martin R. Lee,et al.  Aragonite, breunnerite, calcite and dolomite in the CM carbonaceous chondrites: High fidelity recorders of progressive parent body aqueous alteration , 2014 .

[22]  R. Bowden,et al.  The classification of CM and CR chondrites using bulk H, C and N abundances and isotopic compositions , 2013 .

[23]  M. Zolensky,et al.  Clasts in the CM2 carbonaceous chondrite Lonewolf Nunataks 94101: Evidence for aqueous alteration prior to complex mixing , 2013 .

[24]  P. Hoppe,et al.  NanoSIMS: Technical Aspects and Applications in Cosmochemistry and Biological Geochemistry , 2013 .

[25]  Martin R. Lee,et al.  Extended chronologies of aqueous alteration in the CM2 carbonaceous chondrites: Evidence from carbonates in Queen Alexandra Range 93005 , 2012 .

[26]  Y. Sano,et al.  Evidence for the late formation of hydrous asteroids from young meteoritic carbonates , 2012, Nature Communications.

[27]  P. Bland,et al.  Modal mineralogy of CM chondrites by X-ray diffraction (PSD-XRD): Part 2. Degree, nature and settings of aqueous alteration , 2011 .

[28]  P. Bland,et al.  Modal mineralogy of CV3 chondrites by X-ray diffraction (PSD-XRD) , 2010 .

[29]  L. Taylor,et al.  Origin of a metamorphosed lithic clast in CM chondrite Grove Mountains 021536 , 2010 .

[30]  P. Bland,et al.  Modal mineralogy of CM2 chondrites by X-ray diffraction (PSD-XRD). Part 1: Total phyllosilicate abundance and the degree of aqueous alteration , 2009 .

[31]  F. Ciesla,et al.  The Formation Conditions of Chondrules and Chondrites , 2008, Science.

[32]  A. Rubin Petrography of refractory inclusions in CM2.6 QUE 97990 and the origin of melilite‐free spinel inclusions in CM chondrites , 2007 .

[33]  Alan E. Rubin,et al.  Progressive aqueous alteration of CM carbonaceous chondrites , 2007 .

[34]  J. Trigo‐Rodríguez,et al.  Non-nebular origin of dark mantles around chondrules and inclusions in CM chondrites , 2006 .

[35]  E. Scott,et al.  Nature and Origins of Meteoritic Breccias , 2006 .

[36]  M. Zolensky,et al.  The Meteoritical Bulletin, No. 88, 2004 July , 2004 .

[37]  J. Cuzzi Blowing in the wind: III. Accretion of dust rims by chondrule-sized particles in a turbulent protoplanetary nebula , 2004 .

[38]  P. Bland,et al.  Mechanisms of weathering of meteorites recovered from hot and cold deserts and the formation of phyllosilicates , 2004 .

[39]  P. Bland,et al.  Preparation of TEM samples by focused ion beam (FIB) techniques: applications to the study of clays and phyllosilicates in meteorites , 2003, Mineralogical Magazine.

[40]  A. Brearley,et al.  Aqueous alteration of chondrules in the CM carbonaceous chondrite, Allan Hills 81002: implications for parent body alteration , 2001 .

[41]  R. Clayton,et al.  Oxygen isotope studies of carbonaceous chondrites , 1999 .

[42]  Russell,et al.  Oxygen reservoirs in the early solar nebula inferred from an allende CAI , 1998, Science.

[43]  M. Zolensky,et al.  Progressive alteration in CV3 chondrites: More evidence for asteroidal alteration , 1998 .

[44]  C. Alexander Trace element contents of chondrule rims and interchondrule matrix in ordinary chondrites , 1995 .

[45]  R. Clayton,et al.  Oxygen isotopes in separated components of CI and CM meteorites , 1994 .

[46]  A. Davis,et al.  Refractory inclusions in the prototypical CM chondrite, Mighei , 1994 .

[47]  Martin R. Lee,et al.  Alteration of calcium- and aluminium-rich inclusions in the Murray (CM2) carbonaceous chondrite , 1994 .

[48]  M. Zolensky,et al.  CM chondrites exhibit the complete petrologic range from type 2 to 1. [Abstract only] , 1994 .

[49]  D. J. Barber,et al.  FORMATION AND ALTERATION OF CAIS IN COLD BOKKEVELD (CM2) , 1994 .

[50]  M. Zolensky,et al.  Mineralogy and composition of matrix and chondrule rims in carbonaceous chondrites , 1993 .

[51]  A. Brearley Matrix and fine-grained rims in the unequilibrated CO3 chondrite, ALHA77307: Origins and evidence for diverse, primitive nebular dust components , 1993 .

[52]  D. Stöffler,et al.  Accretionary dust mantles in CM chondrites: Evidence for solar nebula processes , 1992 .

[53]  R. Clayton,et al.  Oxygen Isotopes in Separated Components of CI and CM Chondrites , 1989 .

[54]  R. Clarke,et al.  Corrosion of Fe-Ni alloys by Cl-containing akaganeite (beta -FeOOH); the Antarctic meteorite case , 1989 .

[55]  P. Buseck,et al.  Indicators of aqueous alteration in CM carbonaceous chondrites: Microtextures of a layered mineral containing Fe, S, O and Ni , 1985 .

[56]  D. J. Barber Matrix phyllosilicates and associated minerals in C2M carbonaceous chondrites , 1981 .

[57]  T. E. Bunch,et al.  Carbonaceous chondrites. II - Carbonaceous chondrite phyllosilicates and light element geochemistry as indicators of parent body processes and surface conditions , 1980 .

[58]  Harry Y. McSween,et al.  Alteration in CM carbonaceous chondrites inferred from modal and chemical variations in matrix , 1979 .

[59]  H. McSween Are carbonaceous chondrites primitive or processed? A review , 1979 .

[60]  S. Richardson,et al.  The composition of carbonaceous chondrite matrix , 1977 .

[61]  R. Clayton,et al.  DISTRIBUTION OF THE PRE-SOLAR COMPONENT IN ALLENDE AND OTHER CARBONACEOUS CHONDRITES , 1977 .

[62]  L. Fuchs,et al.  Mineralogy, mineral-chemistry, and composition of the Murchison (C2) meteorite , 1973 .

[63]  G. Mueller Significance of Inclusions in Carbonaceous Meteorites , 1966, Nature.