Optical Microscopy Observations and Construction of Dupin Cyclides at the Isotropic/Smectic A Phase Transition

In this work, we are interested in the nucleation of bâtonnets at the Isotropic/Smectic A phase transition of 10CB liquid crystal. Very often, these bâtonnets are decorated with a large number of focal conics. We present here an example of a bâtonnet obtained by optical crossed polarized microscopy in a frequently observed particular area of the sample. This bâtonnet presents bulges and one of them consists of a tessellation of ellipses. These ellipses are two by two tangent, one to each other, and their confocal hyperbolas merge at the apex of the bâtonnet. We propose a numerical simulation with Python software to reproduce this tiling of ellipses as well as the shape of the smectic layers taking the well-known shape of Dupin cyclides within this particular bâtonnet area.

[1]  D. S. Shankar Rao,et al.  Saddle-splay-induced periodic edge undulations in smectic-A disks immersed in a nematic medium. , 2020, Physical review. E.

[2]  V. Prasad,et al.  Pseudopolar smectic-C phases of azo-substituted achiral bent-core hockey-stick-shaped molecules. , 2020, Physical Review E.

[3]  J. Yeomans,et al.  Electric-field-induced shape transition of nematic tactoids. , 2017, Physical review. E.

[4]  G. R. Luckhurst,et al.  Smectic-like bâtonnets in nematic/twist-bend nematic biphasic samples , 2016 .

[5]  P. Gisse,et al.  DH* in chiral smectics under electric field , 2016, The European physical journal. E, Soft matter.

[6]  M. Pasquali,et al.  Experimental realization of crossover in shape and director field of nematic tactoids. , 2015, Physical review. E, Statistical, nonlinear, and soft matter physics.

[7]  J. Kovensky,et al.  Cholesteryl and diosgenyl glycosteroids: synthesis and characterization of new smectic liquid crystals. , 2015, Carbohydrate research.

[8]  C. Falentin-Daudré,et al.  Influence of alkyl chain length on the mesomorphism of 5-S-alkyl-5-thiopentonolactones and 5-S-alkyl-5-thiopentitols. , 2014, Carbohydrate research.

[9]  C. Meyer,et al.  The Construction of the Dupin Cyclides in a Smectic A Polygonal Texture , 2014 .

[10]  M. Yoneya,et al.  Physics of Liquid Crystals , 2014 .

[11]  Daniel A. Beller,et al.  Focal Conic Flower Textures at Curved Interfaces , 2013, 1310.6797.

[12]  Daniel A. Beller,et al.  Topographically induced hierarchical assembly and geometrical transformation of focal conic domain arrays in smectic liquid crystals , 2012, Proceedings of the National Academy of Sciences.

[13]  Hee‐Tae Jung,et al.  Generation of optical vortex array from Toric Focal Conic Domains (TFCDs) , 2012, 2012 17th Opto-Electronics and Communications Conference.

[14]  Daniel A. Beller,et al.  Pillar‐Assisted Epitaxial Assembly of Toric Focal Conic Domains of Smectic‐A Liquid Crystals , 2011, Advanced materials.

[15]  O. Lavrentovich,et al.  Liquids with conics , 2009 .

[16]  C. Bahr,et al.  Influence of phase sequence on focal conic domains in smectic films. , 2009, Physical review. E, Statistical, nonlinear, and soft matter physics.

[17]  C. Meyer,et al.  Focal Conic Stacking in Smectic A Liquid Crystals: Smectic Flower and Apollonius Tiling , 2009, Materials.

[18]  C. Bahr,et al.  Influence of anchoring strength on focal conic domains in smectic films. , 2009, Physical review. E, Statistical, nonlinear, and soft matter physics.

[19]  G. Demailly,et al.  6-S-Alkyl-6-thiohexonolactones and 6-S-Alkyl-6-thiohexitols: Efficient synthesis and new smectic liquid crystal phases , 2008 .

[20]  S. Herminghaus,et al.  Controlling smectic focal conic domains by substrate patterning. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[21]  Myung Chul Choi,et al.  Internal structure visualization and lithographic use of periodic toroidal holes in liquid crystals. , 2007, Nature materials.

[22]  S. Herminghaus,et al.  AFM study of defect-induced depressions of the smectic-A/air interface. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[23]  S. Bellemin‐Laponnaz,et al.  A new liquid crystal compound based on an ionic imidazolium salt , 2005 .

[24]  A. Kaznacheev,et al.  The influence of anchoring energy on the prolate shape of tactoids in lyotropic inorganic liquid crystals , 2003 .

[25]  P. van der Schoot,et al.  Shape and director-field transformation of tactoids. , 2003, Physical review. E, Statistical, nonlinear, and soft matter physics.

[26]  I. Dierking,et al.  Universal scaling laws for the anisotropic growth of SmA liquid crystal bâtonnets , 2003 .

[27]  Oleg D. Lavrentovich,et al.  Soft Matter Physics: An Introduction , 2002 .

[28]  O. Lavrentovich,et al.  Grain boundaries and the law of corresponding cones in smectics , 2000 .

[29]  Christophe Blanc Etude de l'interface lamellaire-éponge des systèmes lyotropes gonflés : du facettage volumique et des formes de croissance aux modèles microscopiques , 2000 .

[30]  C. Blanc,et al.  On the Shapes of Lamellar Droplets in Sponge Phase , 1999 .

[31]  J. Livage,et al.  A Structural Study of the Lyotropic Nematic Phase of Vanadium Pentoxide Gels , 1995 .

[32]  O. Lavrentovich,et al.  Focal Conics Domains in Smectics , 1994 .

[33]  P. Boltenhagen Quelques aspects des defauts dans les phases lamellaires gonflees , 1993 .

[34]  J. Fournier,et al.  Focal conic faceting in smectic-A liquid crystals , 1991 .

[35]  Cl. Williams DÉFAUTS LINÉAIRES DES MÉSOPHASES SMECTIQUES A , 1978 .

[36]  G. Friedel,et al.  Les états mésomorphes de la matière , 1922 .

[37]  O. Lehmann Cristaux liquides. Réponse à MM. G. Friedel et F. Grandjean , 1910 .

[38]  F. Grandjean,et al.  Observations géométriques sur les liquides à coniques focales , 1910 .