Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations
暂无分享,去创建一个
[1] T. D. Stack,et al. A tris(mu-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue. , 2005, Inorganic chemistry.
[2] K. Karlin,et al. Substrate oxidation by copper-dioxygen adducts: mechanistic considerations. , 2005, Journal of the American Chemical Society.
[3] A. Rosenzweig,et al. Crystal structure of a membrane-bound metalloenzyme that catalyses the biological oxidation of methane , 2005, Nature.
[4] H. Masuda,et al. Thermal Stability of Mononuclear Hydroperoxocopper(II) Species. Effects of Hydrogen Bonding and Hydrophobic Field , 2004 .
[5] E. Solomon,et al. O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms. , 2004, Proceedings of the National Academy of Sciences of the United States of America.
[6] Siegfried Schneider,et al. Combined spectroscopic and theoretical evidence for a persistent end-on copper superoxo complex. , 2004, Angewandte Chemie.
[7] K. Karlin,et al. Oxidant types in copper–dioxygen chemistry: the ligand coordination defines the Cun-O2 structure and subsequent reactivity , 2004, JBIC Journal of Biological Inorganic Chemistry.
[8] S. Fukuzumi,et al. Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand. , 2004, Inorganic chemistry.
[9] K. Karlin,et al. Solvent Effects on the Conversion of Dicopper(II) μ-η2:η2-Peroxo to Bis-μ-oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction , 2004 .
[10] M. A. Carrondo,et al. Substrate and Dioxygen Binding to the Endospore Coat Laccase from Bacillus subtilis* , 2004, Journal of Biological Chemistry.
[11] S. Prigge,et al. Dioxygen Binds End-On to Mononuclear Copper in a Precatalytic Enzyme Complex , 2004, Science.
[12] E. Solomon,et al. Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site. , 2004, Journal of the American Chemical Society.
[13] T. D. Stack,et al. Structure and spectroscopy of copper-dioxygen complexes. , 2004, Chemical reviews.
[14] D. Rorabacher,et al. Electron transfer by copper centers. , 2004, Chemical reviews.
[15] H. Hayashi,et al. Dioxygen Reactivity of Copper(I) Complexes with Tetradentate Tripodal Ligands Having Aliphatic Nitrogen Donors: Synthesis, Structures, and Properties of Peroxo and Superoxo Complexes , 2004 .
[16] William B Tolman,et al. Reactivity of dioxygen-copper systems. , 2004, Chemical reviews.
[17] J. Klinman,et al. Evidence That Dioxygen and Substrate Activation Are Tightly Coupled in Dopamine β-Monooxygenase , 2003, Journal of Biological Chemistry.
[18] J. Klinman,et al. Evidence that dioxygen and substrate activation are tightly coupled in dopamine beta-monooxygenase. Implications for the reactive oxygen species. , 2003, The Journal of biological chemistry.
[19] H. Masuda,et al. Thermal Stability and Absorption Spectroscopic Behavior of (μ‐Peroxo)dicopper Complexes Regulated with Intramolecular Hydrogen Bonding Interactions , 2003 .
[20] H. Hayashi,et al. Ligand effect on reversible conversion between copper(I) and bis(mu-oxo)dicopper(III) complex with a sterically hindered tetradentate tripodal ligand and monooxygenase activity of bis(mu-oxo)dicopper(III) complex. , 2003, Inorganic chemistry.
[21] S. Itoh,et al. Structures and redox reactivities of copper complexes of (2-pyridyl)alkylamine ligands. Effects of the alkyl linker chain length. , 2003, Inorganic chemistry.
[22] H. Masuda,et al. Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity. , 2003, Chemical communications.
[23] H. Masuda,et al. Copper hydroperoxo species activated by hydrogen-bonding interaction with its distal oxygen. , 2003, Inorganic chemistry.
[24] K. Karlin,et al. Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. , 2003, Journal of the American Chemical Society.
[25] K. Ohkubo,et al. Oxidation mechanism of phenols by dicopper-dioxygen (Cu(2)/O(2)) complexes. , 2003, Journal of the American Chemical Society.
[26] T. D. Stack,et al. Complexity with simplicity: a steric continuum of chelating diamines with copper(I) and dioxygen , 2003 .
[27] K. Karlin,et al. Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes. , 2003, Journal of the American Chemical Society.
[28] J. W. Whittaker,et al. Free radical catalysis by galactose oxidase. , 2003, Chemical reviews.
[29] K. Karlin,et al. Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations. , 2003, Inorganic chemistry.
[30] S. Schneider,et al. Reversible binding of dioxygen by the copper(I) complex with tris(2-dimethylaminoethyl)amine (Me6tren) ligand. , 2003, Inorganic chemistry.
[31] K. Karlin,et al. Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics. , 2003, Journal of the American Chemical Society.
[32] H. Masuda,et al. C–H Activation by Cu(III)2O2 Intermediate with Secondary Amino Ligand , 2003 .
[33] D. Root,et al. Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization. , 2003, Journal of the American Chemical Society.
[34] D. Powell,et al. Hydrogen Bonds around M(μ‐O)2M Rhombs: Stabilizing a {CoIII(μ‐O)2CoIII} Complex at Room Temperature , 2003 .
[35] S. Itoh,et al. Low-temperature stopped-flow studies on the reactions of copper(II) complexes and H2O2: the first detection of a mononuclear copper(II)-peroxo intermediate. , 2002, Angewandte Chemie.
[36] C. Cramer,et al. Snapshots of dioxygen activation by copper: the structure of a 1:1 Cu/O(2) adduct and its use in syntheses of asymmetric Bis(mu-oxo) complexes. , 2002, Journal of the American Chemical Society.
[37] N. Hakulinen,et al. Crystal structure of a laccase from Melanocarpus albomyces with an intact trinuclear copper site , 2002, Nature Structural Biology.
[38] Edward I. Solomon,et al. A Stabilized μ-η2:η2 Peroxodicopper(II) Complex with a Secondary Diamine Ligand and Its Tyrosinase-like Reactivity , 2002 .
[39] S. Fukuzumi,et al. Fine-tuning of copper(I)-dioxygen reactivity by 2-(2-pyridyl)ethylamine bidentate ligands. , 2002, Journal of the American Chemical Society.
[40] W. Tolman,et al. Bis(μ‐oxo)dimetal “Diamond” Cores in Copper and Iron Complexes Relevant to Biocatalysis , 2002 .
[41] K. Karlin,et al. Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes. , 2002, Journal of the American Chemical Society.
[42] Patrick L. Holland,et al. β-Diketiminate ligand backbone structural effects on Cu(I)/O2 reactivity: Unique copper-superoxo and bis(μ-oxo) complexes , 2002 .
[43] B. Krebs,et al. The crystal structure of catechol oxidase: new insight into the function of type-3 copper proteins. , 2002, Accounts of chemical research.
[44] S. Fukuzumi,et al. Oxo-transfer reaction from a bis(mu-oxo)dicopper(III) complex to sulfides. , 2002, Journal of the American Chemical Society.
[45] A. Palmer,et al. Oxygen Binding, Activation, and Reduction to Water by Copper Proteins. , 2001, Angewandte Chemie.
[46] S. Fukuzumi,et al. Modulation of coordination chemistry in copper(I) complexes supported by Bis[2-(2-pyridyl)ethyl]amine-based tridentate ligands. , 2001, Inorganic chemistry.
[47] S. Hirota,et al. Hydroperoxo--copper(II) complex stabilized by N(S)s-type ligand having a phenyl thioether. , 2001, Journal of the American Chemical Society.
[48] S. Fukuzumi,et al. Characterization of imidazolate-bridged dinuclear and mononuclear hydroperoxo complexes. , 2001, Inorganic chemistry.
[49] Shinobu Itoh,et al. Oxygenation of Phenols to Catechols by A (μ-η2:η2-Peroxo)dicopper(II) Complex: Mechanistic Insight into the Phenolase Activity of Tyrosinase , 2001 .
[50] K. Hodgson,et al. A Short Copper-Copper Distance in a (μ-1,2-Peroxo)dicopper(II) Complex Having a 1,8-Naphthyridine Unit as an Additional Bridge. , 2001, Angewandte Chemie.
[51] K. Karlin,et al. Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands. , 2001, Inorganic chemistry.
[52] K. Karlin,et al. Dioxygen-binding kinetics and thermodynamics of a series of dicopper(I) complexes with bis[2-(2-pyridyl)ethyl]amine tridendate chelators forming side-on peroxo-bridged dicopper(II) adducts. , 2000, Inorganic chemistry.
[53] T. D. Stack,et al. Differential Reactivity between Interconvertible Side-On Peroxo and Bis-μ-oxodicopper Isomers Using Peralkylated Diamine Ligands , 2000 .
[54] Patrick L. Holland,et al. Ligand macrocycle structural effects on copper-dioxygen reactivity. , 2000, Inorganic chemistry.
[55] Meyer,et al. µ(4)-Peroxo versus Bis(µ(2)-Hydroxo) Cores in Structurally Analogous Tetracopper(II) Complexes We thank Prof. Dr. G. Huttner for his generous and continuous support. Funding by the Deutsche Forschungsgemeinschaft as well as by the Fonds der Chemischen Industrie is gratefully acknowledged. , 2000, Angewandte Chemie.
[56] K. Hodgson,et al. A Systematic K-edge X-ray Absorption Spectroscopic Study of Cu(III) Sites , 2000 .
[57] H. Hayashi,et al. A Bis(μ-oxo)dicopper(III) Complex with Aromatic Nitrogen Donors: Structural Characterization and Reversible Conversion between Copper(I) and Bis(μ-oxo)dicopper(III) Species , 2000 .
[58] E. Monzani,et al. Reversible dioxygen binding and phenol oxygenation in a tyrosinase model system. , 2000, Chemistry.
[59] Patrick L. Holland,et al. Resonance Raman spectroscopy as a probe of the bis(μ-oxo)dicopper core , 2000 .
[60] Taki,et al. Aliphatic Hydroxylation by a Bis(µ-oxo)dicopper(III) Complex. , 2000, Angewandte Chemie.
[61] F. Heinemann,et al. Reversible Binding of Dioxygen by a Copper(I) Complex with Tris(2‐dimethylaminoethyl)amine (Me6tren) as a Ligand , 1999 .
[62] Edward I. Solomon,et al. Spectroscopic and Electronic Structural Studies of the Cu(III)2 Bis-μ-oxo Core and Its Relation to the Side-On Peroxo-Bridged Dimer , 1999 .
[63] A. Deydier,et al. Influence of Coordination Geometry upon Copper(II/I) Redox Potentials. Physical Parameters for Twelve Copper Tripodal Ligand Complexes , 1999 .
[64] P. Comba,et al. Stabilization of Copper Dioxygen Compounds: Design, Synthesis, and Characterization , 1999 .
[65] K. Hodgson,et al. Exogenous Substrate Reactivity with a [Cu(III)2O2]2+ Core: Structural Implications , 1999 .
[66] Patrick L. Holland,et al. Is the Bis(μ-oxo)dicopper Core Capable of Hydroxylating an Arene? , 1999, Angewandte Chemie.
[67] Patrick L. Holland,et al. Experimental Studies of the Interconversion of μ-η2:η2-Peroxo- and Bis(μ-oxo)dicopper Complexes , 1999 .
[68] K. Hodgson,et al. A Study of Solid [{Cu(MePY2)}2O2]2+ Using Resonance Raman and X-ray Absorption Spectroscopies: An Intermediate Cu2O2 Core Structure or a Solid Solution? , 1999 .
[69] E. Pidcock,et al. Peroxo-, Oxo-, and Hydroxo-Bridged Dicopper Complexes: Observation of Exogenous Hydrocarbon Substrate Oxidation , 1998 .
[70] Jeffrey P. Jones,et al. Mechanisms of N-Demethylations Catalyzed by High-Valent Species of Heme Enzymes: Novel Use of Isotope Effects and Direct Observation of Intermediates , 1998 .
[71] E. Pidcock,et al. Investigation of the Reactive Oxygen Intermediate in an Arene Hydroxylation Reaction Performed by Xylyl-Bridged Binuclear Copper Complexes , 1998 .
[72] A. Lapi,et al. Kinetic Deuterium Isotope Effect Profiles and Substituent Effects in the Oxidative N-Demethylation of N,N-Dimethylanilines Catalyzed by Tetrakis(pentafluorophenyl)porphyrin Iron(III) Chloride , 1998 .
[73] K. V. van Holde,et al. Crystal structure of a functional unit from Octopus hemocyanin. , 1998, Journal of molecular biology.
[74] H. Masuda,et al. Structural and Spectroscopic Characterization of a Mononuclear Hydroperoxo-Copper(II) Complex with Tripodal Pyridylamine Ligands. , 1998, Angewandte Chemie.
[75] W. Haase,et al. From Tetranuclear µ4-Oxo to µ4-Peroxocopper(II) Complexes , 1998 .
[76] Adam P. Cole,et al. Irreversible Reduction of Dioxygen by Simple Peralkylated Diamine−Copper(I) Complexes: Characterization and Thermal Stability of a [Cu2(μ-O)2]2+ Core , 1997 .
[77] S. Prigge,et al. Amidation of Bioactive Peptides: The Structure of Peptidylglycine α-Hydroxylating Monooxygenase , 1997 .
[78] A. Bérces. Ligand Effects in the Models and Mimics of Oxyhemocyanin and Oxytyrosinase. A Density Functional Study of Reversible Dioxygen Binding and Reversible O-O Bond Cleavage. , 1997, Inorganic chemistry.
[79] S. Fukuzumi,et al. Mechanistic Studies of Aliphatic Ligand Hydroxylation of a Copper Complex by Dioxygen: A Model Reaction for Copper Monooxygenases , 1997 .
[80] L. Que,et al. Dioxygen Binding at Ambient Temperature: Formation of a Novel Peroxodicopper(II) Complex with an Azole Macrocyclic Ligand , 1997 .
[81] K. Karlin,et al. Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction , 1997 .
[82] E. C. Wilkinson,et al. Structural, Spectroscopic, and Theoretical Characterization of Bis(μ-oxo)dicopper Complexes, Novel Intermediates in Copper-Mediated Dioxygen Activation , 1996 .
[83] Jason A. Halfen,et al. Mechanistic Study of the Oxidative N-Dealkylation Reactions of Bis(μ-oxo)dicopper Complexes , 1996 .
[84] Bradley A. Smith,et al. Ab Initio Characterization of the Isomerism between the μ-η2:η2-Peroxo- and Bis(μ-oxo)dicopper Cores , 1996 .
[85] E. Solomon,et al. Multicopper Oxidases and Oxygenases. , 1996, Chemical reviews.
[86] J. Klinman. Mechanisms Whereby Mononuclear Copper Proteins Functionalize Organic Substrates. , 1996, Chemical reviews.
[87] W. Tolman,et al. Dioxygen Activation by a Copper(I) Complex of a New Tetradentate Tripodal Ligand: Mechanistic Insights into Peroxodicopper Core Reactivity , 1996 .
[88] Adam P. Cole,et al. A Trinuclear Intermediate in the Copper-Mediated Reduction of O2: Four Electrons from Three Coppers , 1996, Science.
[89] Jason A. Halfen,et al. Reversible Cleavage and Formation of the Dioxygen O-O Bond Within a Dicopper Complex , 1996, Science.
[90] E. C. Wilkinson,et al. A New Intermediate in Copper Dioxygen Chemistry: Breaking the O-O Bond To Form a {Cu2(.mu.-O)2}2+ Core , 1995 .
[91] Jeffrey P. Jones,et al. Mechanism of Oxidative Amine Dealkylation of Substituted N,N-Dimethylanilines by Cytochrome P-450: Application of Isotope Effect Profiles , 1995 .
[92] Y. Moro-oka,et al. A Monomeric Side-On Superoxocopper(II) Complex: Cu(O2)(HB(3-tBu-5-iPrpz)3) , 1994 .
[93] A. Messerschmidt. Blue Copper Oxidases , 1994 .
[94] B. Krebs,et al. A Thermally Stable Peroxocopper(II) Complex with Unusual μ4‐Coordination of the Peroxo Ligand , 1994 .
[95] Bart Hazes,et al. Crystallographic analysis of oxygenated and deoxygenated states of arthropod hemocyanin shows unusual differences , 1994, Proteins.
[96] K. Karlin,et al. Reversible Dioxygen Binding and Aromatic Hydroxylation in O2-Reactions with Substituted Xylyl Dinuclear Copper(I) Complexes: Syntheses and Low-Temperature Kinetic/Thermodynamic and Spectroscopic Investigations of a Copper Monooxygenase Model System , 1994 .
[97] M. McPherson,et al. Novel thioether bond revealed by a 1.7 Å crystal structure of galactose oxidase , 1994, Nature.
[98] K. Karlin,et al. Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands , 1993 .
[99] J. Bonaventura,et al. Crystal structure of deoxygenated limulus polyphemus subunit II hemocyanin at 2.18 Å resolution: Clues for a mechanism for allosteric regulation , 1993, Protein science : a publication of the Protein Society.
[100] K. Karlin,et al. Reversible reaction of O2 (and CO) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(μ-1,2-peroxo)dicopper(II) product , 1993 .
[101] L. Simándi. Catalytic Activation of Dioxygen by Metal Complexes , 1992 .
[102] K. Karlin,et al. Mechanism of aromatic hydroxylation in a copper monooxygenase model system. 1,2-methyl migrations and the NIH shift in copper chemistry , 1992 .
[103] Akira Nakamura,et al. A new model for dioxygen binding in hemocyanin. Synthesis, characterization, and molecular structure of the .mu.-.eta.2:.eta.2 peroxo dinuclear copper(II) complexes, [Cu(HB(3,5-R2pz)3)]2(O2) (R = isopropyl and Ph) , 1992 .
[104] K. Karlin,et al. Spectroscopic and theoretical studies of an end-on peroxide-bridged coupled binuclear copper(II) model complex of relevance to the active sites in hemocyanin and tyrosinase , 1991 .
[105] K. Karlin,et al. Kinetic, thermodynamic, and spectral characterization of the primary copper-oxygen (Cu-O2) adduct in a reversibly formed and structurally characterized peroxo-dicopper(II) complex , 1991 .
[106] K. Karlin,et al. Reactivity patterns and comparisons in three classes of synthetic copper-dioxygen {Cu2-O2} complexes: implication for structure and biological relevance , 1991 .
[107] K. Karlin,et al. A trinuclear copper(I) complex: Reaction with dioxygen and the formation of a hexanuclear copper(II) cluster , 1990 .
[108] K. Karlin,et al. Synthesis and X-ray crystal structure of a trinuclear copper(I) cluster , 1989 .
[109] K. Karlin,et al. Kinetic and thermodynamic studies on the reaction of oxygen with two dinuclear copper(I) complexes , 1988 .
[110] K. Karlin,et al. Dioxygen−copper reactivity: generation, characterization, and reactivity of a hydroperoxo−dicopper(II) complex , 1988 .
[111] Jon Zubieta,et al. A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System , 1988 .
[112] K. Karlin,et al. Dioxygen-copper reactivity: x-ray structure and characterization of an (acylperoxo)dicopper complex , 1987 .
[113] K. Karlin,et al. Dioxygen—Copper Reactivity: Hydroxylation-induced Methyl Migration in a Copper Monooxygenase Model System , 1987 .
[114] K. Karlin,et al. Dioxygen-copper reactivity. Reversible binding of O2 and CO to a phenoxo-bridged dicopper(I) complex , 1987 .
[115] K. Karlin,et al. Dioxygen-copper reactivity: intermediacy of a peroxo-dicopper(II) (dioxygen-copper) complex in the hydroxylation reaction of a model mono-oxygenase system , 1986 .
[116] E. Monzani,et al. The phenol ortho-oxygenation by mononuclear copper(I) complexes requires a dinuclear mu-eta2:eta2-peroxodicopper(II) complex rather than mononuclear CuO2 species. , 2003, Chemical communications.
[117] K. Karlin,et al. Dioxygen–copper reactivity at trinuclear centers: formation of hexanuclear and mixed-valent adducts , 1999 .
[118] K. Pierloot,et al. Theoretical Study of the Interconversion of O2-Binding Dicopper Complexes , 1997 .
[119] R. Mains,et al. The biosynthesis of neuropeptides: peptide alpha-amidation. , 1992, Annual review of neuroscience.
[120] K. Karlin,et al. Copper-mediated hydroxylation of an arene ― model system for the action of copper monooxygenases: structures of a binuclear Cu(I) complex and its oxygenated product , 1984 .
[121] K. Karlin,et al. Tetragonal vs. trigonal coordination in copper(II) complexes with tripod ligands: structures and properties of [Cu(C21H24N4)Cl]PF6 and [Cu(C18H18N4)Cl]PF6 , 1982 .