Assessment on thermoelectric power factor in silicon nanowire networks

Thermoelectric devices based on three-dimensional networks of highly interconnected silicon nanowires were fabricated and the parameters that contribute to the power factor, namely the Seebeck coefficient and electrical conductivity were assessed. The large area (2 cm × 2 cm) devices were fabricated at low cost utilizing a highly scalable process involving silicon nanowires grown on steel substrates. Temperature dependence of the Seebeck coefficient was found to be weak over the range of 20–80 °C at approximately −400 µV/K for unintentionally doped devices and ±50 µV/K for p-type and n-type devices, respectively.

[1]  Raja Mannam,et al.  High Seebeck Coefficient BiSbTe Nanowires , 2010 .

[2]  Yu-Ming Lin,et al.  Semimetal–semiconductor transition in Bi1−xSbx alloy nanowires and their thermoelectric properties , 2002 .

[3]  J. Seto The electrical properties of polycrystalline silicon films , 1975 .

[4]  A. Majumdar,et al.  Enhanced thermoelectric performance of rough silicon nanowires , 2008, Nature.

[5]  Gang Zhang,et al.  Size dependent thermoelectric properties of silicon nanowires , 2009 .

[6]  E. Majková,et al.  Temperature Dependence of the Seebeck Coefficient in Insb Prepared by Rapid Quenching , 1989 .

[7]  J. Rand,et al.  Silicon Nanowire Solar Cells , 2007 .

[8]  Xuema Li,et al.  Epitaxial growth of ensembles of indium phosphide nanowires on various non-single crystal substrates using an amorphous template layer , 2011 .

[9]  M. P. Walsh,et al.  Nanostructured thermoelectric materials , 2005 .

[10]  Ke Xu,et al.  Size‐Dependent Transport and Thermoelectric Properties of Individual Polycrystalline Bismuth Nanowires , 2006 .

[11]  Asfaw Beyene,et al.  Low‐grade heat‐driven Rankine cycle, a feasibility study , 2008 .

[12]  Gengchiau Liang,et al.  Geometry effects on thermoelectric properties of silicon nanowires based on electronic band structures , 2010 .

[13]  Amal K. Ghosh,et al.  Theory of the electrical and photovoltaic properties of polycrystalline silicon , 1980 .

[14]  Sung-Mo Kang,et al.  Fringing field effects on electrical resistivity of semiconductor nanowire-metal contacts , 2008 .

[15]  William A. Goddard,et al.  Silicon nanowires as efficient thermoelectric materials , 2008, Nature.

[16]  R. Venkatasubramanian,et al.  Thin-film thermoelectric devices with high room-temperature figures of merit , 2001, Nature.

[17]  S. Müller,et al.  Microchip for the Measurement of Seebeck Coefficients of Single Nanowires , 2009 .

[18]  H. Hng,et al.  A Simple Chemical Approach for PbTe Nanowires with Enhanced Thermoelectric Properties , 2008 .

[19]  Igor Ostrovskii,et al.  Si and Si‐Ge wires for thermoelectrics , 2011 .

[20]  W. Fulkerson,et al.  Thermal Conductivity, Electrical Resistivity, and Seebeck Coefficient of Silicon from 100 to 1300°K , 1968 .

[21]  Osamu Yamashita,et al.  DEPENDENCE OF SEEBECK COEFFICIENT ON CARRIER CONCENTRATION IN HEAVILY B- AND P-DOPED SI1-XGEX (X 0.05) SYSTEM , 1999 .

[22]  Myungsim Jun,et al.  The Characteristics of Seebeck Coefficient in Silicon Nanowires Manufactured by CMOS Compatible Process , 2010, Nanoscale research letters.

[23]  J.D. Meindl,et al.  Modeling and optimization of monolithic polycrystalline silicon resistors , 1981, IEEE Transactions on Electron Devices.

[24]  M. Dresselhaus,et al.  Thermoelectric figure of merit of a one-dimensional conductor. , 1993, Physical review. B, Condensed matter.

[25]  Wei Wang,et al.  Electrochemically assembled p-type Bi2Te3 nanowire arrays , 2004 .