The Escape Probability of Some Ions from Mars and Titan Ionospheres

The Kinetic Energy Release (KER) for various ionic species coming from two-body dissociations reactions, induced by double photoionization of CO2, C2H2 and N2O neutral precursors of interest in planetary atmospheres, are reported. The KER distributions as a function of the VUV photon energy in the range of 30-65 eV are extracted from the coincidences spectra obtained by using tunable synchrotron radiation and electron-ion-ion coincidences coupled with ion imaging techniques. This experimental method, coupled with a computational analysis of the data based on a Monte Carlo trajectoriy simulation, allows to discuss about the probability for some ionic species to escape the upper atmosphere of Mars and Titan. In fact, the KER measured for H + , C + , CH + , CH\(_{\rm 2}^{\rm +}\), N + , O + and CO + fragment ions are ranging between 1.0 and 6.0 eV, and these translational energy contents are large enough to allow these ionic species in participating in the atmospheric escape from Mars and Titan into space.

[1]  Stefano Falcinelli,et al.  Penning ionization of N2O molecules by He*(2(3,1)S) and Ne*(3P2,0) metastable atoms: theoretical considerations about the intermolecular interactions. , 2005, The Journal of chemical physics.

[2]  Marzio Rosi,et al.  Production of ions at high energy and its role in extraterrestrial environments , 2013, Rendiconti Lincei.

[3]  Stefano Falcinelli,et al.  Predicted structure and energetics of HCl2 , 2003 .

[4]  Stefano Falcinelli,et al.  Threshold-photoelectron-spectroscopy-coincidence study of the double photoionization of HBr. , 2004, The Journal of chemical physics.

[5]  Marzio Rosi,et al.  On the bonding in Be22 , 1989 .

[6]  O. Witasse,et al.  Prediction of a CO22+ layer in the atmosphere of Mars , 2002 .

[7]  Stefano Falcinelli,et al.  Mass spectrometric study of double photoionization of HBr molecules , 2002 .

[8]  Vincenzo Aquilanti,et al.  The He + H2+ → HeH+ + H reaction: ab initio studies of the potential energy surface, benchmark time-independent quantum dynamics in an extended energy range and comparison with experiments. , 2012, The Journal of chemical physics.

[9]  Stefano Falcinelli,et al.  Interaction components in the hydrogen halide dications , 2007 .

[10]  Roland Thissen,et al.  Dissociations of the ethyne dication C2H2+2 , 1993 .

[11]  O. Dutuit,et al.  Modelling dications in the diurnal ionosphere of Venus , 2007 .

[12]  Stefano Falcinelli,et al.  Lifetime and kinetic energy release of metastable dications dissociation , 2012 .

[13]  Nadia Balucani,et al.  CRITICAL REVIEW OF N, N+, N+2, N++, And N++2 MAIN PRODUCTION PROCESSES AND REACTIONS OF RELEVANCE TO TITAN'S ATMOSPHERE , 2013 .

[14]  Thomas A. Field,et al.  Lifetimes of metastable molecular doubly charged ions , 1993 .

[15]  A. T. Tokunaga,et al.  Detection of acetylene in the infrared spectrum of comet Hyakutake , 1996, Nature.

[16]  Stefano Falcinelli,et al.  PRODUCTION OF THE MOLECULAR DI-CATION ARN2+ IN THE REACTION AR2+ + N2 , 1999 .

[17]  R. Kaiser,et al.  Experimental investigation on the formation of carbon-bearing molecules in the interstellar medium via neutral-neutral reactions. , 2002, Chemical reviews.

[18]  Carl P. Simon,et al.  Prediction of a N2++ layer in the upper atmosphere of Titan , 2005 .

[19]  Karlsson,et al.  Novel time of flight instrument for doppler free kinetic energy release spectroscopy. , 1995, Physical review letters.

[20]  M. S. El-shall,et al.  Polymerization of ionized acetylene clusters into covalent bonded ions: evidence for the formation of benzene radical cation. , 2006, Journal of the American Chemical Society.

[21]  Stefano Falcinelli MASS SPECTROMETRIC DETECTION OF ALKALINE EARTH MONOHALIDE DICATIONS , 1996 .

[22]  Marzio Rosi,et al.  Addendum to “on the bonding in Be22+” , 1990 .

[23]  E. Bodo,et al.  The soft X-ray absorption spectrum of the allyl free radical. , 2013, Physical chemistry chemical physics : PCCP.

[24]  R. Richter,et al.  Anisotropy of the angular distribution of fragment ions in dissociative double photoionization of N2O molecules in the 30-50 eV energy range. , 2007, The Journal of chemical physics.

[25]  Stefano Falcinelli,et al.  Double photoionization of N2O molecules in the 28–40 eV energy range , 2006 .

[26]  Linsen Pei,et al.  Ion imaging study of reaction dynamics in the N+ + CH4 system. , 2012, The Journal of chemical physics.

[27]  Stefano Falcinelli,et al.  The stereodynamics of the Penning ionization of water by metastable neon atoms. , 2013, The Journal of chemical physics.

[28]  Cleanthes A. Nicolaides,et al.  Energy generation from volcanic ground states. Application to cold He22 , 1989 .

[29]  J. H. Waite,et al.  Composition of Titan's ionosphere , 2006 .

[30]  Linus Pauling,et al.  The Normal State of the Helium Molecule-Ions He 2 + and He 2 ++ , 1933 .

[31]  M. Lavollée,et al.  A new detector for measuring three-dimensional momenta of charged particles in coincidence , 1999 .

[32]  T. R. Carson,et al.  Doubly Charged Diatomic Molecular Ions , 1955 .

[33]  Jean Lilensten,et al.  Doubly-charged ions in the planetary ionospheres: a review. , 2011, Physical chemistry chemical physics : PCCP.

[34]  Marzio Rosi,et al.  Dissociative Ionization of Methyl Chloride and Methyl Bromide by Collision with Metastable Neon Atoms , 1997 .

[35]  Vincenzo Aquilanti,et al.  Revisiting the potential energy surface for the He + H+2 → HeH+ + H reaction at the full configuration interaction level , 2009 .

[36]  Marzio Rosi,et al.  Dissociative double photoionization of benzene molecules in the 26-33 eV energy range. , 2011, Physical chemistry chemical physics : PCCP.

[37]  R. Richter,et al.  Double photoionization of CO2 molecules in the 34-50 eV energy range. , 2009, The journal of physical chemistry. A.

[38]  Eric Herbst,et al.  The Synthesis of Benzene in the Proto-planetary Nebula CRL 618 , 2002 .

[39]  J. W. Winchester,et al.  Chemistry of atmospheres, 2nd ed.: Edited by Richard P. Wayne. Oxford University Press, 1991, US $85.00 (cloth; ISBN 0-19-855574-1), US $39.95 (paper, ISBN 0-19-855571-7) , 1993 .

[40]  C. Callegari,et al.  Angular and energy distribution of fragment ions in dissociative double photoionization of acetylene molecules at 39 eV. , 2012, The Journal of chemical physics.

[41]  Roland Thissen,et al.  Internal energy effects in the reactivity of CO22+ doubly charged molecular ions with CO2 and CO , 2003 .

[42]  Ana Heras,et al.  Infrared Space Observatory's Discovery of C4H2, C6H2, and Benzene in CRL 618 , 2001 .

[43]  P. Lablanquie,et al.  Spectroscopy and metastability of CO2 2+ molecular ions. , 2005, The Journal of chemical physics.

[44]  Linsen Pei,et al.  Ion imaging study of dissociative charge transfer in the N2(+) + CH4 system. , 2013, The Journal of chemical physics.