Insights into the Dynamic Evolution of Defects in Electrocatalysts

This review focuses on the formation and preparation of defects, the dynamic evolution process of defects, and the influence of defect dynamic evolution on catalytic reactions. The summary of the current advances in the dynamic evolution process of defects in oxygen evolution reaction, hydrogen evolution reaction, nitrogen reduction reaction, oxygen reduction reaction, and carbon dioxide reduction reaction, and the given perspectives are expected to provide a more comprehensive understanding of defective electrocatalysts on the structural evolution process during electrocatalysis and the reaction mechanisms, especially for the defect dynamic evolution on the performance in catalytic reactions.

[1]  Qingbing Xia,et al.  Interface challenges and optimization strategies for aqueous zinc-ion batteries , 2022, Journal of Energy Chemistry.

[2]  Liang Wang,et al.  Progress and Prospects of Emerging Potassium–Sulfur Batteries , 2022, Advanced Energy Materials.

[3]  Haifeng Lv,et al.  Constructing Air-Stable and Reconstruction-Inhibited Transition Metal Sulfide Catalysts via Tailoring Electron-Deficient Distribution for Water Oxidation , 2022, ACS Catalysis.

[4]  Shuangyin Wang,et al.  Confinement Engineering of Electrocatalyst Surfaces and Interfaces , 2022, Advanced Functional Materials.

[5]  Guang-bo Zhao,et al.  Pulsed Electrocatalysis Enables the Stabilization and Activation of Carbon-Based Catalysts Towards H2o2 Production , 2022, SSRN Electronic Journal.

[6]  X. Zhao,et al.  Synthesis of Carbon-Modified Cobalt Disphosphide as Anode for Sodium-Ion Storage , 2022, Electrochimica Acta.

[7]  Zichao Yan,et al.  Two‐in‐one shell configuration for bimetal selenides toward fast sodium storage within broadened voltage windows , 2022, Carbon Energy.

[8]  S. Dou,et al.  Nanostructure Engineering Strategies of Cathode Materials for Room-Temperature Na-S Batteries. , 2022, ACS nano.

[9]  Y. Li,et al.  Towards rechargeable Na-SexSy batteries: from fundamental insights to improvement strategies , 2022, Chemical Engineering Journal.

[10]  S. Dou,et al.  Electrolytes/Interphases: Enabling Distinguishable Sulfur Redox Processes in Room‐Temperature Sodium‐Sulfur Batteries , 2022, Advanced Energy Materials.

[11]  Li Tao,et al.  Combined anodic and cathodic hydrogen production from aldehyde oxidation and hydrogen evolution reaction , 2021, Nature Catalysis.

[12]  Shuangyin Wang,et al.  High-Entropy Alloys for Electrocatalysis: Design, Characterization, and Applications. , 2021, Small.

[13]  Hao Ming Chen,et al.  Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis , 2021, Nature Energy.

[14]  Yong‐Mook Kang,et al.  In Situ Defect Engineering Route to Optimize the Cationic Redox Activity of Layered Double Hydroxide Nanosheet via Strong Electronic Coupling with Holey Substrate , 2021, Advanced science.

[15]  Yao Zhou,et al.  Evolution of Cationic Vacancy Defects: A Motif for Surface Restructuration of OER Precatalyst. , 2021, Angewandte Chemie.

[16]  Guoxiu Wang,et al.  Activating Inert Surface Pt Single Atoms via Subsurface Doping for Oxygen Reduction Reaction. , 2021, Nano letters.

[17]  S. Agnoli,et al.  Operando visualization of the hydrogen evolution reaction with atomic-scale precision at different metal–graphene interfaces , 2021, Nature Catalysis.

[18]  Shuangyin Wang,et al.  Coupling Glucose‐Assisted Cu(I)/Cu(II) Redox with Electrochemical Hydrogen Production , 2021, Advanced materials.

[19]  Qingtao Wang,et al.  Defect Engineering of Sb2Te3 through Different Doses of Ion Irradiation to Boost Hydrogen Evolution Reaction Performance , 2021, ACS Applied Energy Materials.

[20]  S. Dou,et al.  Architecting Freestanding Sulfur Cathodes for Superior Room‐Temperature Na–S Batteries , 2021, Advanced Functional Materials.

[21]  Nengneng Xu,et al.  Large-scale defect-engineering tailored tri-doped graphene as a metal-free bifunctional catalyst for superior electrocatalytic oxygen reaction in rechargeable Zn-air battery , 2021 .

[22]  S. Dou,et al.  Understanding Sulfur Redox Mechanisms in Different Electrolytes for Room-Temperature Na–S Batteries , 2021, Nano-Micro Letters.

[23]  Huisheng Peng,et al.  Stabilizing Highly Active Ru Sites by Suppressing Lattice Oxygen Participation in Acidic Water Oxidation. , 2021, Journal of the American Chemical Society.

[24]  L. Robben,et al.  The Impact of the Manufacturing and Corrosion Steps of the AuCu Master Alloy on the Catalytic Activity of Nanoporous Gold for CO Oxidation , 2021, SSRN Electronic Journal.

[25]  R. Ma,et al.  A glass-ceramic with accelerated surface reconstruction toward the efficient oxygen evolution reaction. , 2020, Angewandte Chemie.

[26]  Zongping Shao,et al.  Anion Etching for Accessing Rapid and Deep Self-Reconstruction of Precatalysts for Water Oxidation , 2020, Matter.

[27]  Chuankun Jia,et al.  Defect Chemistry on Electrode Materials for Electrochemical Energy Storage and Conversion , 2020 .

[28]  Huakun Liu,et al.  Efficient separators with fast Li-ion transfer and high polysulfide entrapment for superior lithium-sulfur batteries , 2020 .

[29]  Yuyang Hou,et al.  Tunable Cationic Vacancies of Cobalt Oxides for Efficient Electrocatalysis in Li–O2 Batteries , 2020, Advanced Energy Materials.

[30]  Jun Chen,et al.  A Directional Synthesis for Topological Defect in Carbon , 2020, Chem.

[31]  Conggang Li,et al.  Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions , 2020, Nature Chemistry.

[32]  H. Duan,et al.  Operando Identification of the Dynamic Behavior of Oxygen Vacancy-rich Co3O4 for Oxygen Evolution Reaction. , 2020, Journal of the American Chemical Society.

[33]  S. Dou,et al.  Electrocatalysing S Cathodes via Multisulfiphilic Sites for Superior Room-Temperature Sodium-Sulfur Batteries. , 2020, ACS nano.

[34]  Kang Jiang,et al.  Spontaneous Atomic Ruthenium Doping in Mo2CTX MXene Defects Enhances Electrocatalytic Activity for the Nitrogen Reduction Reaction , 2020, Advanced Energy Materials.

[35]  Yu Wang,et al.  Insights into the role of cation vacancy for significantly enhanced electrochemical nitrogen reduction , 2020 .

[36]  Shiping Huang,et al.  Tackling the Activity and Selectivity Challenges of Electrocatalysts towards Nitrogen Reduction Reaction via Atomically Dispersed Bi-Atom Catalysts. , 2020, Journal of the American Chemical Society.

[37]  M. Jaroniec,et al.  Phosphorus vacancies boost electrocatalytic hydrogen evolution by two orders of magnitude. , 2020, Angewandte Chemie.

[38]  Chuankun Jia,et al.  Defect Engineering on Electrode Materials for Rechargeable Batteries , 2020, Advanced materials.

[39]  A. Ruzsinszky,et al.  Chemisorption can Reverse Defect-defect Interaction on Heterogeneous Catalyst Surfaces. , 2019, The journal of physical chemistry letters.

[40]  D. Gao,et al.  Special atmosphere annealed Co3O4 porous nanoclusters with oxygen defects and high proportion of Co2+ for oxygen evolution reaction , 2019, Journal of Alloys and Compounds.

[41]  M. Antonietti,et al.  Electrochemical Reduction of N2 into NH3 by Donor-Acceptor Couples of Ni and Au Nanoparticles with a 67.8% Faradaic Efficiency. , 2019, Journal of the American Chemical Society.

[42]  Zhichuan J. Xu,et al.  Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation , 2019, Nature Catalysis.

[43]  Cheng Sun,et al.  Defect engineering of molybdenum disulfide through ion irradiation to boost hydrogen evolution reaction performance , 2019, Nano Research.

[44]  M. Bechelany,et al.  Role of Sulfur Vacancies and Undercoordinated Mo Regions in MoS2 Nanosheets toward the Evolution of Hydrogen. , 2019, ACS nano.

[45]  W. Fei,et al.  Defect‐Rich Heterogeneous MoS2/NiS2 Nanosheets Electrocatalysts for Efficient Overall Water Splitting , 2019, Advanced science.

[46]  S. Pawar,et al.  Electrosynthesis of copper phosphide thin films for efficient water oxidation , 2019, Materials Letters.

[47]  Hao Ming Chen,et al.  Operando Unraveling of the Structural and Chemical Stability of P-Substituted CoSe2 Electrocatalysts toward Hydrogen and Oxygen Evolution Reactions in Alkaline Electrolyte , 2019, ACS Energy Letters.

[48]  Changhong Wang,et al.  Understanding the Nature of Ammonia Treatment to Synthesize Oxygen Vacancy-Enriched Transition Metal Oxides , 2019, Chem.

[49]  N. Shibata,et al.  Defect-Rich NiCeOx Electrocatalyst with Ultrahigh Stability and Low Overpotential for Water Oxidation , 2019, ACS Catalysis.

[50]  Meilin Liu,et al.  Defect Engineering in Single-Layer MoS2 Using Heavy Ion Irradiation. , 2018, ACS applied materials & interfaces.

[51]  Jun Chen,et al.  A Defect-Driven Metal-free Electrocatalyst for Oxygen Reduction in Acidic Electrolyte , 2018, Chem.

[52]  Ru Chen,et al.  Recent Advances on Black Phosphorus for Energy Storage, Catalysis, and Sensor Applications , 2018, Advanced materials.

[53]  Guihua Yu,et al.  Significantly Improving Lithium-Ion Transport via Conjugated Anion Intercalation in Inorganic Layered Hosts. , 2018, ACS nano.

[54]  J. Llorca,et al.  Outstanding Methane Oxidation Performance of Palladium-Embedded Ceria Catalysts Prepared by a One-Step Dry Ball-Milling Method , 2018, Angewandte Chemie.

[55]  F. Pan,et al.  Nitrogen‐Doped CoP Electrocatalysts for Coupled Hydrogen Evolution and Sulfur Generation with Low Energy Consumption , 2018, Advanced materials.

[56]  H. Xin,et al.  Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential , 2018, Nature Communications.

[57]  Min Han,et al.  Defect‐Rich Ni3FeN Nanocrystals Anchored on N‐Doped Graphene for Enhanced Electrocatalytic Oxygen Evolution , 2018 .

[58]  Ti-Wei Chen,et al.  An activity recoverable carbon nanotube based electrocatalysts: Rapid annealing effects and importance of defects , 2018 .

[59]  E. Besley,et al.  Implanting Germanium into Graphene. , 2018, ACS nano.

[60]  Shaojun Guo,et al.  Defects and Interfaces on PtPb Nanoplates Boost Fuel Cell Electrocatalysis. , 2018, Small.

[61]  Hui Wu,et al.  Defective MoS2 electrocatalyst for highly efficient hydrogen evolution through a simple ball-milling method , 2017, Science China Materials.

[62]  Shaohua Shen,et al.  Atomic‐Scale CoOx Species in Metal–Organic Frameworks for Oxygen Evolution Reaction , 2017 .

[63]  L. Dai,et al.  Defect Chemistry of Nonprecious‐Metal Electrocatalysts for Oxygen Reactions , 2017, Advanced materials.

[64]  Y. Kimura,et al.  Operando Soft X-ray Absorption Spectroscopic Study on a Solid Oxide Fuel Cell Cathode during Electrochemical Oxygen Reduction. , 2017, ChemSusChem.

[65]  Q. Ramasse,et al.  Ion-beam modification of 2-D materials - single implant atom analysis via annular dark-field electron microscopy. , 2017, Ultramicroscopy.

[66]  Charlie Tsai,et al.  Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution , 2017, Nature Communications.

[67]  Hyunjun Yoo,et al.  Bulk layered heterojunction as an efficient electrocatalyst for hydrogen evolution , 2017, Science Advances.

[68]  A. V. van Duin,et al.  Atomistic-Scale Simulations of Defect Formation in Graphene under Noble Gas Ion Irradiation. , 2016, ACS nano.

[69]  P. Bordet,et al.  Defects do Catalysis: CO Monolayer Oxidation and Oxygen Reduction Reaction on Hollow PtNi/C Nanoparticles , 2016 .

[70]  Y. Orikasa,et al.  Overpotential-Induced Introduction of Oxygen Vacancy in La0.67Sr0.33MnO3 Surface and Its Impact on Oxygen Reduction Reaction Catalytic Activity in Alkaline Solution , 2016 .

[71]  Sung-Fu Hung,et al.  In Operando Identification of Geometrical-Site-Dependent Water Oxidation Activity of Spinel Co3O4. , 2016, Journal of the American Chemical Society.

[72]  Peter Strasser,et al.  Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution , 2015, Nature Communications.

[73]  Hao Ming Chen,et al.  Reversible adapting layer produces robust single-crystal electrocatalyst for oxygen evolution , 2015, Nature Communications.

[74]  Wei Li,et al.  High Substitution Rate in TiO 2 Anatase Nanoparticles with Cationic Vacancies for Fast Lithium Storage , 2015 .

[75]  Shoushan Fan,et al.  Grain-boundary-dependent CO2 electroreduction activity. , 2015, Journal of the American Chemical Society.

[76]  A. El Mel,et al.  Unusual dealloying effect in gold/copper alloy thin films: the role of defects and column boundaries in the formation of nanoporous gold. , 2015, ACS applied materials & interfaces.

[77]  R. Schlögl Heterogeneous catalysis. , 2015, Angewandte Chemie.

[78]  Zhenhai Xia,et al.  A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions. , 2015, Nature nanotechnology.

[79]  Q. Ramasse,et al.  Ion implantation of graphene-toward IC compatible technologies. , 2013, Nano letters.

[80]  H. Hosono,et al.  Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store. , 2012, Nature chemistry.

[81]  J. Baek,et al.  Edge-carboxylated graphene nanosheets via ball milling , 2012, Proceedings of the National Academy of Sciences.

[82]  A. N. Gavrilov,et al.  On the influence of the metal loading on the structure of carbon-supported PtRu catalysts and their electrocatalytic activities in CO and methanol electrooxidation. , 2007, Physical chemistry chemical physics : PCCP.

[83]  Charles T. Campbell,et al.  Oxygen Vacancies and Catalysis on Ceria Surfaces , 2005, Science.

[84]  Jackie Y. Ying,et al.  Defect and transport properties of nanocrystalline CeO2-x , 1996 .