Bis(imino)acenaphthene N ‐Heterocyclic Carbene Palladium Complexes Bearing Tertiary Amines: Structural and Catalytic Studies on the Interaction between Soft Acid and Hard Base

[1]  R. Szostak,et al.  [(NHC)PdCl2(Aniline)] Complexes: Easily Synthesized, Highly Active Pd(II)-NHC Precatalysts for Cross-Coupling Reactions. , 2021, The Journal of organic chemistry.

[2]  M. Michalak,et al.  Acenaphthene-Based N-Heterocyclic Carbene Metal Complexes: Synthesis and Application in Catalysis , 2021, Catalysts.

[3]  Ming‐Tsz Chen,et al.  ( N ‐Heterocyclic carbene) ion‐pair palladium complexes: Suzuki–Miyaura cross‐coupling studies in neat water under mild conditions , 2020 .

[4]  B. Hammouti,et al.  Metal-NHC heterocycle complexes in catalysis and biological applications: Systematic review , 2020, Materials Today: Proceedings.

[5]  Kuo-Hui Wu,et al.  N , N ′‐bridged binuclear NHC palladium complexes: A combined experimental catalytic and computational study for the Suzuki reaction , 2020 .

[6]  Ming‐Tsz Chen,et al.  N‐heterocyclic carbene–palladium complexes for Suzuki–Miyaura coupling reaction with benzyl chloride and aromatic boronic acid leading to diarylmethanes , 2019, Applied Organometallic Chemistry.

[7]  R. Szostak,et al.  Triflamides: Highly Reactive, Electronically Activated N-Sulfonyl Amides in Catalytic N-C(O) Amide Cross-Coupling. , 2019, Organic letters.

[8]  A. Nova,et al.  Designing Pd and Ni Catalysts for Cross-Coupling Reactions by Minimizing Off-Cycle Species , 2018 .

[9]  Yang Zhang,et al.  Robust Acenaphthoimidazolylidene Palladacycles: Highly Efficient Catalysts for the Amination of N-Heteroaryl Chlorides. , 2017, Chemistry, an Asian journal.

[10]  Zhuofeng Ke,et al.  Flexible Steric Bulky Bis(Imino)acenaphthene (BIAN)-Supported N-Heterocyclic Carbene Palladium Precatalysts: Catalytic Application in Buchwald-Hartwig Amination in Air. , 2017, The Journal of organic chemistry.

[11]  K. Houk,et al.  Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Esters. , 2017, Journal of the American Chemical Society.

[12]  Beibei Ma,et al.  Pd-PEPPSI Complexes Bearing Bulky [(1,2-Di-(tert-butyl)acenaphthyl] (DtBu-An) on N-Heterocarbene Backbones: Highly Efficient for Suzuki–Miyaura Cross-Coupling under Aerobic Conditions , 2016 .

[13]  N. Chatani,et al.  Cross-Couplings Using Aryl Ethers via C-O Bond Activation Enabled by Nickel Catalysts. , 2015, Accounts of chemical research.

[14]  E. Jésus,et al.  Water-Soluble Palladium(II) Complexes with Sulfonated N-Heterocyclic Carbenes in Suzuki Cross-Coupling and Hydrodehalogenation Reactions , 2015 .

[15]  Jonathan M. Behrendt,et al.  Conjugated polymer nanoparticles by Suzuki-Miyaura cross-coupling reactions in an emulsion at room temperature , 2014 .

[16]  Ming‐Tsz Chen,et al.  Sonogashira couplings catalyzed by collaborative (N-heterocyclic carbene)-copper and -palladium complexes. , 2014, Organic letters.

[17]  M. Turner,et al.  [(1,3-Bis{2,6-bis(diphenylmethyl)-4-methylphenyl}imidazole-2-ylidene)PdCl2(NEt3)]: “Throwing away” a different ancillary ligand to enhance the catalytic activity at room temperature , 2014 .

[18]  S. M. Humphrey,et al.  Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C–C coupling catalysts and solvent effects in organic and aqueous media , 2014 .

[19]  Yi-Xiang Wang,et al.  N-Heterocyclic Carbene–Palladium(II)–4,5-Dihydrooxazole Complexes: Synthesis and Catalytic Activity toward Amination of Aryl Chlorides , 2014 .

[20]  Lei Zhu,et al.  Structure–activity relationship of N‐heterocyclic carbene–Pd(II)–imidazole complexes in Suzuki–Miyaura coupling between 4‐methoxyphenyl chloride and phenylboronic acid , 2014 .

[21]  S. Bräse,et al.  Metal-catalyzed cross-coupling reactions and more , 2014 .

[22]  Reiner Sebastian Sprick,et al.  (N-heterocyclic carbene)Pd(triethylamine)Cl2as precatalyst for the synthesis of Poly(triarylamine)s , 2013 .

[23]  T. Tu,et al.  Mild Negishi cross-coupling reactions catalyzed by acenaphthoimidazolylidene palladium complexes at low catalyst loadings. , 2013, The Journal of organic chemistry.

[24]  Á. Molnár.  Palladium-catalyzed coupling reactions : practical aspects and future developments , 2013 .

[25]  M. Turner,et al.  Inhibited Catalyst Activation in (N-Heterocyclic carbene)PdCl2(diethylamine) Complexes by Intramolecular Hydrogen Bonding , 2011 .

[26]  Lixiong Shao,et al.  NHC–Pd(II)–Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complexes as efficient catalysts for Suzuki-Miyaura coupling reactions of aryl chlorides , 2011 .

[27]  T. Tu,et al.  A highly efficient precatalyst for amination of aryl chlorides: synthesis, structure and application of a robust acenaphthoimidazolylidene palladium complex. , 2011, Chemical communications.

[28]  M. Turner,et al.  (N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the "throw-away" ligand in catalytic activity , 2011 .

[29]  S. Nolan,et al.  Well-defined N-heterocyclic carbenes-palladium(II) precatalysts for cross-coupling reactions. , 2008, Accounts of chemical research.

[30]  A. Lough,et al.  Easily prepared air- and moisture-stable Pd-NHC (NHC=N-heterocyclic carbene) complexes: a reliable, user-friendly, highly active palladium precatalyst for the Suzuki-Miyaura reaction. , 2006, Chemistry.

[31]  Cory Valente,et al.  A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst. , 2006, Chemistry.

[32]  M. Hird,et al.  Palladium-Catalyzed Cross-Coupling Reactions in the Synthesis of Novel Aromatic Polymers , 2004 .

[33]  S. Nolan,et al.  A general method for the Suzuki-Miyaura cross-coupling of sterically hindered aryl chlorides: synthesis of di- and tri-ortho-substituted biaryls in 2-propanol at room temperature. , 2003, Journal of the American Chemical Society.

[34]  J. Cannon,et al.  Borylation of aryldiazonium ions with N-heterocyclic carbene-palladium catalysts formed without added base. , 2003, Organic letters.

[35]  E. Negishi.  Handbook of organopalladium chemistry for organic synthesis , 2002 .

[36]  S. Nolan,et al.  An air-stable palladium/N-heterocyclic carbene complex and its reactivity in aryl amination. , 2002, Organic letters.