Oriented chlorite lamellae in chromite from the Pedra Branca Mafic-Ultramafic Complex , Ceari , Brazil

Chromite grains in chromitite from the Pedra Branca Mafic-Ultramafic Complex,Cear6, Brazll, contain lamellar inclusions of chlorite oriented parallel to {l I l}. The chromite grains have a core of aluminian chromite and a broad margin of ferrian chromite, formerly called "ferritchromit." The chlorite is a Cr-bearing IIb clinochlore, and the inclusions occur preferentially within "ferritchromit." The orientation relationship is c*.n".,.11[111].n--,., a.nb,i,.ll[rr0].h.o*,,", and b,n",ftlllhh'nl"n,"-,,". This is equivalent to the orientation ofchlorite-olivine intergrowths and corresponds to topotaxial sharing ofa layer of closest-packed anions at the interface between the two phases. Because of the considerable misfit in the strain-free equivalent lattices, the interface structures in both chloritechromite and chlorite-olivine intergrowths may consist of an interlayer sheet (brucite layer) of H bonded to a layer of closest-packed O of the host substrate. Chloritization of the chromite was broadly contemporaneous with the alteration to "ferritchromit."

[1]  M. Fleet,et al.  Partitioning of platinum group elements in the Fe‐O‐S System to 11 GPa and their fractionation in the mantle and meteorites , 1991 .

[2]  M. Tarkian,et al.  Platinum-group minerals in chromitites from the Eastern Rhodope ultramafic complex, Bulgaria , 1991 .

[3]  W. Prochaska,et al.  Solid inclusions in chrome-spinels and platinum group element concentrations from the hochgrössen and kraubath ultramafic massifs (Austria) , 1990 .

[4]  M. Fleet,et al.  Two-phase nickeliferous monosulfide solid solution (mss) in megacrysts from Mount Shasta, California; a natural laboratory for nickel-copper sulfides , 1989 .

[5]  J. Cottin,et al.  Na- Ti- Zr- H2O-rich mineral inclusions indicating postcumulus chrome-spinel dissolution and recrystallization in the Western Laouni mafic intrusion, Algeria , 1987 .

[6]  L. Hulbert,et al.  Textural and compositional features of chromite in the lower and critical zones of the Bushveld Complex south of Potgietersrus , 1985 .

[7]  Mtcnenr E. FuBr Oriented hematite inclusions in sillimanite , 1985 .

[8]  B. Lipin,et al.  Exsolution in metamorphosed chromite from the Red Lodge District, Montana , 1983 .

[9]  Peter C. Jones,et al.  Platinum-group minerals and other solid inclusions in chromite of ophiolitic complexes: Occurrence and petrological significance , 1983 .

[10]  Mlcuenl E. Fr-eBr Orientation of phase and domain boundaries in crystalline solids , 1982 .

[11]  P. L. Gal,et al.  Oxidation reactions in natural Fe–Ti oxide spinels , 1980 .

[12]  G. L. Nord,et al.  Exsolution lamellae in augite and pigeonite; fossil indicators of lattice parameters at high temperature and pressure , 1977 .

[13]  P. Hamlyn Chromite alteration in the Panton Sill, East Kimberley Region, Western Australia , 1975, Mineralogical Magazine.

[14]  G. Ulmer,et al.  Alteration of chromite during serpentinization in the Pennsylvania-Maryland District , 1974 .

[15]  S. W. Bailey,et al.  Chlorite polytypism: i. regular and semi-random one-layer structures , 1962 .

[16]  G. Brown,et al.  A Structural study of iddingsite from New South Wales, Australia , 1959 .

[17]  Samim Ali,et al.  X‐ray study of thermal transformations in some magnesian chlorite minerals , 1950 .

[18]  R. E. Stevens Composition of some chromites of the Western Hemisphere , 1944 .