Practical Approach to Zeolitic Membranes and Coatings: State of the Art, Opportunities, Barriers, and Future Perspectives

In this work, the concept of zeolite (zeolitic) membrane is discussed from a practical perspective. We consider the limitations of the existing synthesis methods and speculate on new opportunities of zeolites and zeolite-type materials such as metal organic frameworks for the production of membranes. This paper focuses on the barriers that need to be eliminated before the commercialization of these membranes becomes attractive. Additional opportunities for commercialization may arise in the shape either of mixed matrix membranes, taking advantage of composites with polymers, or as zeolite coatings useful for a plethora of new applications.

[1]  C. Téllez,et al.  Exfoliated zeolite Nu-6(2) as filler for 6FDA-based copolyimide mixed matrix membranes , 2012 .

[2]  N. Xu,et al.  Pervaporation dehydration of ethylene glycol by NaA zeolite membranes , 2012 .

[3]  Jia Shao,et al.  The preparation of zeolite NaA membranes on the inner surface of hollow fiber supports , 2012 .

[4]  D. Sholl,et al.  Ultem®/ZIF-8 mixed matrix hollow fiber membranes for CO2/N2 separations , 2012 .

[5]  Freek Kapteijn,et al.  Metal–organic frameworks as scaffolds for the encapsulation of active species: state of the art and future perspectives , 2012 .

[6]  S. M. Kuznicki,et al.  Evolving applications of zeolite molecular sieves , 2012 .

[7]  R. Snurr,et al.  Self-Diffusion of Chain Molecules in the Metal-Organic Framework IRMOF-1: Simulation and Experiment. , 2012, The journal of physical chemistry letters.

[8]  Yushan Yan,et al.  Effects of the synthesis hydrogel on the formation of zeolite LTA membranes , 2012 .

[9]  N. Xu,et al.  Ball-milled NaA zeolite seeds with submicron size for growth of NaA zeolite membranes , 2012 .

[10]  Hong-Cai Zhou,et al.  Metal-organic frameworks for separations. , 2012, Chemical reviews.

[11]  Shyam Biswas,et al.  Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. , 2012, Chemical reviews.

[12]  S. Sachdeva,et al.  Current Status of Metal–Organic Framework Membranes for Gas Separations: Promises and Challenges , 2012 .

[13]  C. Wilmer,et al.  Large-scale screening of hypothetical metal-organic frameworks. , 2012, Nature chemistry.

[14]  F. Kapteijn,et al.  Simple modification of macroporous alumina supports for the fabrication of dense NaA zeolite coatings: Interplay of electrostatic and chemical interactions , 2011 .

[15]  W. Xing,et al.  Pretreatment of Isopropanol Solution from Pharmaceutical Industry and Pervaporation Dehydration by NaA Zeolite Membranes , 2011 .

[16]  M. Tsapatsis Toward High-Throughput Zeolite Membranes , 2011, Science.

[17]  J. Santamaría,et al.  Bactericidal effects of different silver-containing materials , 2011 .

[18]  Peyman Z. Moghadam,et al.  p-Xylene-selective metal-organic frameworks: a case of topology-directed selectivity. , 2011, Journal of the American Chemical Society.

[19]  Seda Keskin,et al.  Screening Metal–Organic Framework-Based Mixed-Matrix Membranes for CO2/CH4 Separations , 2011 .

[20]  V. Valtchev,et al.  Co3(HCOO)6 microporous metal-organic framework membrane for separation of CO2/CH4 mixtures. , 2011, Chemistry.

[21]  Zhong Li,et al.  Synthesis, characterization and gas transport properties of MOF-5 membranes , 2011 .

[22]  B. C. Ng,et al.  Recent advances of inorganic fillers in mixed matrix membrane for gas separation , 2011 .

[23]  L. Francis,et al.  Dispersible Exfoliated Zeolite Nanosheets and Their Application as a Selective Membrane , 2011, Science.

[24]  Yi Tang,et al.  Zeolite microspheres with hierarchical structures: formation, mechanism and catalytic performance , 2011 .

[25]  J. Caro,et al.  Are MOF membranes better in gas separation than those made of zeolites , 2011 .

[26]  J. Santamaría,et al.  Zeolite films and membranes. Emerging applications , 2011 .

[27]  N. Xu,et al.  Effect of seeding methods on growth of NaA zeolite membranes , 2011 .

[28]  Z. Lai,et al.  Synthesis of highly c-oriented ZIF-69 membranes by secondary growth and their gas permeation propert , 2011 .

[29]  Freek Kapteijn,et al.  Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures. , 2011, Chemical communications.

[30]  J. Falconer,et al.  Zeolite membranes: microstructure characterization and permeation mechanisms. , 2011, Accounts of chemical research.

[31]  F. Kapteijn,et al.  Understanding the anomalous alkane selectivity of ZIF-7 in the separation of light alkane/alkene mixtures. , 2011, Chemistry.

[32]  Mircea Dincă,et al.  Reductive electrosynthesis of crystalline metal-organic frameworks. , 2011, Journal of the American Chemical Society.

[33]  H. Verweij,et al.  Post-synthesis defect abatement of inorganic membranes for gas separation , 2011 .

[34]  T. Sooknoi,et al.  Selective ethylene-permeable zeolite composite double-layered film for novel modified atmosphere packaging , 2011 .

[35]  Chien-Hung Chen,et al.  Scratch-resistant zeolite anti-reflective coating on glass for solar applications , 2011 .

[36]  Freek Kapteijn,et al.  Sulfation of metal–organic frameworks: Opportunities for acid catalysis and proton conductivity , 2011 .

[37]  W. B. Sediawan,et al.  H 2/CO 2 permeation through a silicalite-1 composite membrane , 2011 .

[38]  R. Scaffaro,et al.  PVC silver zeolite composites with antimicrobial properties , 2011, Journal of Materials Science.

[39]  Christopher W. Jones,et al.  Modified Mesoporous Silica Gas Separation Membranes on Polymeric Hollow Fibers , 2011 .

[40]  J. Caro,et al.  Covalent post-functionalization of zeolitic imidazolate framework ZIF-90 membrane for enhanced hydrogen selectivity. , 2011, Angewandte Chemie.

[41]  W. Jin,et al.  Step-by-step seeding procedure for preparing HKUST-1 membrane on porous α-alumina support. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[42]  A. Feldhoff,et al.  Oriented Zeolitic Imidazolate Framework-8 Membrane with Sharp H2/C3H8 Molecular Sieve Separation , 2011 .

[43]  C. Téllez,et al.  Copolyimide mixed matrix membranes with oriented microporous titanosilicate JDF-L1 sheet particles , 2011 .

[44]  F. Kapteijn,et al.  Complexity behind CO2 capture on NH2-MIL-53(Al). , 2011, Langmuir : the ACS journal of surfaces and colloids.

[45]  Sankar Nair,et al.  Pore size analysis of >250,000 hypothetical zeolites. , 2011, Physical chemistry chemical physics : PCCP.

[46]  R. Krishna,et al.  Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion , 2011 .

[47]  D. Farrusseng,et al.  Guest-induced gate-opening of a zeolite imidazolate framework , 2011 .

[48]  C. Téllez,et al.  Mixed matrix membranes comprising glassy polymers and dispersed mesoporous silica spheres for gas separation , 2011 .

[49]  Hae‐Kwon Jeong,et al.  Isoreticular metal-organic frameworks and their membranes with enhanced crack resistance and moisture stability by surfactant-assisted drying. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[50]  Wantai Yang,et al.  Preparation of pH-sensitive membranes via dopamine-initiated atom transfer radical polymerization , 2011 .

[51]  O. Shekhah,et al.  MOF thin films: existing and future applications. , 2011, Chemical Society reviews.

[52]  W. Jin,et al.  Metal-organic framework membranes fabricated via reactive seeding. , 2011, Chemical communications.

[53]  J. Santamaría,et al.  Antibacterial action of Ag-containing MFI zeolite at low Ag loadings. , 2011, Chemical communications.

[54]  D. Farrusseng,et al.  Facile synthesis of an ultramicroporous MOF tubular membrane with selectivity towards CO2 , 2011 .

[55]  D. Ruthven Molecular Sieve Separations , 2011 .

[56]  F. Kapteijn,et al.  Isobutane dehydrogenation in a DD3R zeolite membrane reactor , 2011 .

[57]  Y. Sekine,et al.  Review on Prospects for Energy Saving in Distillation Process with Microporous Membranes , 2011 .

[58]  W. Jin,et al.  A simple method for healing nonzeolitic pores of MFI membranes by hydrolysis of silanes , 2011 .

[59]  Christopher W. Jones,et al.  A high-performance gas-separation membrane containing submicrometer-sized metal-organic framework crystals. , 2010, Angewandte Chemie.

[60]  F. Kapteijn,et al.  Ethane/ethene separation turned on its head: selective ethane adsorption on the metal-organic framework ZIF-7 through a gate-opening mechanism. , 2010, Journal of the American Chemical Society.

[61]  A. Ismail,et al.  Performance studies of mixed matrix membranes for gas separation: A review , 2010 .

[62]  J. Caro,et al.  Novel MOF‐Membrane for Molecular Sieving Predicted by IR‐Diffusion Studies and Molecular Modeling , 2010, Advanced materials.

[63]  A. Stein,et al.  High-performance randomly oriented zeolite membranes using brittle seeds and rapid thermal processing. , 2010, Angewandte Chemie.

[64]  J. Dalmon,et al.  Separation and isomerization of xylenes using zeolite membranes: a short overview , 2010 .

[65]  J. Caro,et al.  Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization. , 2010, Journal of the American Chemical Society.

[66]  Hong-xin Li,et al.  The Uses and Challenges of Zeolites in Automotive Applications , 2010 .

[67]  R. Masel,et al.  Effects of molecular sieving and electrostatic enhancement in the adsorption of organic compounds on the zeolitic imidazolate framework ZIF-8. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[68]  Hae‐Kwon Jeong,et al.  Synthesis of zeolitic imidazolate framework films and membranes with controlled microstructures. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[69]  J. Caro,et al.  Controllable Synthesis of Metal–Organic Frameworks: From MOF Nanorods to Oriented MOF Membranes , 2010, Advanced materials.

[70]  J. Caro,et al.  Cationic Polymer Used to Capture Zeolite Precursor Particles for the Facile Synthesis of Oriented Zeolite LTA Molecular Sieve Membrane , 2010 .

[71]  J. Caro,et al.  Molecular-sieve membrane with hydrogen permselectivity: ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker. , 2010, Angewandte Chemie.

[72]  F. Kapteijn,et al.  High temperature permeation and separation characteristics of an all-silica DDR zeolite membrane , 2010 .

[73]  F. Kapteijn,et al.  Performance of hydroxy sodalite membranes as absolute water selective materials under acidic and basic conditions , 2010 .

[74]  Hiroshi Uji-i,et al.  Direct Patterning of Oriented Metal–Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor Solutions , 2010, Advanced materials.

[75]  C. Serre,et al.  Explanation of the adsorption of polar vapors in the highly flexible metal organic framework MIL-53(Cr). , 2010, Journal of the American Chemical Society.

[76]  Abass A. Olajire,et al.  CO2 capture and separation technologies for end-of-pipe applications – A review , 2010 .

[77]  Fangyi Liang,et al.  Zeolitic imidazolate framework ZIF-7 based molecular sieve membrane for hydrogen separation , 2010 .

[78]  Sankar Nair,et al.  Efficient calculation of diffusion limitations in metal organic framework materials: a tool for identifying materials for kinetic separations. , 2010, Journal of the American Chemical Society.

[79]  Hae‐Kwon Jeong,et al.  HKUST-1 membranes on porous supports using secondary growth , 2010 .

[80]  Easir A Khan,et al.  Synthesis and characterization of ZIF-69 membranes and separation for CO2/CO mixture , 2010 .

[81]  Mark E. Davis,et al.  Pure-silica LTA, CHA, STT, ITW, and -SVR thin films and powders for low-k applications , 2010 .

[82]  J. Falconer,et al.  Scale-up of SAPO-34 membranes for CO2/CH4 separation , 2010 .

[83]  Yi Zhang,et al.  Hydroformylation of 1-Hexene on Silicalite-1 Zeolite Membrane Coated Pd–Co/A.C. Catalyst , 2010 .

[84]  A. Corma,et al.  Engineering metal organic frameworks for heterogeneous catalysis. , 2010, Chemical reviews.

[85]  Frank Steinbach,et al.  Preparation and separation properties of LTA membranes by using 3-aminopropyltriethoxysilane as covalent linker , 2010 .

[86]  Mark E. Davis,et al.  Pure-silica zeolite thin films by vapor phase transport of fluoride for low-k applications , 2010 .

[87]  Freek Kapteijn,et al.  Metal-organic framework membranes--high potential, bright future? , 2010, Angewandte Chemie.

[88]  Rui Cai,et al.  Zeolite thin films: from computer chips to space stations. , 2010, Accounts of chemical research.

[89]  Yi Zhang,et al.  Silicalite-1 membrane encapsulated Rh/activated-carbon catalyst for hydroformylation of 1-hexene with high selectivity to normal aldehyde , 2010 .

[90]  Gérard Férey,et al.  Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging. , 2010, Nature materials.

[91]  M. Carreon,et al.  Highly permeable zeolite imidazolate framework-8 membranes for CO2/CH4 separation. , 2010, Journal of the American Chemical Society.

[92]  Armin Feldhoff,et al.  Molecular sieve membrane: supported metal-organic framework with high hydrogen selectivity. , 2010, Angewandte Chemie.

[93]  Fernando Etayo,et al.  Exfoliated Titanosilicate Material UZAR‐S1 Obtained from JDF‐L1 , 2010 .

[94]  Freek Kapteijn,et al.  Building MOF bottles around phosphotungstic acid ships: One-pot synthesis of bi-functional polyoxometalate-MIL-101 catalysts , 2010 .

[95]  S. Basu,et al.  Solvent resistant nanofiltration (SRNF) membranes based on metal-organic frameworks , 2009 .

[96]  Yushan Yan,et al.  High-performance zeolite NaA membranes on polymer-zeolite composite hollow fiber supports. , 2009, Journal of the American Chemical Society.

[97]  Jürgen Caro,et al.  Zeolitic imidazolate framework membrane with molecular sieving properties by microwave-assisted solvothermal synthesis. , 2009, Journal of the American Chemical Society.

[98]  A. Benin,et al.  Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration. , 2009, Journal of the American Chemical Society.

[99]  Yushan Yan,et al.  Biocompatibility of corrosion-resistant zeolite coatings for titanium alloy biomedical implants. , 2009, Acta biomaterialia.

[100]  O. Terasaki,et al.  Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts , 2009, Nature.

[101]  R. Ranjan,et al.  Microporous Metal Organic Framework Membrane on Porous Support Using the Seeded Growth Method , 2009 .

[102]  V. Edwards-Jones The benefits of silver in hygiene, personal care and healthcare , 2009, Letters in applied microbiology.

[103]  L. F. Gorup,et al.  International Journal of Antimicrobial Agents the Growing Importance of Materials That Prevent Microbial Adhesion: Antimicrobial Effect of Medical Devices Containing Silver , 2022 .

[104]  R. Masel,et al.  Grain Boundary Defect Elimination in a Zeolite Membrane by Rapid Thermal Processing , 2009, Science.

[105]  C. Téllez,et al.  Mesoporous silica sphere-polysulfone mixed matrix membranes for gas separation. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[106]  Enrico Drioli,et al.  Membrane Gas Separation: A Review/State of the Art , 2009 .

[107]  O. Shekhah,et al.  Thin films of metal-organic frameworks. , 2009, Chemical Society reviews.

[108]  Mircea Dincă,et al.  Hydrogen storage in metal-organic frameworks. , 2009, Chemical Society reviews.

[109]  Freek Kapteijn,et al.  An amine-functionalized MIL-53 metal-organic framework with large separation power for CO2 and CH4. , 2009, Journal of the American Chemical Society.

[110]  Freek Kapteijn,et al.  Detemplation of DDR type zeolites by ozonication , 2009 .

[111]  Yushan Yan,et al.  Initial bacterial deposition on bare and zeolite-coated aluminum alloy and stainless steel. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[112]  Easir A Khan,et al.  Synthesis of continuous MOF-5 membranes on porous α-alumina substrates , 2009 .

[113]  S. Qiu,et al.  "Twin copper source" growth of metal-organic framework membrane: Cu(3)(BTC)(2) with high permeability and selectivity for recycling H(2). , 2009, Journal of the American Chemical Society.

[114]  F. Kapteijn,et al.  Amino-based metal-organic frameworks as stable, highly active basic catalysts , 2009 .

[115]  Xingang Li One-step Synthesis of H-beta Zeolite Enwrapped Co/Al2O3 Fischer-Tropsch Catalyst with High Spatial Selectivity , 2009 .

[116]  S. Bhatia,et al.  Membrane separation process—Pervaporation through zeolite membrane , 2008 .

[117]  J. Caro,et al.  Zeolite membranes – Recent developments and progress , 2008 .

[118]  T. Nakane,et al.  Separation of ethanol/ethyl acetate mixture by pervaporation at 100–130 °C through NaY zeolite membrane for industrial purpose , 2008 .

[119]  Shiro Ikeda,et al.  Dehydrating performance of commercial LTA zeolite membranes and application to fuel grade bio-ethanol production by hybrid distillation/vapor permeation process , 2008 .

[120]  Yushan Yan,et al.  Corrosion-Resistant Zeolite Coatings , 2008 .

[121]  Robert Lee,et al.  Influence of counter ions on the reverse osmosis through MFI zeolite membranes: implications for produced water desalination , 2008 .

[122]  F. Kapteijn,et al.  Dehydration performance of a hydrophobic DD3R zeolite membrane , 2008 .

[123]  F. Kapteijn,et al.  Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on α-alumina , 2008 .

[124]  L. Robeson,et al.  The upper bound revisited , 2008 .

[125]  J. Hao,et al.  Upgrading low-quality natural gas with H2S- and CO2-selective polymer membranes: Part II. Process design, economics, and sensitivity study of membrane stages with recycle streams , 2008 .

[126]  T. Nakane,et al.  Mass-production of tubular NaY zeolite membranes for industrial purpose and their application to ethanol dehydration by vapor permeation , 2008 .

[127]  Freek Kapteijn,et al.  Separation and permeation characteristics of a DD3R zeolite membrane , 2008 .

[128]  Z. Lai,et al.  Fabrication and gas separation properties of polybenzimidazole (PBI)/nanoporous silicates hybrid membranes , 2008 .

[129]  C. Téllez,et al.  Preparation of ITQ-29 (Al-free zeolite A) membranes , 2008 .

[130]  C. Williams,et al.  Separating nitrogen/methane on zeolite-like molecular sieves , 2008 .

[131]  T. Nakane,et al.  Synthesis of industrial scale NaY zeolite membranes and ethanol permeating performance in pervaporation and vapor permeation up to 130 °C and 570 kPa , 2008 .

[132]  G. Aguilar,et al.  Hydrophilic Zeolite Coatings for Improved Heat Transfer: A Quantitative Analysis , 2008 .

[133]  Michael O'Keeffe,et al.  High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture , 2008, Science.

[134]  K. P. Möller,et al.  Water/hydrogen/hexane multicomponent selectivity of thin MFI membranes with different Si/Al ratios , 2008 .

[135]  Yushan Yan,et al.  Hydrophilic and antimicrobial low-silica-zeolite LTA and high-silica-zeolite MFI hybrid coatings on aluminum alloys , 2008 .

[136]  Zhongwei Chen,et al.  Ionothermal synthesis of oriented zeolite AEL films and their application as corrosion-resistant coatings. , 2008, Angewandte Chemie.

[137]  W. Oh,et al.  Layered silicates by swelling of AMH-3 and nanocomposite membranes. , 2008, Angewandte Chemie.

[138]  Junlan Wang,et al.  Hydrophobicity-dependent friction and wear of spin-on zeolite thin films , 2008 .

[139]  R. Pal Permeation models for mixed matrix membranes. , 2008, Journal of colloid and interface science.

[140]  K. Nakanishi,et al.  Hydrogen-permeable membranes composed of zeolite nano-blocks , 2007 .

[141]  I. Ortiz,et al.  Pervaporation Technology for the Dehydration of Solvents and Raw Materials in the Process Industry , 2007 .

[142]  Tracy Q. Gardner,et al.  Enhanced flux through double-sided zeolite membranes , 2007 .

[143]  T. Nenoff,et al.  Membranes for hydrogen separation. , 2007, Chemical reviews.

[144]  Yi Tang,et al.  Novel, efficient hollow zeolitically microcapsulized noble metal catalysts , 2007 .

[145]  Shuji Himeno,et al.  Synthesis and Permeation Properties of a DDR-Type Zeolite Membrane for Separation of CO2/CH4 Gaseous Mixtures , 2007 .

[146]  T. Nakane,et al.  A high reproducible fabrication method for industrial production of high flux NaA zeolite membrane , 2007 .

[147]  C. Téllez,et al.  Study on the reproducibility of mordenite tubular membranes used in the dehydration of ethanol , 2007 .

[148]  Brian F. Towler,et al.  Polymer-inorganic nanocomposite membranes for gas separation , 2007 .

[149]  K. Gademann Cyanobacterial Natural Products for the Inhibition of Biofilm Formation and Biofouling , 2007 .

[150]  C. Deyá,et al.  A new pigment for smart anticorrosive coatings , 2007 .

[151]  R. Fischer,et al.  Selective Growth and MOCVD Loading of Small Single Crystals of MOF-5 at Alumina and Silica Surfaces Modified with Organic Self-Assembled Monolayers† , 2007 .

[152]  Yi Li,et al.  MIXED MATRIX MEMBRANES (MMMS) COMPRISING ORGANIC POLYMERS WITH DISPERSED INORGANIC FILLERS FOR GAS SEPARATION , 2007 .

[153]  William J. Koros,et al.  Mixed matrix hollow fiber membranes made with modified HSSZ-13 zeolite in polyetherimide polymer matrix for gas separation , 2007 .

[154]  Deborah J. Jones,et al.  Oriented Crystallisation on Supports and Anisotropic Mass Transport of the Metal‐Organic Framework Manganese Formate , 2007 .

[155]  J. Dalmon,et al.  Nanocomposite MFI-alumina membranes via pore-plugging synthesis , 2008 .

[156]  Woo Nyon Kim,et al.  Fabrication and characterization of multi-walled carbon nanotubes/polymer blend membranes , 2006 .

[157]  N. Nishiyama,et al.  Selective formation of para-xylene over H-ZSM-5 coated with polycrystalline silicalite crystals , 2006 .

[158]  J. Dalmon,et al.  Nanocomposite MFI-alumina membranes via pore-plugging synthesis. Preparation and morphological characterisation , 2006 .

[159]  E. Miró,et al.  Xylene isomerization in a membrane reactor Part II. Simulation of an industrial reactor , 2006 .

[160]  V. Valtchev,et al.  Factors Controlling the Formation of Core−Shell Zeolite−Zeolite Composites , 2006 .

[161]  Yushan Yan,et al.  Corrosion resistant high-silica-zeolite MFI coating One general solution formulation for aluminum alloy AA-2024-T3; AA-5052-H32; AA-6061-T4; and AA-7075-T6 , 2006 .

[162]  N. Hanzawa,et al.  New antiaxillary odour deodorant made with antimicrobial Ag‐zeolite (silver‐exchanged zeolite) , 2006, International journal of cosmetic science.

[163]  Michael O’Keeffe,et al.  Exceptional chemical and thermal stability of zeolitic imidazolate frameworks , 2006, Proceedings of the National Academy of Sciences.

[164]  Mark E. Davis,et al.  Mechanical and dielectric properties of pure-silica-zeolite low-k materials. , 2006, Angewandte Chemie.

[165]  Dianne E. Wiley,et al.  Comparison of CO2 separation options for geo-sequestration: are membranes competitive? , 2006 .

[166]  V. Valtchev,et al.  Bi-phase MOR/MFI-type zeolite core–shell composite , 2006 .

[167]  Freek Kapteijn,et al.  Zeolite based films, membranes and membrane reactors: Progress and prospects , 2006 .

[168]  Chris Dotremont,et al.  Performance of Mitsui NaA type zeolite membranes for the dehydration of organic solvents in comparison with commercial polymeric pervaporation membranes , 2006 .

[169]  Wilfred Chen,et al.  Durability of Hydrophilic and Antimicrobial Zeolite Coatings under Water Immersion , 2006 .

[170]  A. Corma,et al.  Amorphous microporous molecular sieves with different pore dimensions and topologies: Synthesis, characterization and catalytic activity , 2006 .

[171]  C. Téllez,et al.  The use of post-synthetic treatments to improve the pervaporation performance of mordenite membranes , 2006 .

[172]  Jungkyu Choi,et al.  Uniformly a-oriented MFI zeolite films by secondary growth. , 2006, Angewandte Chemie.

[173]  V. Valtchev,et al.  Core–Shell Zeolite Microcomposites , 2005 .

[174]  T. Melin,et al.  Performance evaluation of microporous inorganic membranes in the dehydration of industrial solvents , 2005 .

[175]  C. Wöll,et al.  Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111). , 2005, Journal of the American Chemical Society.

[176]  J. Hedlund,et al.  Permeation of H2, N2, He and SF6 in real MFI membranes , 2005 .

[177]  F. Kapteijn,et al.  Silicalite-1 coating on Pt/TiO2 particles by a two-step hydrothermal synthesis , 2005 .

[178]  N. Nishiyama,et al.  Single Crystals of ZSM‐5/Silicalite Composites , 2005 .

[179]  J. Caro,et al.  Zeolite Membranes: From the Laboratory Scale to Technical Applications , 2005 .

[180]  C. Téllez,et al.  A new titanosilicate umbite membrane for the separation of H2. , 2005, Chemical communications.

[181]  J. C. Jansen,et al.  Technical and economical evaluation of a zeolite membrane based heptane hydroisomerization process , 2005 .

[182]  Mark E. Davis,et al.  Zeolite synthesis using degradable structure-directing agents and pore-filling agents. , 2005, The journal of physical chemistry. B.

[183]  D. Beving,et al.  Hydrophilic and Antimicrobial Zeolite Coatings for Gravity‐Independent Water Separation , 2005 .

[184]  I. Ortiz,et al.  Pervaporative recovery of acetic acid from an acetylation industrial effluent using commercial membranes , 2005 .

[185]  T. E. Cloete,et al.  Biofouling and Biocorrosion in Industrial Water Systems , 2005, Critical reviews in microbiology.

[186]  J. Falconer,et al.  Fundamentals and applications of pervaporation through zeolite membranes , 2004 .

[187]  King Lun Yeung,et al.  Low-temperature ozone treatment for organic template removal from zeolite membrane , 2004 .

[188]  J. Santamaría,et al.  Preparation of Silicalite-1 Micromembranes on Laser-Perforated Stainless Steel Sheets , 2004 .

[189]  S. Nair,et al.  Fabrication of polymer/selective-flake nanocomposite membranes and their use in gas separation , 2004 .

[190]  Z. Lai,et al.  Siliceous ZSM‐5 Membranes by Secondary Growth of b‐Oriented Seed Layers , 2004 .

[191]  Y. Akagawa,et al.  Effect of saliva on an antimicrobial tissue conditioner containing silver-zeolite. , 2004, Journal of oral rehabilitation.

[192]  R. Dittmeyer,et al.  A Review of Catalytic Membrane Layers for Gas/Liquid Reactions , 2004 .

[193]  J. Santamaría,et al.  State-of-the-Art in Zeolite Membrane Reactors , 2004 .

[194]  M. Smaïhi,et al.  Template extraction from surface-functionalised zeolite β nanoparticles , 2004 .

[195]  T. Tomita,et al.  Gas separation characteristics of DDR type zeolite membrane , 2004 .

[196]  W. Koros,et al.  Hybrid membrane materials comprising organic polymers with rigid dispersed phases , 2004 .

[197]  Weidong Zhu,et al.  Reactant-Selective Hydrogenation over Composite Silicalite-1-Coated Pt/TiO2 Particles , 2004 .

[198]  J. Caro Zeolites and mesoporous materials as advanced functional material , 2004 .

[199]  S. Pillai,et al.  Field Evaluation of the Effectiveness of Surfactant Modified Zeolite and Iron‐Oxide‐Coated Sand for Removing Viruses and Bacteria from Ground Water , 2003 .

[200]  E. Drioli,et al.  Permeation properties of a thin silicalite-1 (MFI) membrane , 2003 .

[201]  I. Ortiz,et al.  Pervaporative dehydration of industrial solvents using a zeolite NaA commercial membrane , 2003 .

[202]  M. Menéndez,et al.  On the effect of morphological features on the properties of MFI zeolite membranes , 2003 .

[203]  Karen Maex,et al.  Low dielectric constant materials for microelectronics , 2003 .

[204]  O. Terasaki,et al.  Microstructural Optimization of a Zeolite Membrane for Organic Vapor Separation , 2003, Science.

[205]  Stephen J. Miller,et al.  Mixed matrix membranes using carbon molecular sieves: II. Modeling permeation behavior , 2003 .

[206]  William J. Koros,et al.  Mixed matrix membranes using carbon molecular sieves: I. Preparation and experimental results , 2003 .

[207]  R. Townsin The Ship Hull Fouling Penalty , 2003, Biofouling.

[208]  Y Goto,et al.  Behavior of nuisance mussel, Limnoperna fortunei, in water supply facilities. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[209]  Stefania Quintavalla,et al.  Antimicrobial food packaging in meat industry. , 2002, Meat science.

[210]  R. Mahajan,et al.  Challenges in forming successful mixed matrix membranes with rigid polymeric materials , 2002 .

[211]  Yoshihiro Inoue,et al.  Bactericidal activity of Ag-zeolite mediated by reactive oxygen species under aerated conditions. , 2002, Journal of inorganic biochemistry.

[212]  G. W. Meindersma,et al.  Economical feasibility of zeolite membranes for industrial scale separations of aromatic hydrocarbons , 2002 .

[213]  Kang Li,et al.  Preparation and characterization of high-flux polysulfone hollow fibre gas separation membranes , 2002 .

[214]  J. Hedlund,et al.  High-flux MFI membranes , 2002 .

[215]  A. J. Hill,et al.  Ultrapermeable, Reverse-Selective Nanocomposite Membranes , 2002, Science.

[216]  L. M. F. D. Santos,et al.  Dehydration of water/t-butanol mixtures by pervaporation: comparative study of commercially available polymeric, microporous silica and zeolite membranes , 2002 .

[217]  R. Baker Future directions of membrane gas separation technology , 2002 .

[218]  R. Mahajan,et al.  Mixed Matrix Membrane Materials: An Answer to the Challenges Faced by Membrane Based Gas Separations Today? , 2002 .

[219]  Christopher W. Jones,et al.  Tailoring molecular sieve properties during SDA removal via solvent extraction , 2001 .

[220]  K. Yeung,et al.  Engineering the shape of zeolite crystal grain in MFI membranes and their effects on the gas permeation properties , 2001 .

[221]  H. Kita,et al.  The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane , 2001 .

[222]  Huanting Wang,et al.  Pure Silica Zeolite Films as Low‐k Dielectrics by Spin‐On of Nanoparticle Suspensions , 2001 .

[223]  Miguel Menéndez,et al.  Separation of hydrocarbons from natural gas using silicalite membranes , 2001 .

[224]  J. Ferraris,et al.  Gas Permeability Properties of Polysulfone Membranes Containing the Mesoporous Molecular Sieve MCM-41 , 2001 .

[225]  D. Creaser,et al.  Preparation and evaluation of thin ZSM-5 membranes synthesized in the absence of organic template molecules , 2001 .

[226]  Huanting Wang,et al.  Pure‐Silica Zeolite Low‐k Dielectric Thin Films , 2001 .

[227]  B. Louis,et al.  Synthesis of ZSM-5 coatings on stainless steel grids and their catalytic performance for partial oxidation of benzene by N2O , 2001 .

[228]  J. Falconer,et al.  Aromatic Permeation through Crystalline Molecular Sieve Membranes , 2001 .

[229]  George Xomeritakis,et al.  Separation of xylene isomer vapors with oriented MFI membranes made by seeded growth , 2001 .

[230]  J. Falconer,et al.  Isomorphous substitution of Al, Fe, B, and Ge into MFI-zeolite membranes , 2000 .

[231]  T. Matsufuji Separation of butane and xylene isomers with MFI-type zeolitic membrane synthesized by a vapor-phase transport method , 2000 .

[232]  Kyung Byung Yoon,et al.  Facile Assembly of Zeolite Monolayers on Glass, Silica, Alumina, and Other Zeolites Using 3‐Halopropylsilyl Reagents as Covalent Linkers , 2000 .

[233]  Jürgen Caro,et al.  Zeolite membranes – state of their development and perspective , 2000 .

[234]  R. Mahajan,et al.  Factors Controlling Successful Formation of Mixed-Matrix Gas Separation Materials , 2000 .

[235]  Y. S. Lin,et al.  Template-removal-associated microstructural development of porous-ceramic-supported MFI zeolite membranes , 2000 .

[236]  J. Dalmon,et al.  Experimental study and numerical simulation of hydrogen/isobutane permeation and separation using MFI-zeolite membrane reactor , 2000 .

[237]  K. Yeung,et al.  The role of surface chemistry in zeolite membrane formation , 2000 .

[238]  S. Nakao,et al.  Preparation of zeolite A and faujasite membranes from a clear solution , 1999 .

[239]  J. Caro,et al.  ZSM-5 membranes synthesized without organic templates using a seeding technique , 1999 .

[240]  F. D. De Schryver,et al.  Characterization of nanosized material extracted from clear suspensions for MFI zeolite synthesis , 1999 .

[241]  G. Clet,et al.  Synthesis of a Zeolite Y Coating on Stainless Steel Support , 1999 .

[242]  F. Kapteijn,et al.  Application of a silicalite-1 membrane reactor in metathesis reactions , 1999 .

[243]  J. Santamaría,et al.  Separations Using Zeolite Membranes , 1999 .

[244]  S. Nair,et al.  Zeolite-β grown epitaxially on SSZ-31 nanofibers , 1999 .

[245]  R. Noble,et al.  Synthesis and Permeation Properties of SAPO-34 Tubular Membranes , 1998 .

[246]  G. Férey,et al.  Hybrid open frameworks (MIL-n). Part 3 Crystal structures of the HT and LT forms of MIL-7 : a new vanadium propylenediphosphonate with an open-framework. Influence of the synthesis temperature on the oxidation state of vanadium within the same structural type , 1998 .

[247]  William J. Koros,et al.  Tailoring mixed matrix composite membranes for gas separations , 1997 .

[248]  S. Nakao,et al.  Silicalite Membranes Modified by Counterdiffusion CVD Technique , 1997 .

[249]  J. Falconer,et al.  Characterization and permeation properties of ZSM‐5 tubular membranes , 1997 .

[250]  Takahiro Kuroda,et al.  Formation of a Y-Type Zeolite Membrane on a Porous α-Alumina Tube for Gas Separation , 1997 .

[251]  M. Vallet‐Regí,et al.  A new microporous polymorph of silica isomorphous to zeolite MCM-22 , 1996 .

[252]  Freek Kapteijn,et al.  Permeation characteristics of a metal-supported silicalite-1 zeolite membrane , 1996 .

[253]  M. Tsapatsis,et al.  Preparation of an asymmetric zeolite L film , 1996 .

[254]  Thomas Bein,et al.  Synthesis and Applications of Molecular Sieve Layers and Membranes , 1996 .

[255]  J. Falconer,et al.  Separation of Hydrocarbon Isomer Vapors with Silicalite Zeolite Membranes , 1996 .

[256]  O. Yaghi,et al.  Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels , 1995 .

[257]  S. Yamazaki,et al.  Synthesis of an A-type zeolite membrane on silicon oxide film-silicon, quartz plate and quartz fiber filter , 1995 .

[258]  Stuart R. Batten,et al.  Two Interpenetrating 3D Networks Which Generate Spacious Sealed-Off Compartments Enclosing of the Order of 20 Solvent Molecules in the Structures of Zn(CN)(NO3)(tpt)2/3.cntdot.solv (tpt = 2,4,6-tri(4-pyridyl)-1,3,5-triazine, solv = .apprx.3/4C2H2Cl4.cntdot.3/4CH3OH or .apprx.3/2CHCl3.cntdot.1/3CH3OH , 1995 .

[259]  Mark E. Davis,et al.  Preparation of Zeolite ZSM-5 Membranes by In-Situ Crystallization on Porous α-Al_2O_3 , 1995 .

[260]  H. Kita,et al.  Synthesis of a zeolite NaA membrane for pervaporation of water/organic liquid mixtures , 1995 .

[261]  T. M. Gür Permselectivity of zeolite filled polysulfone gas separation membranes , 1994 .

[262]  J. Falconer,et al.  Ceramic-zeolite composite membranes and their application for separation of vapor/gas mixtures , 1994 .

[263]  William J. Koros,et al.  Membrane-based gas separation , 1993 .

[264]  K. Peinemann,et al.  Ceramic zeolite composite membranes.: Preparation, characterization and gas permeation , 1993 .

[265]  C. A. Smolders,et al.  Adsorbent filled membranes for gas separation. Part 1. Improvement of the gas separation properties of polymeric membranes by incorporation of microporous adsorbents , 1993 .

[266]  S. Kawata,et al.  Synthesis and crystal structures of novel copper(I) co-ordination polymers and a hexacopper(I) cluster of quinoline-2-thione , 1993 .

[267]  W. Koros,et al.  Controlled Permeability Polymer Membranes , 1992 .

[268]  M. D. Exter,et al.  Synthesis and characterization of zeolite (MFI) membranes on porous ceramic supports , 1992 .

[269]  L. Robeson,et al.  Correlation of separation factor versus permeability for polymeric membranes , 1991 .

[270]  S. Kitagawa,et al.  Synthesis and crystal structures of novel one-dimensional polymers, [{M(bpen)X}∞][M = CuI, X = PF6–; M = AgI, X = ClO4–; bpen =trans-1,2-bis(2-pyridyl)ethylene] and [{Cu(bpen)(CO)(CH3CN)(PF6)}∞] , 1991 .

[271]  R. Robson,et al.  Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and Cu , 1990 .

[272]  F. Toda,et al.  Separation of water–alcohol mixtures by permeation through a zeolite membrane on porous glass , 1989 .

[273]  E. Tomic Thermal stability of coordination polymers , 1965 .

[274]  Sidney Loeb,et al.  Sea Water Demineralization by Means of an Osmotic Membrane , 1963 .

[275]  E. S. Roth,et al.  COORDINATION POLYMERS WITH INORGANIC BACKBONES FORMED BY DOUBLE-BRIDGING OF TETRAHEDRAL ELEMENTS. , 1962 .

[276]  M. Kubo,et al.  Polymer molecules involving coordination links in the crystals of cupric oxalate and related compounds , 1960 .

[277]  A. Berlin,et al.  POLYMERIC CHELATE COMPOUNDS , 1960 .

[278]  Yoshihiko Saito,et al.  The Crystal Structure of Bis(adiponitrilo)copper(I) Nitrate , 1959 .

[279]  F. W. Knobloch,et al.  Coordination polymers of copper(II) prepared at liquid-liquid interfaces , 1959 .