Managing abnormal operation through process integration and cogeneration systems

Flaring is a common industrial practice that leads to substantial greenhouse gas emissions, health problems, and economic losses. When the causes, magnitudes, and frequency of flaring are properly understood and incorporated into the design and operation of the industrial plants, significant reduction in flaring can be achieved. In this paper, a process integration approach is presented to retrofit the process design to account for flaring and to consider the use of process cogeneration to mitigate flaring while gaining economic and environmental benefits. It is based on simultaneous design and operational optimization where key flaring sources, causes, and consequences of process upsets are identified then included in the energy profile of the process to design a combined heat and power system with special emphasis on discontinuous sources due to process upset. Environmental and economic benefits are weighed against the cost of process retrofitting. A base case study for an ethylene process is used to illustrate the applicability of the proposed approach and to evaluate the process performance under varying abnormal situation scenarios.

[1]  Mohammad Reza Rahimpour,et al.  The major sources of gas flaring and air contamination in the natural gas processing plants: A case study , 2013 .

[2]  K. M. Sundaram,et al.  Modeling of thermal cracking kinetics—II: Cracking of iso-butane, of n-butane and of mixtures ethane—propane—n-butane , 1977 .

[3]  Qiang Xu,et al.  Simultaneous study on energy consumption and emission generation for an ethylene plant under different start-up strategies , 2013, Comput. Chem. Eng..

[4]  Hugo A. Jakobsen,et al.  Kinetic Analysis and Upper Bound of Ethylene Yield of Gas Phase Oxidative Dehydrogenation of Ethane to Ethylene , 2012 .

[5]  Mahmoud M. El-Halwagi,et al.  Targeting cogeneration and waste utilization through process integration , 2009 .

[6]  O. Deneux,et al.  Establishment of a Model for a Combined Heat and Power Plant with ThermosysPro Library , 2013, ANT/SEIT.

[7]  Ola Olsvik,et al.  Pyrolysis of natural gas: chemistry and process concepts , 1995 .

[8]  Mahmoud El-Halwagi,et al.  An algorithmic approach to the optimization of process cogeneration , 2009 .

[9]  Qiang Xu,et al.  Emission Source Characterization for Proactive Flare Minimization during Ethylene Plant Start-ups , 2010 .

[10]  Mahmoud M. El-Halwagi,et al.  Sustainable Design Through Process Integration: Fundamentals and Applications to Industrial Pollution Prevention, Resource Conservation, and Profitability Enhancement , 2011 .

[11]  S. Narayanan,et al.  Thermal Cracking of Ethane and Ethane-Propane Mixtures , 1976 .

[12]  Mahmoud M. El-Halwagi,et al.  Multi-objective optimization of process cogeneration systems with economic, environmental, and social tradeoffs , 2012, Clean Technologies and Environmental Policy.

[13]  Xiongtao Yang,et al.  Flare Minimization Strategy for Ethylene Plants , 2010 .

[14]  Mohammad Reza Rahimpour,et al.  Modeling of ethane pyrolysis process: A study on effects of steam and carbon dioxide on ethylene and hydrogen productions , 2013 .

[15]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .

[16]  Peter J.T. Verheijen,et al.  A kinetic modelling study of ethane cracking for optimal ethylene yield , 2013 .