This paper discusses a method of measuring transient potential response of a corrosion interface to a small galvanostatic pulse perturbation for a rapid assessment of the corrosion rate of reinforcing steel in concrete structures. Measurements were taken on 100 mm sections of steel bars which were subjected to a wide range of corrosion conditions, from passive steel to actively corroding steel. The duration of the applied galvanostatic pulse was varied between 5s and 180s, and the lateral distance of the point of measurement on the steel bar varied from zero to 400 mm. The result of the electrochemical transient response was investigated using a typical sampling rate of 1 kHz. Analysis of the transient potential response to the applied galvanostatic pulse has enabled the separation of equivalent electronic components so that the components of a series of capacitances and resistances, whose values are dependent on the corrosion condition of the reinforcing steel, could be isolated. The corrosion rate was calculated from a summation of the separate resistive components, which were associated with the corrosion interface, and was compared with the corrosion rate obtained from linear polarization resistance (LPR) method. The results show that the galvanostatic pulse transient technique enables the components of the polarization resistance to be evaluated separately so as to give more reliable corrosion rate values than those obtained from the LPR method. Additionally, this paper shows how the galvanostatic pulse transient response technique can be implemented. An appropriate measurement time for passive and actively corroding reinforcing steel is suggested for the galvanostatic pulse transient response measurements in the field site.
[1]
Steve Millard,et al.
Practical field measurement of reinforcement corrosion in concrete using linear polarisation methods
,
1992
.
[2]
Carmen Andrade,et al.
Corrosion rate monitoring in the laboratory and on-site
,
1996
.
[3]
Steve Millard,et al.
ELECTROCHEMICAL TECHNIQUES FOR CORROSION ASSESSMENT OF REINFORCED CONCRETE STRUCTURES.
,
1999
.
[4]
S. Sathiyanarayanan,et al.
Corrosion monitoring of steel in concrete by galvanostatic pulse technique
,
2006
.
[5]
J. Sykes,et al.
A GALVANOSTATIC PULSE TECHNIQUE FOR INVESTIGATION OF STEEL CORROSION IN CONCRETE
,
1989
.
[6]
M. Stern,et al.
Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves
,
1957
.
[7]
J. Randles.
Kinetics of rapid electrode reactions
,
1947
.
[8]
J. M. Miranda,et al.
Considerations on reproducibility of potential and corrosion rate measurements in reinforced concrete
,
2004
.
[9]
Ns Berke,et al.
Techniques to Assess the Corrosion Activity of Steel Reinforced Concrete Structures
,
1996
.
[10]
J. Broomfield.
Corrosion of Steel in Concrete: Understanding, investigation and repair
,
1996
.
[11]
Steve Millard,et al.
Use of galvanostatic pulse measurements on active reinforcing steel in concrete to assess corrosion rates
,
2001
.