High Performance Schottky Barrier TFTs With Indium–Gallium–Zinc-Oxide/Mo Schottky Junction

IGZO/Mo Schottky barrier TFTs are demonstrated, in which the tunable Schottky junction is formed between IGZO and Mo electrode after vacuum annealing at 280 °C or above. Oxygen-related trap states could be eliminated by vacuum annealing, and the pinning of Fermi level at IGZO/Mo interface is inhibited. The intrinsic IGZO/Mo Schottky barrier height is 0.37 eV. It can be further modulated from ~0.6 eV to ~0 eV as the gate voltage is changed, because the Fermi level of IGZO thin films can be adjusted by the external gate field. Large on-off ratio on the source-drain current (~106) and low off current density (<inline-formula> <tex-math notation="LaTeX">$10^{-8}$ </tex-math></inline-formula> Acm<inline-formula> <tex-math notation="LaTeX">${}^{-{2}}$ </tex-math></inline-formula>) are achieved. The field effect mobility is ~102.58 cm<inline-formula> <tex-math notation="LaTeX">$^{{2}}\text{V}^{-{1}}\text{s}^{-{1}}$ </tex-math></inline-formula>, superior to the conventional IGZO TFTs. HfO2 passivation layer is utilized to suppress the diffusion of ambient O2 and thus enhance the stability of TFTs.

[1]  G. Wang,et al.  New Opportunities for High‐Performance Source‐Gated Transistors Using Unconventional Materials , 2021, Advanced science.

[2]  H. Seul,et al.  Achieving a Low-Voltage, High-Mobility IGZO Transistor through an ALD-Derived Bilayer Channel and a Hafnia-Based Gate Dielectric Stack. , 2021, ACS applied materials & interfaces.

[3]  M. Furuta,et al.  Record-High-Performance Hydrogenated In-Ga-Zn-O Flexible Schottky Diodes. , 2020, ACS applied materials & interfaces.

[4]  Min Jae Kim,et al.  Atomic-layer-deposition process enabled carrier mobility boosting in field-effect transistors through a nanoscale ZnO/IGO heterojunction. , 2020, ACS applied materials & interfaces.

[5]  A. Song,et al.  Extremely high-gain source-gated transistors , 2019, Proceedings of the National Academy of Sciences.

[6]  H. Klauk,et al.  Quantitative Analysis of the Density of Trap States in Semiconductors by Electrical Transport Measurements on Low-Voltage Field-Effect Transistors , 2018, Physical Review Applied.

[7]  J. Cho,et al.  Large‐Area Schottky Barrier Transistors Based on Vertically Stacked Graphene–Metal Oxide Heterostructures , 2017 .

[8]  Arokia Nathan,et al.  Subthreshold Schottky-barrier thin-film transistors with ultralow power and high intrinsic gain , 2016, Science.

[9]  Jin-seong Park,et al.  The effect of ITO and Mo electrodes on the properties and stability of In-Ga-Zn-O thin film transistors , 2016, Journal of Electroceramics.

[10]  R. Moriya,et al.  Electric field modulation of Schottky barrier height in graphene/MoSe2 van der Waals heterointerface , 2015, 1507.05188.

[11]  R. Moriya,et al.  Large current modulation in exfoliated-graphene/MoS2/metal vertical heterostructures , 2014, 1408.6942.

[12]  K. Hirschman,et al.  Impact of Annealing on Contact Formation and Stability of IGZO TFTs , 2014 .

[13]  X. Duan,et al.  Highly flexible electronics from scalable vertical thin film transistors. , 2014, Nano letters.

[14]  Georges Gielen,et al.  High-performance a-In-Ga-Zn-O Schottky diode with oxygen-treated metal contacts , 2012 .

[15]  Kinam Kim,et al.  Graphene Barristor, a Triode Device with a Gate-Controlled Schottky Barrier , 2012, Science.

[16]  Jun Koyama,et al.  Evaluation of Off-State Current Characteristics of Transistor Using Oxide Semiconductor Material, Indium–Gallium–Zinc Oxide , 2012 .

[17]  R. Vega Comparison study of tunneling models for Schottky field effect transistors and the effect of Schottky barrier lowering , 2006, IEEE Transactions on Electron Devices.

[18]  Hideo Hosono,et al.  Ionic amorphous oxide semiconductors: Material design, carrier transport, and device application , 2006 .

[19]  H. Ohta,et al.  Room-temperature fabrication of transparent flexible thin-film transistors using amorphous oxide semiconductors , 2004, Nature.

[20]  L. Schlapbach,et al.  Electron affinity and work function of differently oriented and doped diamond surfaces determined by photoelectron spectroscopy , 1998 .

[21]  E. A. Kraut,et al.  Precise Determination of the Valence-Band Edge in X-Ray Photoemission Spectra: Application to Measurement of Semiconductor Interface Potentials , 1980 .

[22]  R. Jha,et al.  Deep-subthreshold Schottky barrier IGZO TFT for ultra low-power applications , 2020 .