Brominated flame retardants in the European chemicals policy of REACH-Regulation and determination in materials.

The EU REACH legislation will require the registration of 30,000 currently marketed chemicals, including the main commercial BFRs in use (Deca-BDE, HBCD and TBBP-A). Much of the data needed for registration are already available, thanks to risk assessments of continued production and use already undertaken in the EU. Within the authorisation, substitution by less hazardous chemicals is encouraged. Both qualitative and quantitative methods for the analysis of flame-retarded polymers are needed in order that the identity and concentration of the BFRs can be established and compliance with regulations including the RoHS Directive demonstrated. These are reviewed.

[1]  C. Marvin,et al.  Refinements to the diastereoisomer-specific method for the analysis of hexabromocyclododecane. , 2005, Rapid communications in mass spectrometry : RCM.

[2]  K. Kawauchi,et al.  Non-destructive Rapid Analysis of Brominated Flame Retardants in Electrical and Electronic Equipment Using Raman Spectroscopy , 2004, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[3]  R. Bossi,et al.  Method development for simultaneous analysis of HBCD, TBBPA, and dimethyl-TBBPA in marine biota from Greenland and the Faroe Islands , 2007 .

[4]  R. Law,et al.  Levels of the flame retardants hexabromocyclododecane and tetrabromobisphenol A in the blubber of harbor porpoises (Phocoena phocoena) stranded or bycaught in the U.K., with evidence for an increase in HBCD concentrations in recent years. , 2006, Environmental science & technology.

[5]  Stephan Hamm,et al.  Comparison of the recyclability of flame-retarded plastics. , 2003, Environmental science & technology.

[6]  Adrian Covaci,et al.  Hexabromocyclododecanes (HBCDs) in the environment and humans: a review. , 2006, Environmental science & technology.

[7]  R. Niessner,et al.  Determination of metal additives and bromine in recycled thermoplasts from electronic waste by TXRF analysis , 2000, Fresenius' journal of analytical chemistry.

[8]  Peter Lepom,et al.  Levels and trends of polybrominated diphenylethers and other brominated flame retardants in wildlife. , 2003, Environment international.

[9]  Martin Schlummer,et al.  Analysis of flame retardant additives in polymer fractions of waste of electric and electronic equipment (WEEE) by means of HPLC-UV/MS and GPC-HPLC-UV. , 2005, Journal of chromatography. A.

[10]  Müfit Bahadir,et al.  Examination of organic and inorganic xenobiotics in equipped printed circuits , 1997 .

[11]  Rudi van Eldik,et al.  Extraction of brominated flame retardants from polymeric waste material using different solvents and supercritical carbon dioxide , 2003 .

[12]  Rudi van Eldik,et al.  Identification of brominated flame retardants in polymeric materials by reversed-phase liquid chromatography with ultraviolet detection , 1998 .

[13]  M. Riess,et al.  Analysis of flame retarded polymers and recycling materials. , 2000, Chemosphere.

[14]  L. H. Grimme,et al.  Working Group I , 2000 .

[15]  Y. Lim,et al.  Affinity purification and enzymatic cleavage of inter-alpha inhibitor proteins using antibody and elastase immobilized on CIM monolithic disks. , 2005, Journal of chromatography. A.

[16]  F. Wang Polymer additive analysis by pyrolysis-gas chromatography. II. Flame retardants. , 2000, Journal of chromatography. A.

[17]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[18]  C. A. Wit An overview of brominated flame retardants in the environment. , 2002 .

[19]  S Hamm,et al.  Determination of polybrominated diphenyl ethers and PBDD/Fs during the recycling of high impact polystyrene containing decabromodiphenyl ether and antimony oxide. , 2001, Chemosphere.

[20]  A. Covaci,et al.  Determination of brominated flame retardants, with emphasis on polybrominated diphenyl ethers (PBDEs) in environmental and human samples--a review. , 2003, Environment international.

[21]  Sabine Kemmlein,et al.  BFR-governmental testing programme. , 2003, Environment international.

[22]  Rudi van Eldik,et al.  Rapid identification of RoHS-relevant flame retardants from polymer housings by ultrasonic extraction and RP-HPLC/UV. , 2005, Journal of chromatography. A.

[23]  K. Oberg,et al.  Distribution and levels of brominated flame retardants in sewage sludge. , 2002, Chemosphere.

[24]  Jacob de Boer,et al.  Levels and trends of brominated flame retardants in the European environment. , 2006, Chemosphere.

[25]  Reinhard Niessner,et al.  Detection of bromine in thermoplasts from consumer electronics by laser-induced plasma spectroscopy , 2004 .

[26]  Robin J Law,et al.  Levels of polybrominated diphenyl ether (PBDE) flame retardants in animals representing different trophic levels of the North Sea food Web. , 2002, Environmental science & technology.

[27]  Vladimir Zitko Qualitative determination of 10,10'-oxybisphenoxarsine and decabromodiphenyl ether in plastics. , 1999, Chemosphere.

[28]  T. Lampe,et al.  Examination of the emission of (semi-)volatile organic compounds from polymer materials used as interior trim materials in automobiles , 1993 .

[29]  Arnold Schecter,et al.  Polybrominated diphenyl ethers (PBDEs) in U.S. mothers' milk. , 2003, Environmental health perspectives.

[30]  H. Neels,et al.  Recent developments in the analysis of brominated flame retardants and brominated natural compounds. , 2007, Journal of chromatography. A.

[31]  Martin Schlummer,et al.  Characterisation of polymer fractions from waste electrical and electronic equipment (WEEE) and implications for waste management. , 2007, Chemosphere.

[32]  M. Zanetti,et al.  Thermal decomposition of fire retardant brominated epoxy resins cured with different nitrogen containing hardeners , 2007 .

[33]  G. Camino,et al.  Thermal decomposition of fire retardant brominated epoxy resins , 2002 .

[34]  T. Hyötyläinen,et al.  Determination of brominated flame retardants in environmental samples , 2002 .