论文信息 - 1,4,6-Tris(di-isopropylamino)-1,4,6-triboraspiro[4.4]nona-2,8-diene from the reaction of benzene with subvalent boron species

1,4,6-Tris(di-isopropylamino)-1,4,6-triboraspiro[4.4]nona-2,8-diene from the reaction of benzene with subvalent boron species

Reaction of benzene with sodium/potassium alloy and dichloro(di-isopropylamino)borane (1 : 2) in 1,2-dimethoxyethane gives, in addition to other products, the title compound, characterised by its mass (El, Fl) and NMR (1H, 11B, 13C) spectra and X-ray crystallography.

[1] G. Sheldrick,et al. Synthesis and structure of novel polycyclic species from toluene and m-xylene and the dehalogenation product of difluoro(diisopropylamino)borane , 1989 .

[2] A. Meller,et al. Zur Borylierung von Benzol und Naphthalin durch Dehalogenierungsprodukte von Dichlor(diisopropylamino)boran , 1988 .