Numerical analysis of CO2 concentration and recovery from flue gas by a novel vacuum swing adsorption cycle

Abstract The objective of this work is to study the feasibility of carbon dioxide concentration and recovery from flue gases using a novel VSA cycle without rinse step with the aid of mathematical modeling. A theoretical model based on conservation equations (following the one proposed by Da Silva and Rodrigues (2001) ) is used for an initial evaluation of the process performance. Activated carbon is the adsorbent considered, simulating adsorption equilibrium and kinetics with the equations proposed by Kikkinides, Yang, and Cho (1993) . According to the simulated results, it is possible to recover carbon dioxide with high purity (>93%) from a mixture with 13% carbon dioxide at 40 °C, with higher recovery (>90%) and a lower power consumption (

[1]  H. Herzog Peer Reviewed: What Future for Carbon Capture and Sequestration? , 2001 .

[2]  Soon-Haeng Cho,et al.  Numerical Analysis on the Power Consumption of the PSA Process for Recovering CO2 from Flue Gas , 2002 .

[3]  Umberto Desideri,et al.  Performance modelling of a carbon dioxide removal system for power plants , 1999 .

[4]  K. S. Knaebel,et al.  Pressure swing adsorption , 1993 .

[5]  Alírio E. Rodrigues,et al.  Propylene/propane separation by vacuum swing adsorption using 13X zeolite , 2001 .

[6]  Carlos A. Grande,et al.  Biogas to Fuel by Vacuum Pressure Swing Adsorption I. Behavior of Equilibrium and Kinetic-Based Adsorbents , 2007 .

[7]  Kee-Kahb Koo,et al.  Effect of Rinse and Recycle Methods on the Pressure Swing Adsorption Process To Recover CO2 from Power Plant Flue Gas Using Activated Carbon , 2002 .

[8]  R. T. Yang,et al.  Concentration and recovery of carbon dioxide from flue gas by pressure swing adsorption , 1993 .

[9]  Alírio E. Rodrigues,et al.  Analysis of the boundary conditions for the simulation of the pressure equalization step in PSA cycles , 2008 .

[10]  R. T. Yang,et al.  Gas Separation by Adsorption Processes , 1987 .

[11]  Kornelis Blok,et al.  Underground storage of carbon dioxide , 1995 .

[12]  R. T. Yang,et al.  Comparison of Activated Carbon and Zeolite 13X for CO2 Recovery from Flue-Gas by Pressure Swing Adsorption , 1995 .

[13]  Jun Zhang,et al.  Effect of process parameters on power requirements of vacuum swing adsorption technology for CO2 capture from flue gas , 2008 .

[14]  Richard F. Sincovec,et al.  Algorithm 540: PDECOL, General Collocation Software for Partial Differential Equations [D3] , 1979, TOMS.

[15]  Tatsuo Kabata,et al.  Technology for removing carbon dioxide from power plant flue gas by the physical adsorption method , 1996 .

[16]  James A. Ritter,et al.  Stripping PSA cycles for CO2 recovery from flue gas at high temperature using a hydrotalcite-like adsorbent , 2006 .