Immobilization of η5-cyclopentadienyltris(dimethylamido)zirconium polymerization catalysts on a chlorosilane- and HMDS-modified mesoporous silica surface: a new concept for supporting metallocene amides towards heterogeneous single-site-catalysts

[1]  T. Pakkanen,et al.  Synthesis of supported titanocene amide complex and its use as a catalyst in ethylene polymerization , 1999 .

[2]  J. Rosenholm,et al.  Preparation and Characterization of MCM-41 Supported Metallocene Catalysts for Olefin Polymerization , 1999 .

[3]  T. Pakkanen,et al.  AMINOSILANE AS A COUPLING AGENT FOR CYCLOPENTADIENYL LIGANDS ON SILICA , 1999 .

[4]  H. C. L. Abbenhuis Die Heterogenisierung von Metallocenkatalysatoren für Alkenpolymerisationen , 1999 .

[5]  A. Fukuoka,et al.  Immobilization of a C2-Symmetric ansa-Zirconocene Complex on Silica Surfaces Using a Si-Cl Anchor : Catalysts for Isospecific Propene Polymerization , 1999 .

[6]  S. Noh,et al.  Ethylene Polymerization with the Heterogeneous Single Site CpIndZrCl2 Catalyst , 1999 .

[7]  V. Pasquet,et al.  Supported Metallocene Catalysts in Olefin Polymerization: Toward High Performances , 1999 .

[8]  E. Rytter,et al.  Supported metallocene catalysts prepared by impregnation of MAO modified silica by a metallocene/monomer solution , 1998 .

[9]  T. Pakkanen,et al.  Cyclopentadienyl Surface as a Support for Zirconium Polyethylene Catalysts , 1997 .

[10]  Keun-byoung Yoon,et al.  Polymerization of ethylene by using zirconocene catalyst anchored on silica with trisiloxane and pentamethylene spacers , 1997 .

[11]  T. Takata,et al.  Syndiospecific propene polymerization with polymer-supported metallocene catalyst , 1997 .

[12]  W. Kaminsky,et al.  Metallocenes for Polymer Catalysis , 1997 .

[13]  D. O′Hare,et al.  STEREOSPECIFIC PROPENE POLYMERISATION CATALYSIS USING AN ORGANOMETALLIC MODIFIED MESOPOROUS SILICATE , 1997 .

[14]  M. Białek,et al.  Vanadium-based Ziegler-Natta catalyst supported on MgCl2(THF)2 for ethylene polymerization , 1996 .

[15]  R. Grubbs,et al.  Safe and Convenient Procedure for Solvent Purification , 1996 .

[16]  W. Herrmann,et al.  TIN-BRIDGED ANSA-METALLOCENES OF ZIRCONIUM : SYNTHESIS AND CATALYTIC PERFORMANCE IN OLEFIN POLYMERIZATION , 1996 .

[17]  W. Herrmann,et al.  UNSYMMETRICAL ANSA-METALLOCENES OF ZIRCONIUM AND HAFNIUM , 1996 .

[18]  Kouki Ohnishi,et al.  Ethene polymerization with modified-polypropene-supported highly stable Ziegler catalyst , 1996 .

[19]  Keun-byoung Yoon,et al.  Metallocene/mao polymerization catalysts supported on cyclodextrin , 1995 .

[20]  David Fischer,et al.  Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts , 1995 .

[21]  B. Rieger,et al.  Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren , 1995 .

[22]  Keun-byoung Yoon,et al.  Olefin polymerization with titanium tetrachloride catalysts supported on surface-modified silica , 1995 .

[23]  K. Soga,et al.  Heterogeneous Metallocene Catalysts , 1995 .

[24]  G. Diamond,et al.  EFFICIENT SYNTHESIS OF RAC-(ETHYLENEBIS(INDENYL)ZRX2 COMPLEXES VIA AMINE ELIMINATION , 1995 .

[25]  Keun-byoung Yoon,et al.  Ethylene polymerization initiated with the Cp2ZrCl2-methylaluminoxane catalyst system supported on α-cyclodextrin , 1994 .

[26]  A. Maldotti,et al.  Reduction of bis(η5‐cyclopentadienyl)zirconium dichloride in the presence of methylalumoxane , 1994 .

[27]  K. Soga,et al.  Highly isospecific SiO2-supported zirconocene catalyst activated by ordinary alkylaluminiums , 1994 .

[28]  K. Soga,et al.  Activation of SiO2‐supported zirconocene catalysts by common trialkylaluminiums , 1993 .

[29]  G. Erker,et al.  The role of torsional isomers of planarly chiral nonbridged bis(indenyl)metal type complexes in stereoselective propene polymerization , 1993 .

[30]  W. Kaminsky,et al.  High melting polypropenes by silica‐supported zirconocene catalysts , 1993 .

[31]  B. Bachmann,et al.  High Molecular Weight Polypropylene through Specifically DesigneZirconocene Catalysts , 1992 .

[32]  K. Soga,et al.  Polymerization of propene with the heterogeneous catalyst system Et[IndH4]2ZrCl2/MAO/SiO2 combined with trialkylaluminium , 1992 .

[33]  J. Chien,et al.  Isospecific polymerization of propylene catalyzed by rac-ethylenebis(indenyl)methylzirconium cation , 1991 .

[34]  J. Chien,et al.  Olefin copolymerization with metallocene catalysts. III. Supported metallocene/methylaluminoxane catalyst for olefin copolymerization , 1991 .

[35]  A. Winter,et al.  Stereospecific polymerizations with metallocene catalysts: Products and technological aspects , 1991 .

[36]  W. Cooper,et al.  Analysis of thermally and chemically modified silica gels by heterogeneous gas-solid chromatography and infrared spectroscopy , 1989 .

[37]  T. Marks,et al.  Organometallic molecule-support interactions. Highly active organozirconium hydrogenation catalysts and the formation of cationic species on alumina surfaces , 1988 .

[38]  J. Nawrocki On some aspects of the silica surface modification with hexamethylcyclotrisilazane, hexamethyldisilazane and their mixtures , 1988 .

[39]  W. Kaminsky,et al.  Polymerisation von Propen und Buten mit einem chiralen Zirconocen und Methylaluminoxan als Cokatalysator , 1985 .

[40]  J. Ewen Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts , 1984 .

[41]  H. Sinn,et al.  Bis(cyclopentadienyl)zirkon‐verbindungen und aluminoxan als Ziegler‐Katalysatoren für die polymerisation und copolymerisation von olefinen , 1983 .

[42]  G. Maciel,et al.  Cross-polarization magic-angle-spinning silicon-29 nuclear magnetic resonance study of silica gel using trimethylsilane bonding as a probe of surface geometry and reactivity , 1982 .

[43]  W. Kaminsky Neues über Ziegler–Natta–Katalyse , 1981 .

[44]  F. Buzek,et al.  Stoichiometry and kinetics of the reaction of silica with organosilicon compounds , 1981 .

[45]  A. Roosmalen,et al.  Active centers for the isomerization of linear butenes on silica gel: Specific poisoning of Brønsted acid sites by silylation , 1980 .

[46]  D. Leibfritz,et al.  Rigid Phenyl-Group Conformation in Complexes†‡ , 1980 .

[47]  H. Vollmer,et al.  „Lebende Polymere”︁ bei Ziegler‐Katalysatoren extremer Produktivität , 1980 .

[48]  H. Vollmer,et al.  Halogenfreie lösliche Ziegler‐Katalysatoren für die Ethylen‐Polymerisation. Regelung des Molekulargewichtes durch Wahl der Reaktionstemperatur , 1976 .

[49]  Walter Kaminsky,et al.  Halogen‐Free Soluble Ziegler Catalysts for the Polymerization of Ethylene. Control of Molecular Weight by Choice of Temperature , 1976 .

[50]  Wendell P. Long,et al.  Der Einfluß von Wasser auf die katalytische Aktivität von Bis(π‐cyclopentadienyl)titandichlorid‐Dimethylaluminiumchlorid zur Polymerisation von Äthylen , 1975 .

[51]  K. Reichert,et al.  Zur kinetik der niederdruckpolymerisation von äthylen mit löslichen ZIEGLER‐katalysatoren , 1973 .

[52]  J. Waters,et al.  Study of (π‐C5H5)2Ti(C2H5)Cl and its higher homologs in soluble Ziegler catalysts , 1972 .

[53]  W. Hertl,et al.  Reaction of hexamethyldisilazane with silica , 1971 .

[54]  J. Boor Review of Recent Literature on Ziegler-Type Catalysts , 1970 .

[55]  W. Hertl,et al.  Comment on: “Adsorption and reaction of methylchlorosilanes at an aerosil surface,” by B. Evans and T. E. White , 1969 .

[56]  W. Hertl,et al.  Reactions of chlorosilanes with silica surfaces , 1969 .

[57]  B. Evans,et al.  Adsorption and reaction of methylchlorosilanes at an “Aerosil” surface , 1968 .

[58]  W. Hertl Mechanism of gaseous siloxane reaction with silica. II , 1968 .

[59]  M. Lappert,et al.  Amido-derivatives of metals and metalloids. Part VI. Reactions of titanium(IV), zirconium(IV), and hafnium(IV) amides with protic compounds , 1968 .

[60]  G. Henrici-Olivé,et al.  Die aktive Spezies in homogenen Ziegler‐Natta‐Katalysatoren für die Äthylenpolymerisation , 1967 .

[61]  G. Henrici-Olivė,et al.  The Active Species in Homogeneous Ziegler‐Natta Catalysts for the Polymerization of Ethylene , 1967 .

[62]  A. Zecchina,et al.  Infrared study of methanol adsorption on Aerosil. I. Chemisorption at room temperature , 1967 .

[63]  J. W. Ward,et al.  The Surface Structure of Porous Silicas , 1966 .

[64]  J. Peri Infrared Study of OH and NH2 Groups on the Surface of a Dry Silica Aerogel , 1966 .

[65]  K. Ziegler Folgen und Werdegang einer Erfindung Nobel‐Vortrag am 12. Dezember 1963 , 1964 .

[66]  A. Michaels,et al.  Gas transmission in irradiated polyethylene , 1963 .

[67]  D. C. Bradley,et al.  765. Metallo-organic compounds containing metal–nitrogen bonds. Part I. Some dialkylamino-derivatives of titanium and zirconium , 1960 .

[68]  H. Kohlschütter,et al.  Umsetzung von Trimethylsiliciummonochlorid mit Silicagel , 1956 .

[69]  Hans-Dieter Martin,et al.  Das Mülheimer Normaldruck‐Polyäthylen‐Verfahren , 1955 .

[70]  R. O. Sauer,et al.  Derivatives of the Methylchlorosilanes. IV. Amines , 1946 .

[71]  R. O. Sauer Derivatives of the Methylchlorosilanes. I. Trimethylsilanol and its Simple Ethers , 1944 .