N-(4-Bromobenzylidene)-3,4-dimethylisoxazol-5-amine

In the title compound, C12H11BrN2O, the 4-bromobenzaldehyde and 5-amino-3,4-dimethylisoxazole units are oriented at a dihedral angle of 4.89 (8)°. In the crystal, weak π–π interactions are present between the benzene rings at a centroid–centroid distance of 3.7862 (14) Å.

[1]  Raymond E. Davis,et al.  Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals , 1995 .

[2]  M. Nawaz Tahir,et al.  4-Chloro-2-[(E)-({4-[N-(3,4-dimethylisoxazol-5-yl)sulfamoyl]phenyl}iminio)methyl]phenolate , 2008, Acta crystallographica. Section E, Structure reports online.

[3]  Seik Weng Ng,et al.  N-[4-(Dimethylamino)benzylidene]-3,4-dimethylisoxazol-5-amine , 2010, Acta crystallographica. Section E, Structure reports online.

[4]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[5]  M. Nawaz Tahir,et al.  4-Bromo-2-((E)-{4-[(3,4-dimethylisoxazol-5-yl)sulfamoyl]phenyl}iminiomethyl)phenolate , 2008, Acta crystallographica. Section E, Structure reports online.

[6]  Anthony L. Spek,et al.  Structure validation in chemical crystallography , 2009, Acta crystallographica. Section D, Biological crystallography.

[7]  Louis J. Farrugia,et al.  ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[8]  Hoong-Kun Fun,et al.  2-[(E)-(3,4-Dimethylisoxazol-5-yl)iminomethyl]phenol , 2010, Acta crystallographica. Section E, Structure reports online.

[9]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[10]  Madhukar Hemamalini,et al.  1-[(E)-(3,4-Dimethylisoxazol-5-yl)iminomethyl]-2-naphthol , 2010, Acta crystallographica. Section E, Structure reports online.

[11]  Louis J. Farrugia,et al.  WinGX suite for small-molecule single-crystal crystallography , 1999 .