An empirical investigation of the accuracy of virial equations for apolar and slightly polar vapours

The applicability of the Berthelot, the Guggenheim-McGlashan, the Pitzer-Curl, the McGlashan-Potter, and the Kreglewski virial equation to gas imperfection calculations has been examined empirically. For this purpose, calculated virial coefficients were compared with experimental data for a number of normal and branched alkanes, some polymethylenes, some aromatic and halogenated hydrocarbons, and ethers.

[1]  A. Kreglewski.  Second virial coefficient of real gases , 1969 .

[2]  B. Zwolinski,et al.  Critical Constants of Organic Substances , 1968 .

[3]  G. E. Macwood,et al.  Second Virial Coefficients and the Force Constants, ε0 and r0, of Six Halogen‐Substituted Methanes , 1968 .

[4]  J. McKetta,et al.  Graphical determination of virial coefficients by the Burnett method. Isopentane and neopentane , 1967 .

[5]  J. Prausnitz,et al.  Empirical Correlation of Second Virial Coefficients for Vapor-Liquid Equilibrium Calculations , 1967 .

[6]  T. Spurling,et al.  Measurement of the temperature variation of virial coefficients. III. The second virial coefficient of Carbon Disulphide, Methyl Chloride, Acetone, and Methanol, and certain of their binary mixtures , 1967 .

[7]  T. Wassenaar,et al.  P-V-T- Data and Thermodynamical Properties of Freon-12 (CCl2F2) and Freon-13 (CClF3) Fluorocarbons at Temperatures Between 0° and 150° C. and at Pressures Up to 400 Atm. , 1966 .

[8]  T. Spurling,et al.  Measurement of the temperature variation of virial coefficients. II. The second virial coefficients of benzene , 1966 .

[9]  E. A. Guggenheim,et al.  Systematic Deviations from the Principle of Corresponding States , 1965 .

[10]  M. L. Mcglashan,et al.  Second virial coefficients of some alk-1-enes, and of a mixture of propene + hept-1-ene , 1964 .

[11]  L. Canjar,et al.  Second and Third Virial Coefficients for n-Hexane and Its Isomers. , 1963 .

[12]  R. Dunlap,et al.  SECOND VIRIAL COEFFICIENTS FOR THE SYSTEMS: n-BUTANE + PERFLUORO-n-BUTANE AND DIMETHYL ETHER + 1-HYDROPERFLUOROPROPANE , 1962 .

[13]  G. Bottomley,et al.  Virial Coefficients of Three Organic Sulphides , 1962 .

[14]  J. Mccullough,et al.  Thermodynamics of cyclopentane, methylcyclopentane and 1,cis-3-dimethylcyclopentane: verification of the concept of pseudorotation , 1959 .

[15]  J. McCoubrey,et al.  The second virial coefficients of hydrocarbon + fluorocarbon mixtures , 1959 .

[16]  Robert F. Curl,et al.  The Volumetric and Thermodynamic Properties of Fluids. III. Empirical Equation for the Second Virial Coefficient1 , 1957 .

[17]  J. Martin,et al.  The second virial coefficients of pyridine and benzene, and certain of their methyl homologues , 1957 .

[18]  W. D. Good,et al.  Fluorobenzene: Thermodynamic Properties in the Solid, Liquid and Vapor States; A Revised Vibrational Assignment1 , 1956 .

[19]  Robert F. Curl,et al.  The Volumetric and Thermodynamic Properties of Fluids. II. Compressibility Factor, Vapor Pressure and Entropy of Vaporization1 , 1955 .

[20]  Kenneth S. Pitzer,et al.  The Volumetric and Thermodynamic Properties of Fluids. I. Theoretical Basis and Virial Coefficients1 , 1955 .

[21]  Robert C. Shair,et al.  Thermodynamic Properties of Halogenated Ethanes and Ethylenes , 1955 .

[22]  S. Schwimmer,et al.  Temperature Tolerance in Frozen Food Processing , 1955 .

[23]  M. L. Mcglashan,et al.  Second virial coefficients of vapour mixtures , 1955 .

[24]  Sd Hamann,et al.  The behaviour of fluids of Quasi-Spherical molecules. I. Gases at low densities , 1954 .

[25]  K. D. Williamson,et al.  Thermodynamic Properties of Furan , 1952 .

[26]  H. M. Huffman,et al.  Experimental vapor heat capacities and heats of vaporization of 2-methylpentane, 3-methylpentane, and 2,3-dimethylbutane , 1949 .

[27]  H. M. Huffman,et al.  Thermodynamic Properties of Three Isomeric Pentenes , 1949 .

[28]  W. Stockmayer,et al.  Determination of the Lennard‐Jones Parameters from Second Virial Coefficients Tabulation of the Second Virial Coefficient , 1942 .

[29]  Edwin E. Roper.  Gas Imperfection. I. Experimental Determination of Second Virial Coefficients for Seven Unsaturated Aliphatic Hydrocarbons. , 1940 .