A Multi-Analytical Approach to the Use of Conifer Needles as Passive Samplers of Particulate Matter and Organic Pollutants

The present work regards the analysis of airborne pollutants emitted by an electric arc furnace steel making plant at a test site in Northern Italy and collected by conifer needles. The spatial and temporal trends of accumulation of Mn, Zn, Fe, Cr, Pb, polychlorinated dibenzo-p-dioxins/dibenzofurans and polychlorinated biphenyls dioxin revealed that the contribution from the steel making plant has never been particularly high, whereas traffic emerged as a significant pollution source. The benefits of combining bulk and single particle analysis in air pollution studies from different sources are also discussed.

[1]  M. Oehme,et al.  Development of a comprehensive analytical method for the determination of chlorinated paraffins in spruce needles applied in passive air sampling. , 2009, Environmental pollution.

[2]  Weijun Li,et al.  Characterization of PM(2.5) in the ambient air of Shanghai City by analyzing individual particles. , 2006, The Science of the total environment.

[3]  P. Schleppi,et al.  The concentration of Ca, Sr, Ba and Mn in successive needle age classes of Norway spruce [Picea abies (L.) Karst.] , 2004, Trees.

[4]  P. Muukkonen.  Needle biomass turnover rates of Scots pine (Pinus sylvestris L.) derived from the needle-shed dynamics , 2005, Trees.

[5]  M. Chettri,et al.  A Study of Air Pollution with Heavy Metals in Athens City and Attica Basin Using Evergreen Trees as Biological Indicators , 2012, Biological Trace Element Research.

[6]  Jérôme Rose,et al.  Zinc speciation in steel plant atmospheric emissions: A multi-technical approach , 2006 .

[7]  H. Torvela,et al.  Comparison of dissolution methods for multi-element analysis of some plant materials used as bioindicator of sulphur and heavy metal deposition determined by ICP-AES and ICP-MS , 2000 .

[8]  S. Ciută,et al.  ROLE OF FEEDSTOCK TRANSPORT IN THE BALANCE OF PRIMARY PM EMISSIONS IN TWO CASE-STUDIES: RMSW INCINERATION VS. SINTERING PLANT , 2012 .

[9]  K. Percy,et al.  Epicuticular wax of subarctic Scots pine needles: response to sulphur and heavy metal deposition , 1997 .

[10]  Roy M Harrison,et al.  Sources and properties of non-exhaust particulate matter from road traffic: a review. , 2008, The Science of the total environment.

[11]  A. Wyttenbach,et al.  The concentrations of Fe, Zn and Co in successive needle age classes of Norway spruce [Picea abies (L.) Karst.] , 1995, Trees.

[12]  K. Schrøder,et al.  Major and Trace Elements in Spruce Needles from Urban Areas: Some Aspects of Analysis in Environmental Studies , 2002 .

[13]  Christopher A. Laroo,et al.  Brake Wear Particulate Matter Emissions , 2000 .

[14]  L. Schwark,et al.  Biomonitoring of air quality in the Cologne conurbation using pine needles as a passive sampler—Part I: magnetic properties , 2004 .

[15]  J. Derome,et al.  The Applicability of Needle Chemistry for Diagnosing Heavy Metal Toxicity to Trees , 2004 .

[16]  M. Schiavon,et al.  A proposal for a diet-based local PCDD/F deposition limit. , 2013, Chemosphere.

[17]  D. Calamari,et al.  Conifer needles as passive biomonitors of the spatial and temporal distribution of DDT from a point source. , 2003, Chemosphere.

[18]  Huixia Wang,et al.  Leaf dust capturing capacity of urban greening plant species in relation to leaf micromorphology , 2011, 2011 International Symposium on Water Resource and Environmental Protection.

[19]  Roy M. Harrison,et al.  Identification of brake wear particles and derivation of a quantitative tracer for brake dust at a major road , 2010 .

[20]  E. Teper.  Dust-particle migration around flotation tailings ponds: pine needles as passive samplers , 2009, Environmental monitoring and assessment.

[21]  J. Klánová,et al.  Can pine needles indicate trends in the air pollution levels at remote sites? , 2009, Environmental pollution.

[22]  S. Huttunen,et al.  Scots pine needle surfaces on radial transects across the north boreal area of Finnish Lapland and the Kola Peninsula of Russia. , 1996, Environmental pollution.

[23]  D. Calamari,et al.  A study of the spatial distribution of PCBs in the UK atmosphere using pine needles , 1996 .

[24]  H. Kylin,et al.  Environmental monitoring of polychlorinated biphenyls using pine needles as passive samplers. , 1994, Environmental science & technology.

[25]  D. Calamari,et al.  Fingerprints of some chlorinated hydrocarbons in plant foliage from Africa , 1993 .

[26]  S. Jensen,et al.  The pine needle as a monitor of atmospheric pollution , 1989, Nature.

[27]  Elena Cristina Rada,et al.  DEPOSITION NEAR A SINTERING PLANT: PRELIMINARY COMPARISON BETWEEN TWO METHODS OF MEASUREMENTS BY DEPOSIMETERS , 2012 .

[28]  L. Schwark,et al.  Biomonitoring of air quality in the Cologne Conurbation using pine needles as a passive sampler: Part II: polycyclic aromatic hydrocarbons (PAH) , 2004 .

[29]  K. Wichterle,et al.  Zinc Stripping from Steelwork Dust , 2010 .