Surface Modification of PdZn Nanoparticles via Galvanic Replacement for the Selective Hydrogenation of Terminal Alkynes

In this study, a novel intermetallic compound-derived trimetallic surface site in nanoscale via the galvanic replacement reaction (GRR) is described. A PdZn/SiO2 catalyst, which exhibited high acti...

[1]  A. Stakheev,et al.  PdZn/α-Al 2 O 3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics , 2018 .

[2]  S. Furukawa,et al.  Regio- and Chemoselective Hydrogenation of Dienes to Monoenes Governed by a Well-Structured Bimetallic Surface. , 2017, Journal of the American Chemical Society.

[3]  D. Murzin,et al.  Pd₃Sn nanoparticles on TiO₂ and ZnO supports as catalysts for semi-hydrogenation : synthesis and catalytic performance , 2017 .

[4]  D. Banerjee,et al.  Synthetically Tuned Atomic Ordering in PdCu Nanoparticles with Enhanced Catalytic Activity toward Solvent-Free Benzylamine Oxidation. , 2017, ACS applied materials & interfaces.

[5]  Takayuki Komatsu,et al.  Intermetallic Compounds: Promising Inorganic Materials for Well-Structured and Electronically Modified Reaction Environments for Efficient Catalysis , 2017 .

[6]  L. Grabow,et al.  Synergistic Effects in Bimetallic Palladium-Copper Catalysts Improve Selectivity in Oxygenate Coupling Reactions. , 2016, Journal of the American Chemical Society.

[7]  Zhenmin Cheng,et al.  Selective hydrogenation of phenylacetylene over bimetallic Pd–Cu/Al2O3 and Pd–Zn/Al2O3 catalysts , 2016 .

[8]  S. Furukawa,et al.  Selective Hydrogenation of Functionalized Alkynes to (E)-Alkenes, Using Ordered Alloys as Catalysts , 2016 .

[9]  Tao Zhang,et al.  PdZn Intermetallic Nanostructure with Pd–Zn–Pd Ensembles for Highly Active and Chemoselective Semi-Hydrogenation of Acetylene , 2016 .

[10]  S. Ha,et al.  Carbon supported Pd-based bimetallic and trimetallic catalyst for formic acid electrochemical oxidation , 2016 .

[11]  X. Bao,et al.  Architecture of PtFe/C catalyst with high activity and durability for oxygen reduction reaction , 2014, Nano Research.

[12]  Yadong Li,et al.  Sophisticated construction of Au islands on Pt-Ni: an ideal trimetallic nanoframe catalyst. , 2014, Journal of the American Chemical Society.

[13]  M. Arai,et al.  Liquid phase hydrogenation of phenylacetylene over Pd and PdZn catalysts in toluene: effects of alloying and CO2 pressurization , 2014 .

[14]  V. Van Speybroeck,et al.  Error Estimates for Solid-State Density-Functional Theory Predictions: An Overview by Means of the Ground-State Elemental Crystals , 2012, 1204.2733.

[15]  Junyao Zhou,et al.  Ni–In Intermetallic Nanocrystals as Efficient Catalysts toward Unsaturated Aldehydes Hydrogenation , 2013 .

[16]  B. Hwang,et al.  Simple replacement reaction for the preparation of ternary Fe(1-x)PtRu(x) nanocrystals with superior catalytic activity in methanol oxidation reaction. , 2012, Journal of the American Chemical Society.

[17]  Kyoung Hwan Choi,et al.  Improvement of activity for oxygen reduction reaction by decoration of Ir on PdCu/C catalyst , 2012 .

[18]  R. Behm,et al.  The interaction of CO with PdAg/Pd(111) surface alloys--a case study of ensemble effects on a bimetallic surface. , 2011, Physical chemistry chemical physics : PCCP.

[19]  J. Bokhoven,et al.  Formation and Characterization of PdZn Alloy: A Very Selective Catalyst for Alkyne Semihydrogenation , 2011 .

[20]  B. Bridier,et al.  A density functional theory study of the ‘mythic’ Lindlar hydrogenation catalyst , 2011 .

[21]  A. Manthiram,et al.  Synthesis of Pt@Cu Core−Shell Nanoparticles by Galvanic Displacement of Cu by Pt4+ Ions and Their Application as Electrocatalysts for Oxygen Reduction Reaction in Fuel Cells , 2010 .

[22]  Weijiang Zhou,et al.  Pt-decorated PdFe nanoparticles as methanol-tolerant oxygen reduction electrocatalyst. , 2010, ACS applied materials & interfaces.

[23]  C. V. Rao,et al.  ORR Activity and Direct Ethanol Fuel Cell Performance of Carbon-Supported Pt-M (M = Fe, Co, and Cr) Alloys Prepared by Polyol Reduction Method , 2009 .

[24]  J. Mellor,et al.  Pd catalysed hexyne hydrogenation modified by Bi and by Pb , 2009 .

[25]  Thomas Bligaard,et al.  Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene , 2008, Science.

[26]  E. Antolini Platinum-based ternary catalysts for low temperature fuel cells: Part II. Electrochemical properties , 2007 .

[27]  B. Hwang,et al.  Chemical transformation from FePt to Fe1-xPtMx (M = Ru, Ni, Sn) nanocrystals by a cation redox reaction: X-ray absorption spectroscopic studies. , 2007, Journal of the American Chemical Society.

[28]  Matt Probert,et al.  First-principles simulation: ideas, illustrations and the CASTEP code , 2002 .

[29]  C. Pu,et al.  Methanol Oxidation on Single‐Phase Pt‐Ru‐Os Ternary Alloys , 1997 .

[30]  T. Fischer,et al.  The electronic effect in alloy chemisorption: CO and H2 studies on nickel titanium alloys , 1981 .

[31]  G. Bond,et al.  The kinetics and mechanism of carbon monoxide hydrogenation over silica-supported ruthenium-copper catalysts , 1976 .