Does the Methylene Blue Test Give Equally Satisfactory Results in All Studied Igneous Rocks Relative to the Identification of Swelling Clay Minerals?

The presence or the absence of swelling clay minerals in rocks, which are used in various construction applications, constitutes a determinant factor for their strength, and consequently, in their general behavior in various construction applications, as they have the ability to swell up to 400 times of their usual volume, causing failures to any application in which they participate. The aim of this study is to respond to the question of whether the empirical method of methylene blue yields equally safe and correct results in different types of igneous rocks and if not, which is the determining factor affecting the results. The answer to this complex question is feasible by investigating the microscopic structure and the mineralogy of the studied rocks, and particularly, using the content of specific phyllosilicate minerals which may be related or not with the methylene blue values. According to the results, the methylene blue test seems to work correctly for the intermediate (Group I) and mafic (Group II) examined rocks, but it seems to be wrong for the highly serpentinized ultramafic rocks (up to 70% of serpentine) (Group III).

[1]  A. Rogkala,et al.  Using Factor Analysis to Determine the Interrelationships between the Engineering Properties of Aggregates from Igneous Rocks in Greece , 2018, Minerals.

[2]  P. Lampropoulou,et al.  The Impact of Secondary Phyllosilicate Minerals on the Engineering Properties of Various Igneous Aggregates from Greece , 2018, Minerals.

[3]  P. Lampropoulou,et al.  The Influence of Alteration of Aggregates on the Quality of the Concrete: A Case Study from Serpentinites and Andesites from Central Macedonia (North Greece) , 2018 .

[4]  Runliang Zhu,et al.  Conversion of serpentine to smectite under hydrothermal condition: Implication for solid-state transformation , 2018 .

[5]  B. W. Evans,et al.  Serpentinite: What, Why, Where? , 2013 .

[6]  A. K. Singh,et al.  Genetic implications of Zn‐ and Mn‐rich Cr‐spinels in serpentinites of the Tidding Suture Zone, eastern Himalaya, NE India , 2013 .

[7]  R. Kadam,et al.  Characterization of Indian serpentine by X-ray diffraction, photoacoustic spectroscopy and electron paramagnetic resonance spectroscopy , 2010 .

[8]  J. Astier,et al.  TEM-assisted dynamic scanning force microscope imaging of (001) antigorite: Surfaces and steps on a modulated silicate , 2010 .

[9]  A. Kaya,et al.  Comparison of Methods for Determining Specific Surface Area of Soils , 2006 .

[10]  B. Theng,et al.  Chapter 2 Structures and Mineralogy of Clay Minerals , 2006 .

[11]  C. Scavia,et al.  Clay mineral characterization through the methylene blue test: comparison with other experimental techniques and applications of the method , 2004 .

[12]  B. Grobéty Polytypes and higher-order structures of antigorite: A TEM study , 2003 .

[13]  D. Schulze,et al.  Soil mineralogy with environmental applications. , 2002 .

[14]  Alessandro F. Gualtieri,et al.  Accuracy of XRPD QPA using the combined Rietveld–RIR method , 2000 .

[15]  S. Hillier Accurate quantitative analysis of clay and other minerals in sandstones by XRD: comparison of a Rietveld and a reference intensity ratio (RIR) method and the importance of sample preparation , 2000, Clay Minerals.

[16]  Lynne B. McCusker,et al.  Rietveld refinement guidelines , 1999 .

[17]  D. Bish,et al.  Quantitative mineralogical analysis using the Rietveld full-pattern fitting method , 1993 .

[18]  E. Stapel,et al.  THE USE OF THE METHYLENE BLUE ADSORPTION TEST IN ASSESSING THE QUALITY OF BASALTIC TUFF ROCK AGGREGATE , 1989 .

[19]  D. Bish,et al.  Quantitative phase analysis using the Rietveld method , 1988 .

[20]  M. Mellini The crystal structure of lizardite 1T: hydrogen bonds and polytypism , 1982 .

[21]  C. Tchoubar Crystal Structures of Clay Minerals and Their X-ray Identification , 1981, Clay Minerals.

[22]  S. W. Bailey Summary of recommendations of AIPEA Nomenclature Committee on clay minerals , 1980 .

[23]  M. Wilson,et al.  Interlayer and Intercalation Complexes of Clay Minerals , 1980 .

[24]  F. Wicks,et al.  A reappraisal of the structures of the serpentine minerals , 1975 .

[25]  Pham Till Hang,et al.  Methylene Blue Absorption by Clay Minerals. Determination of Surface Areas and Cation Exchange Capacities (Clay-Organic Studies XVIII) , 1970 .