Principles and phenomena of bioengineering with glass-ceramics for dental restoration

Abstract The main aim of this paper is to demonstrate the processes of bioengineering by controlled microstructure formation, property control and special processing. Based on the mechanisms of nucleation and crystallization, the authors deduced directions to develop of leucite-based, lithium disilicate and leucite-apatite glass-ceramics. Thus, leucite glass-ceramics were developed by surface nucleation and crystallization. Viscous flow pressing and CAD/CAM are the preferred methods of processing single units for dental restoration. Lithium disilicate glass-ceramics were developed by heterogeneous nucleation and crystallization. The microstructure resulted in a flexural strength of approximately 400 MPa of the material. The glass-ceramic is translucent and processing by pressing of CAD/CAM in a two step process is possible. Veneered with an apatite containing glass-ceramic, the material is used as three-unit dental bridge. Fundamental research showed improvement of flexural strength. Leucite and apatite were precipitated according to a two-fold nucleation and crystallization mechanism. The final result is a material characterized by translucency and a high C.T.E., that allows veneering of metal frameworks for dental restoration.

[1]  R. Müller,et al.  Coarsening of needle-shaped apatite crystals in SiO2 • Al2O3 • Na2O • K2O • CaO • P2O5 • F glass , 1999 .

[2]  M. Bredig Isomorphism and allotropy in compounds of the type A_2XO_4 , 1942 .

[3]  P. Hagenmuller,et al.  Structure of the low‐temperature variety of calcium sodium orthophosphate, NaCaPO4 , 1983 .

[4]  M. Frank,et al.  Surface crystallization of leucite in glasses , 1995 .

[5]  H. Eckert,et al.  Apatite Crystallization in an Aluminosilicate Glass Matrix: Mechanistic Studies by X-ray Powder Diffraction, Thermal Analysis, and Multinuclear Solid-State NMR Spectroscopy , 2001 .

[6]  W. J. O'brien,et al.  An outline of dental materials and their selection , 1978 .

[7]  W. Höland,et al.  Influence of ZrO2 on the crystallization and properties of lithium disilicate glass-ceramics derived from a multi-component system , 2007 .

[8]  George H. Beall,et al.  Glass Ceramic Technology , 2002 .

[9]  Edgar Dutra Zanotto Metastable phases in lithium disilicate glasses , 1997 .

[10]  W H Mörmann,et al.  The Cerec 3--a quantum leap for computer-aided restorations: initial clinical results. , 2000, Quintessence international.

[11]  W. Höland,et al.  Effect of ZnO on the crystallization, microstructure, and properties of glass-ceramics in the SiO2-Li2O-ZnO-K2O-P2O5 system , 2001 .

[12]  J. Deubener,et al.  Induction time analysis of nucleation and crystal growth in di- and metasilicate glasses , 1993 .

[13]  T. Headley,et al.  Crystallization of a Glass‐Ceramic by Epitaxial Growth , 1984 .

[14]  M. Frank,et al.  A comparison of the microstructure and properties of the IPS Empress 2 and the IPS Empress glass-ceramics. , 2000, Journal of biomedical materials research.

[15]  W. Höland,et al.  Studies of crystal phase formations in high-strength lithium disilicate glass–ceramics , 2006 .

[16]  W. Höland,et al.  Control of nucleation in glass ceramics , 2003, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.