A two-phase Eulerian approach using relative permeability concept for modeling of hydrodynamics in trickle-bed reactors at elevated pressure

Most commercial trickle-bed reactors (TBRs) employed in hydroprocessing and other industrially relevant operations normally operate at elevated pressures. Two-phase pressure drop and liquid holdup are two foremost important hydrodynamic parameters to consider for analysis and design of a TBR, including those operating at higher pressures. Even after several decades of research efforts directed towards the development of TBR technology, know-how about the hydrodynamics of two-phase flow in a TBR especially operating at high-pressure conditions has been inadequate. In this study, an effort has been made to assess the complex hydrodynamics of high-pressure TBR through the development of a Computational Fluid Dynamics (CFD) based model to predict pressure drop and liquid saturation. A two-phase Eulerian CFD model envisaging the flow field as porous region has been utilized for evaluating these hydrodynamic parameters. Different combinations of relative permeability correlations in the closure terms have been exercised to realize the best fit. The comparisons between model predictions and numerous experimental data, collected from different independent sources under a varied set of operating conditions, lead to the favourable implementation of this less computationally intensive, yet first-principle based CFD model to forecast the two-phase hydrodynamics for high-pressure TBRs.

[1]  Gary Edward Mueller,et al.  Radial void fraction distributions in randomly packed fixed beds of uniformly sized spheres in cylindrical containers , 1992 .

[2]  Krishna D.P. Nigam,et al.  Liquid distribution in trickle-bed reactors , 1998 .

[3]  Lynn F. Gladden,et al.  Magnetic resonance imaging as a quantitative probe of gas–liquid distribution and wetting efficiency in trickle-bed reactors , 2001 .

[4]  Shantanu Roy,et al.  CFD Prediction of Hydrodynamics in High-Pressure Trickle Bed Reactor , 2009 .

[5]  Klaas R. Westerterp,et al.  The transition between trickle flow and pulse flow in a cocurrent gas—liquid trickle-bed reactor at elevated pressures , 1990 .

[6]  Milorad P. Dudukovic,et al.  CFD of multiphase flow in packed‐bed reactors: I. k‐Fluid modeling issues , 2002 .

[7]  K. Nigam,et al.  RECENT DEVELOPMENTS ON HYDROPROCESSING REACTORS , 2003 .

[8]  Janez Levec,et al.  Flow through packed bed reactors: 2. Two-phase concurrent downflow , 2005 .

[9]  Ruben G. Carbonell,et al.  hydrodynamic parameters for gas-liquid cocurrent flow in packed beds , 1985 .

[10]  Milorad P. Dudukovic,et al.  Statistical characterization of macroscale multiphase flow textures in trickle beds , 2001 .

[11]  V. Specchia,et al.  Hydrodynamics and solid‐liquid contacting effectiveness in trickle‐bed reactors , 1978 .

[12]  Vivek V. Ranade,et al.  Liquid Distribution and RTD in Trickle Bed Reactors: Experiments and CFD Simulations , 2008 .

[13]  A. Attou Hydrodynamics in a Pressurized Cocurrent Gas‐Liquid Trickle‐Bed Reactor: A Physical Model , 1999 .

[14]  Milorad P. Dudukovic,et al.  CFD of multiphase flow in packed-bed reactors: II. Results and applications , 2002 .

[15]  Klaas R. Westerterp,et al.  Hydrodynamics in a cocurrent gas-liquid trickle bed at elevated pressures , 1991 .

[16]  Christophe Boyer,et al.  Modelling of the hydrodynamics of the cocurrent gas–liquid trickle flow through a trickle-bed reactor , 1999 .

[17]  Arno de Klerk,et al.  Voidage variation in packed beds at small column to particle diameter ratio , 2003 .

[18]  Shantanu Roy,et al.  Prediction of pressure drop and liquid holdup in trickle bed reactor using relative permeability concept in CFD , 2007 .

[19]  Vivek V. Ranade,et al.  Hydrodynamics of Trickle-Bed Reactors: Experiments and CFD Modeling , 2005 .

[20]  Krishna D.P. Nigam,et al.  Modeling hydrodynamics of trickle-bed reactors at high pressure , 2002 .

[21]  Janez Levec,et al.  Hydrodynamics of trickling flow in packed beds: Relative permeability concept , 2002 .

[22]  Krishna D.P. Nigam,et al.  TRICKLE BED REACTORS , 1996 .

[23]  G. Eigenberger,et al.  Fluid flow through catalyst filled tubes , 1997 .

[24]  J. Levec,et al.  The hydrodynamics of trickling flow in packed beds operating at high pressures. The relative permeability concept , 2001 .

[25]  Gary Edward Mueller,et al.  Prediction of Radial Porosity Distributions in Randomly Packed Fixed Beds of Uniformly Sized Spheres in Cylindrical Containers , 1991 .

[26]  Faïçal Larachi,et al.  Experimental study of a trickle-bed reactor operating at high pressure: two-phase pressure drop and liquid saturation , 1991 .

[27]  K. Westerterp,et al.  The influence of the reactor pressure on the hydrodynamics in a cocurrent gas-liquid trickle-bed reactor , 1990 .

[28]  Milorad P. Dudukovic,et al.  Pressure drop and liquid holdup in high pressure trickle-bed reactors , 1994 .

[29]  Shantanu Roy,et al.  Investigation of liquid maldistribution in trickle-bed reactors using porous media concept in CFD , 2007 .

[30]  S. Ergun Fluid flow through packed columns , 1952 .

[31]  Rodrigo J. G. Lopes,et al.  Turbulence modelling of multiphase flow in high-pressure trickle-bed reactors , 2009 .