The pure rotational spectrum of water vapor—A millimeter, submillimeter, and far infrared analysis

Line positions, strengths, and absolute energies are calculated for the pure rotational spectrum of water in the region between 0 cm−1 and 877 cm−1. These calculations are done in the context of a reduced centrifugal distortion Hamiltonian, and are based on microwave measurements of this spectrum to 1 THz, and Far Infrared measurements between 32 cm−1 and 715 cm−1.

[1]  J. Flaud,et al.  The 2v 2, v 1 and v 3 bands of H2 16O , 1973 .

[2]  J. Flaud,et al.  Water vapour line parameters from microwave to medium infrared: An atlas of H2O-16, H2O-17 and H2O-18 line positions and intensities between 0 and 4350/cm , 1981 .

[3]  R. Cook,et al.  Millimeter and Submillimeter Wave Rotational Spectrum and Centrifugal Distortion Effects of HDO , 1971 .

[4]  F. D. Lucia,et al.  Extension of Microwave Absorption Spectroscopy to 0.37-mm Wavelength , 1970 .

[5]  Walter Gordy,et al.  Microwave Molecular Spectra , 1970 .

[6]  R. Cook,et al.  Submillimeter Microwave Spectrum ofH2O16 , 1972 .

[7]  Frank C. De Lucia,et al.  Continuously tunable coherent spectroscopy for the 0.1–1.0‐THz region , 1983 .

[8]  J. Bellet,et al.  Application of Watson's centrifugal distortion theory to water and light asymmetric tops. General methods. Analysis of the ground state and the ν2 state of D2O16 , 1973 .

[9]  J. Watson Determination of Centrifugal Distortion Coefficients of Asymmetric‐Top Molecules , 1967 .

[10]  F. X. Kneizys,et al.  Reduction of the Fourth‐Order Asymmetric‐Rotor Hamiltonian , 1966 .

[11]  R. Cook,et al.  Molecular force field and structure of water: Recent microwave results , 1974 .

[12]  J. Flaud,et al.  High resolution Fourier transform spectrum of water between 2930 and 4255 cm-1 , 1973 .

[13]  E. Bright Wilson,et al.  The Vibration‐Rotation Energy Levels of Polyatomic Molecules I. Mathematical Theory of Semirigid Asymmetrical Top Molecules , 1936 .

[14]  R. Cook,et al.  Microwave spectrum and centrifugal distortion effects of HDS , 1971 .

[15]  William H. Kirchhoff,et al.  On the calculation and interpretation of centrifugal distortion constants: A statistical basis for model testing: The calculation of the force field , 1972 .

[16]  R. Cook,et al.  Millimeter and submillimeter wave rotational spectrum and centrifugal distortion effects of D2S , 1972 .

[17]  Jyrki K. Kauppinen,et al.  High-resolution spectrum of water vapor between 30 and 720 cm−1 , 1978 .