Overview of Sensors and Needs for Environmental Monitoring

This paper surveys the needs associated with environmental monitoring and long-term environmental stewardship. Emerging sensor technologies are reviewed to identify compatible technologies for various environmental monitoring applications. The contaminants that are considered in this report are grouped into the following categories: (1) metals, (2) radioisotopes, (3) volatile organic compounds, and (4) biological contaminants. United States regulatory drivers are evaluated for different applications (e.g., drinking water, storm water, pretreatment, and air emissions), and sensor requirements are derived from these regulatory metrics. Sensor capabilities are then summarized according to contaminant type, and the applicability of the different sensors to various environmental monitoring applications is discussed.

[1]  E. D. Cyan Handbook of Chemistry and Physics , 1970 .

[2]  H. S. Wolff,et al.  iRun: Horizontal and Vertical Shape of a Region-Based Graph Compression , 2022, Sensors.

[3]  E. Grill,et al.  Phytochelatins: The Principal Heavy-Metal Complexing Peptides of Higher Plants , 1985, Science.

[4]  E. Paleček,et al.  Adsorptive stripping voltammetry of biomacromolecules with transfer of the adsorbed layer , 1986 .

[5]  E. Paleček,et al.  New trends in electrochemical analysis of nucleic acids , 1988 .

[6]  E. Paleček,et al.  Adsorptive transfer stripping voltammetry: determination of nanogram quantities of DNA immobilized at the electrode surface. , 1988, Analytical biochemistry.

[7]  E. Paleček,et al.  Adsorptive transfer stripping voltammetry: effect of electrode potential on the structure of DNA adsorbed at the mercury surface , 1992 .

[8]  O. Mullins,et al.  First Observation of the Urbach Tail in a Multicomponent Organic System , 1992 .

[9]  O. Mullins,et al.  The Electronic Absorption Edge of Petroleum , 1992 .

[10]  Stephen A. Dyer,et al.  Digital signal processing , 2018, 8th International Multitopic Conference, 2004. Proceedings of INMIC 2004..

[11]  M. Fedurco,et al.  Adsorption study of cysteine, N-acetylcysteamine, cysteinesulfinic acid and cysteic acid on a polycrystalline gold electrode , 1994 .

[12]  W. Wampler,et al.  Low-energy beta spectroscopy using pin diodes to monitor tritium surface contamination , 1994 .

[13]  L. Wilson,et al.  Handbook of Vadose Zone Characterization & Monitoring , 1994 .

[14]  R. Crooks,et al.  SAW chemical sensor arrays using new thin-film materials , 1994 .

[15]  M. Friedrichs A model-free algorithm for the removal of baseline artifacts , 1995, Journal of biomolecular NMR.

[16]  R. V. Matalucci,et al.  Characterization, monitoring, and sensor technology catalogue , 1995 .

[17]  E. DeYoe,et al.  Reduction of physiological fluctuations in fMRI using digital filters , 1996, Magnetic resonance in medicine.

[18]  PRETREATMENT REGULATIONS FOR EXISTING AND NEW SOURCES OF POLLUTION , 1996 .

[19]  M. Zenk Heavy metal detoxification in higher plants--a review. , 1996, Gene.

[20]  R. Tauler,et al.  CADMIUM-BINDING PROPERTIES OF GLUTATHIONE: A CHEMOMETRICAL ANALYSIS OF VOLTAMMETRIC DATA , 1997 .

[21]  R. Niessner,et al.  Field screening Europe : proceedings of the First International Conference on Strategies and Techniquies for the Investigation and Monitoring of Contaminated Sites , 1997 .

[22]  D. Blair Evaluation of an evanescent fiber optic chemical sensor for monitoring aqueous volatile organic compounds , 1997 .

[23]  R. C. Hughes,et al.  A simple ionizing radiation spectrometer/dosimeter based on radiation sensing field effect transistors (RadFETs) , 1997, Proceedings of International Solid State Sensors and Actuators Conference (Transducers '97).

[24]  E. Paleček,et al.  Adsorptive stripping square-wave voltammetry of DNA , 1997 .

[25]  H. A. Johnsen,et al.  Performance testing of a Laser-Induced Breakdown Spectroscopy (LIBS) based continuous metal emissions monitor at a pyrolytic waste treatment facility , 1997 .

[26]  R. Pease,et al.  Common-source TLD and RADFET characterization of Co-60, Cs-137, and X-ray irradiation sources [bipolar linear ICs] , 1997, 1997 IEEE Radiation Effects Data Workshop NSREC Snowmass 1997. Workshop Record Held in conjunction with IEEE Nuclear and Space Radiation Effects Conference.

[27]  M. Fedurco,et al.  The anodic reactions at mercury electrodes due to cysteine , 1997 .

[28]  I. Šestáková,et al.  Voltammetric Methods for Speciation of Plant Metallothioneins , 1998 .

[29]  R. Tauler,et al.  STUDY OF THE ZINC-BINDING PROPERTIES OF GLUTATHIONE BY DIFFERENTIAL PULSE POLAROGRAPHY AND MULTIVARIATE CURVE RESOLUTION , 1998 .

[30]  S. Lieberman,et al.  Cone penetrometer deployable in situ video microscope for characterizing sub-surface soil properties , 1998 .

[31]  R. Cernosek,et al.  Method and apparatus for phase and amplitude detection , 1998 .

[32]  N. I. Kanjuk,et al.  Multienzyme electrochemical sensor array for determination of heavy metal ions , 1999 .

[33]  H. Löhmannsröben,et al.  Laser-Induced Fluorescence (LIF) Spectroscopy for In Situ Analysis of Petroleum Products and Biological Oils in Soils , 1999 .

[34]  L. Toppi,et al.  Response to cadmium in higher plants , 1999 .

[35]  G. Vizkelethy,et al.  Ion beam induced charge collection (IBICC) studies of cadmium zinc telluride (CZT) radiation detectors , 1999 .

[36]  M. Casolino,et al.  Measurements of ground-level muons at two geomagnetic locations , 1999 .

[37]  B. Sures,et al.  Parasites as accumulation indicators of heavy metal pollution. , 1999, Parasitology today.

[38]  J W Gardner and P N Bartlett,et al.  Electronic Noses: Principles and Applications , 1999 .

[39]  M. Hill,et al.  Long-Range Electron Transfer through DNA Films. , 1999, Angewandte Chemie.

[40]  J. Lloyd,et al.  Whole cell- and protein-based biosensors for the detection of bioavailable heavy metals in environmental samples , 1999 .

[41]  Z. Qian,et al.  BOD measurement in the presence of heavy metal ions using a thermally-killed-Bacillus subtilis biosensor , 1999 .

[42]  I. Šestáková,et al.  Voltammetry on mercury and carbon electrodes as a tool for studies of metallothionein interactions with metal ions. , 2000, Cellular and molecular biology.

[43]  Ren Jie Kuo,et al.  Multi-sensor integration for on-line tool wear estimation through artificial neural networks and fuz , 2000 .

[44]  M. J. Kelly,et al.  Grating light reflection spectroelectrochemistry for detection of trace amounts of aromatic hydrocarbons in water , 2000 .

[45]  V. Brabec DNA sensor for the determination of antitumor platinum compounds , 2000 .

[46]  A. Mulchandani,et al.  Enhanced bioaccumulation of heavy metals by bacterial cells displaying synthetic phytochelatins. , 2000, Biotechnology and bioengineering.

[47]  C. Cobbett Phytochelatin biosynthesis and function in heavy-metal detoxification. , 2000, Current opinion in plant biology.

[48]  M. Fojta,et al.  Adsorptive Transfer Stripping AC Voltammetry of DNA Complexes with Intercalators , 2000 .

[49]  H. Löhmannsröben,et al.  In situ laser-induced fluorescence (LIF) analysis of petroleum product-contaminated soil samples. , 2000, Journal of environmental monitoring : JEM.

[50]  J. Lloyd,et al.  Bacterial metal-resistance proteins and their use in biosensors for the detection of bioavailable heavy metals. , 2000, Journal of inorganic biochemistry.

[51]  R. Tauler,et al.  Soft- and hard-modeling approaches for the determination of stability constants of metal-peptide systems by voltammetry. , 2000, Analytical biochemistry.

[52]  Stephen A. Casalnuovo,et al.  Integrated chemiresistor array for small sensor platforms , 2000, Defense, Security, and Sensing.

[53]  M. Nordberg,et al.  Metallothioneins and diseases with special reference to cadmium poisoning , 2000 .

[54]  T. Moriizumi,et al.  Radial basis neural networks for identification of volatile organic compounds , 2000 .

[55]  L. Havran,et al.  The “Presodium” Catalysis of Electroreduction of Hydrogen Ions on Mercury Electrodes by Metallothionein. An Investigation by Constant Current Derivative Stripping Chronopotentiometry , 2000 .

[56]  Yu Lu,et al.  Quantitative artificial neural network for electronic noses , 2000 .

[57]  W. S. Murray,et al.  Automated radioisotope identification using fuzzy logic and portable CZT detectors , 2000, 2000 IEEE Nuclear Science Symposium. Conference Record (Cat. No.00CH37149).

[58]  M. Dabrio,et al.  Electrochemical study of human foetal liver metallothionein: influence of the additions of cadmium and zinc , 2000 .

[59]  M. Dabrio,et al.  Study of complexing properties of the α-metallothionein domain with cadmium and/or zinc, using differential pulse polarography , 2000 .

[60]  J. Pei,et al.  Simultaneous determination and speciation of zinc, cadmium, lead, and copper in natural water with minimum handling and artifacts, by voltammetry on a gel-integrated microelectrode array. , 2000, Analytical chemistry.

[61]  M. Lehmann,et al.  Amperometric measurement of copper ions with a deputy substrate using a novel Saccharomyces cerevisiae sensor. , 2000, Biosensors & bioelectronics.

[62]  L. Kish,et al.  Identifying natural and artificial odours through noise analysis with a sampling-and-hold electronic nose , 2001 .

[63]  G. Marrazza,et al.  NEW PROCEDURES TO OBTAIN ELECTROCHEMICAL SENSORS FOR HEAVY METAL DETECTION , 2001 .

[64]  D. B. Hibbert,et al.  Electrochemical Metal Ion Sensors. Exploiting Amino Acids and Peptides as Recognition Elements , 2001 .

[65]  R. Kizek,et al.  Determination of metallothionein at the femtomole level by constant current stripping chronopotentiometry. , 2001, Analytical chemistry.

[66]  A. Willing,et al.  Lubricants based on renewable resources--an environmentally compatible alternative to mineral oil products. , 2001, Chemosphere.

[67]  Y. Vlasov,et al.  Multisensor system on the basis of an array of non-specific chemical sensors and artificial neural networks for determination of inorganic pollutants in a model groundwater. , 2001, Talanta.

[68]  M. Dabrio,et al.  Study of complexing properties of the α and β metallothionein domains with cadmium and/or zinc using electrospray ionisation mass spectrometry , 2001 .

[69]  S. Han,et al.  A methylene blue-mediated enzyme electrode for the determination of trace mercury(II), mercury(I), methylmercury, and mercury-glutathione complex. , 2001, Biosensors & bioelectronics.

[70]  J. Havel,et al.  Use of artificial neural networks for the evaluation of electrochemical signals of adenine and cytosine in mixtures interfered with hydrogen evolution , 2001 .

[71]  R. Kizek,et al.  Silver electrode as a sensor for determination of zinc in cell cultivation medium. , 2002, Analytical biochemistry.

[72]  R. Kizek,et al.  Catalytic signal of rabbit liver metallothionein on a mercury electrode: a combination of derivative chronopotentiometry with adsorptive transfer stripping. , 2002, Bioelectrochemistry.

[73]  S. Boyde Green lubricants. Environmental benefits and impacts of lubrication , 2002 .

[74]  P. Apostoli Elements in environmental and occupational medicine. , 2002, Journal of chromatography. B, Analytical technologies in the biomedical and life sciences.

[75]  O. Wolfbeis,et al.  Engineered Bacteria Based Biosensors for Monitoring Bioavailable Heavy Metals , 2002 .

[76]  Kevin A. Delin The Sensor Web: A Macro-Instrument for Coordinated Sensing , 2002 .

[77]  M. Erk,et al.  Evaluation of different purification procedures for the electrochemical quantification of mussel metallothioneins. , 2002, Talanta.

[78]  B. Yosypchuk,et al.  Cathodic stripping voltammetry of cysteine using silver and copper solid amalgam electrodes. , 2002, Talanta.

[79]  M. Quinn,et al.  THE APPLICATION OF LASER-INDUCED FLUORESCENCE TECHNIQUES FOR THE MEASUREMENT OF HYDROCARBONS IN THE GROUNDWATER OF KUWAIT , 2002 .

[80]  V. Kuban,et al.  Mass Spectrometric Study of Platinum Complexes Based on Cisplatin , 2002 .

[81]  Yue Wang,et al.  A Novel Methodology to Cancel the Additive Colored Noise for Real-Time Communication Application , 2002 .

[82]  M. Fojta Electrochemical Sensors for DNA Interactions and Damage , 2002 .

[83]  M. Dabrio,et al.  Recent developments in quantification methods for metallothionein. , 2002, Journal of inorganic biochemistry.

[84]  R. C. Hughes,et al.  In-Situ Chemiresistor Sensor Package for Real-Time Detection of Volatile Organic Compounds in Soil and Groundwater , 2002 .

[85]  S. Jefferis Vadose Zone Science and Technology Solutions , 2002 .

[86]  F. Jelen,et al.  DNA and PNA sensing on mercury and carbon electrodes by using methylene blue as an electrochemical label. , 2002, Bioelectrochemistry.

[87]  C. Cobbett,et al.  Phytochelatins and metallothioneins: roles in heavy metal detoxification and homeostasis. , 2002, Annual review of plant biology.

[88]  R. Kizek,et al.  Voltammetry of two single-stranded isomeric end-labeled -SH deoxyoligonucleotides on mercury electrodes. , 2002, Talanta.

[89]  D. Adkins,et al.  Portable explosives detection system : MicroHound. , 2003 .

[90]  Wilfred Chen,et al.  Novel synthetic phytochelatin-based capacitive biosensor for heavy metal ion detection. , 2003, Biosensors & bioelectronics.

[91]  Issam Abu-Mahfouz,et al.  Drilling wear detection and classification using vibration signals and artificial neural network , 2003 .

[92]  H. Troy Nagle,et al.  Handbook of Machine Olfaction: Electronic Nose Technology , 2003 .

[93]  R. Kizek,et al.  Two-surface strategy in electrochemical DNA hybridization assays: Detection of osmium-labeled target DNA at carbon electrodes , 2003 .

[94]  L. Blevins,et al.  Laser-induced breakdown spectroscopy at high temperatures in industrial boilers and furnaces. , 2003, Applied optics.

[95]  D. Armstrong,et al.  Pore exclusion chromatography-inductively coupled plasma-mass spectrometry for monitoring elements in bacteria: a study on microbial removal of uranium from aqueous solution. , 2003, Analytical chemistry.

[96]  T. W. Speir,et al.  Temporal response of soil biochemical properties in a pastoral soil after cultivation following high application rates of undigested sewage sludge , 2003, Biology and Fertility of Soils.

[97]  R. Kizek,et al.  Electrochemical study of heavy metals and metallothionein in yeast Yarrowia lipolytica. , 2003, Bioelectrochemistry.

[98]  H. Tsai,et al.  Sol–gel derived urease-based optical biosensor for the rapid determination of heavy metals , 2003 .

[99]  J. N. Petersen,et al.  Heavy metal induced inhibition of Aspergillus niger nitrate reductase : applications for rapid contaminant detection in aqueous samples , 2003 .

[100]  Clifford K. Ho,et al.  Chemiresistor Microsensors for In-Situ Monitoring of Volatile Organic Compounds: Final LDRD Report , 2003 .

[101]  R. Kizek,et al.  Electrochemical Biosensors in Agricultural and Environmental Analysis , 2003 .

[102]  H. Masjuki,et al.  Vegetable‐based biodegradable lubricating oil additives , 2003 .

[103]  R. Hoffman,et al.  Practice Guidelines : Recommendations for the Use of Laboratory Tests to Support Poisoned Patients Who Present to the Emergency Department , 2003 .

[104]  D. W. Johnson,et al.  Sensor Web in Antarctica: Developing an Intelligent, Autonomous Platform for Locating Biological Flourishes in Cryogenic Environments , 2003 .

[105]  Ø. Mikkelsen,et al.  Amalgam Electrodes for Electroanalysis , 2003 .

[106]  B. Kuswandi Simple optical fibre biosensor based on immobilised enzyme for monitoring of trace heavy metal ions , 2003, Analytical and bioanalytical chemistry.

[107]  Juewen Liu,et al.  New highly sensitive and selective catalytic DNA biosensors for metal ions. , 2003, Biosensors & bioelectronics.

[108]  D. Townsend,et al.  The importance of glutathione in human disease. , 2003, Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie.

[109]  Scott Burleigh,et al.  The JPL Sensor Webs Project: Fielded Technology , 2003 .

[110]  N. Jaffrezic‐Renault,et al.  Biosensors based on enzyme field-effect transistors for determination of some substrates and inhibitors , 2003, Analytical and bioanalytical chemistry.

[111]  I. Šestáková,et al.  Voltammetric determination of phytochelatins using copper solid amalgam electrode. , 2003, Talanta.

[112]  D. A. Russell,et al.  Novel determination of cadmium ions using an enzyme self-assembled monolayer with surface plasmon resonance , 2003 .

[113]  A. P. V. Schaik,et al.  Bio-indicators to assess impacts of heavy metals in land-applied sewage sludge , 2003 .

[114]  H. Löhmannsröben,et al.  Application of laser-based ion mobility (IM) spectrometry for the analysis of polycyclic aromatic compounds (PAC) and petroleum products in soils. , 2003, Journal of environmental monitoring : JEM.

[115]  Jose C. Principe,et al.  Improving pattern recognition of electronic nose data with time-delay neural networks , 2003 .

[116]  M. Shamsipur,et al.  On-line preconcentration and simultaneous determination of heavy metal ions by inductively coupled plasma-atomic emission spectrometry , 2004 .

[117]  P. Hering,et al.  Laser in Environmental and Life Sciences , 2004 .

[118]  B. Sures,et al.  Parasites as a Threat to Freshwater Eels? , 2004, Science.

[119]  Ching-Mei Wu,et al.  Immobilization of metallothionein as a sensitive biosensor chip for the detection of metal ions by surface plasmon resonance. , 2004, Biosensors & bioelectronics.

[120]  N. Lewen,et al.  A rapid ICP-MS screen for heavy metals in pharmaceutical compounds. , 2004, Journal of pharmaceutical and biomedical analysis.

[121]  David W. Johnson,et al.  Sensor Web for Spatio-Temporal Monitoring of a Hydrological Environment , 2004 .

[122]  B. Sures,et al.  Significance of platinum group metals emitted from automobile exhaust gas converters for the biosphere , 2004, Environmental science and pollution research international.

[123]  M. Chudy,et al.  Multi-step analysis of Hg2+ ion inhibition of jack bean urease. , 2004, Journal of inorganic biochemistry.

[124]  A. Abdelghani,et al.  Electrical Characterization of a Thiol SAM on Gold as a First Step for the Fabrication of Immunosensors based on a Quartz Crystal Microbalance , 2004, Sensors (Basel, Switzerland).

[125]  E. Szłyk,et al.  Determination of cadmium, lead, and copper in margarines and butters by galvanostatic stripping chronopotentiometry. , 2004, Journal of agricultural and food chemistry.

[126]  B. Sures Environmental parasitology: relevancy of parasites in monitoring environmental pollution. , 2004, Trends in parasitology.

[127]  D. Barceló,et al.  Biosensors for environmental applications: Future development trends , 2004 .

[128]  S. Babkina,et al.  Amperometric biosensor based on denatured DNA for the study of heavy metals complexing with DNA and their determination in biological, water and food samples. , 2004, Bioelectrochemistry.

[129]  Larry Wasserman,et al.  All of Statistics: A Concise Course in Statistical Inference , 2004 .

[130]  M. Baldo,et al.  Remote Stripping Analysis of Lead and Copper by a Mercury-Coated Platinum Microelectrode , 2004 .

[131]  R. Kizek,et al.  Multiply osmium-labeled reporter probes for electrochemical DNA hybridization assays: detection of trinucleotide repeats. , 2004, Biosensors & bioelectronics.

[132]  Liping Dong,et al.  On-line coupling of flow injection displacement sorption preconcentration to high-performance liquid chromatography for speciation analysis of mercury in seafood. , 2004, Journal of chromatography. A.

[133]  Steve Ankuo Chien,et al.  Central Avra Valley Storage and Recovery Project (CAVSARP) Site, Tucson, Arizona: Floodwater and Soil Moisture Investigations with Extraterrestrial Applications , 2004 .

[134]  L. Havel,et al.  Electrochemical determination of lead and glutathione in a plant cell culture. , 2004, Bioelectrochemistry.

[135]  M. Heyrovský Early Polarographic Studies on Proteins , 2004 .

[136]  M. Soylak,et al.  Preconcentration‐Separation of Heavy Metal Ions in Environmental Samples by Membrane Filtration‐Atomic Absorption Spectrometry Combination , 2004 .

[137]  W. Yelton,et al.  Functionalized Nanoelectrode Arrays for In-Situ Identification and Quantification of Regulated Chemicals in Water , 2005 .

[138]  J. Sastre,et al.  Glutathione, oxidative stress and aging , 1996, AGE.

[139]  American Conference Of Governmental Industrial Hygienists 1998 Ventilation A O , 2019 .