High‐entropy oxides: Harnessing crystalline disorder for emergent functionality

[1]  A. Yakovenko,et al.  Phase Stability and Tensorial Thermal Expansion Properties of Single to High‐Entropy Rare‐Earth Disilicates , 2023, Journal of the American Ceramic Society.

[2]  J. Janek,et al.  Embracing disorder in solid-state batteries , 2022, Science.

[3]  G. Ceder,et al.  High-entropy mechanism to boost ionic conductivity , 2022, Science.

[4]  F. Gao,et al.  High-entropy MTiO3 perovskite oxides with glass-like thermal conductivity for thermoelectric applications , 2022, Journal of Alloys and Compounds.

[5]  H. Hahn,et al.  High Entropy Approach to Engineer Strongly Correlated Functionalities in Manganites , 2022, Advanced materials.

[6]  Yongjin Wang,et al.  Orientations-Dependent Metal-to-Insulator Transition in Solution-Deposited High-Entropy Nickelate Thin Films , 2022, Crystal Growth & Design.

[7]  G. Sawatzky,et al.  Entropy Engineering and Tunable Magnetic Order in the Spinel High-Entropy Oxide. , 2022, Journal of the American Chemical Society.

[8]  S. Trolier-McKinstry,et al.  Electrocaloric Effect of Perovskite High Entropy Oxide Films , 2022, Advanced Electronic Materials.

[9]  J. Miao,et al.  High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery , 2022, Science.

[10]  Yiguang Wang,et al.  Reactive flash sintering and electrical transport properties of high‐entropy (MgCoNiCuZn) 1‐ x Li x O oxides , 2022, Journal of the American Ceramic Society.

[11]  H. Hahn,et al.  Determining role of individual cations in high entropy oxides: Structure and reversible tuning of optical properties , 2022, Scripta Materialia.

[12]  R. Brand,et al.  Comprehensive investigation of crystallographic, spin-electronic and magnetic structure of (Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)3O4: Unraveling the suppression of configuration entropy in high entropy oxides , 2021, Acta Materialia.

[13]  Christina M. Rost,et al.  Searching for superconductivity in high entropy oxide Ruddlesden–Popper cuprate films , 2021, Journal of Vacuum Science & Technology A.

[14]  Zhiyong Liu,et al.  Microstructure and ferroelectric properties of high-entropy perovskite oxides with A-site disorder , 2021, Ceramics International.

[15]  K. Vecchio,et al.  A universal configurational entropy metric for high-entropy materials , 2021 .

[16]  Yuguang C. Li,et al.  A novel (La0.2Ce0.2Gd0.2Er0.2Tm0.2)2(WO4)3 high-entropy ceramic material for thermal neutron and gamma-ray shielding , 2021, Materials & Design.

[17]  Aiping Chen,et al.  High Entropy Oxide Relaxor Ferroelectrics. , 2021, ACS applied materials & interfaces.

[18]  Yiquan Wu,et al.  New optical ceramics: High-entropy sesquioxide X2O3 multi-wavelength emission phosphor transparent ceramics , 2021 .

[19]  S. Dai,et al.  High-entropy materials for catalysis: A new frontier , 2021, Science Advances.

[20]  L. An,et al.  High‐entropy oxides based on valence combinations: design and practice , 2021 .

[21]  Jyoti Gupta,et al.  Band-gap engineering in novel delafossite-type multicomponent oxides for photocatalytic degradation of methylene blue , 2021 .

[22]  Ronald I. Smith,et al.  Phase stability and structural transitions in compositionally complex LnMO3 perovskites , 2021 .

[23]  K. Świerczek,et al.  Mixed ionic-electronic transport in the high-entropy (Co,Cu,Mg,Ni,Zn)1-Li O oxides , 2021 .

[24]  J. Ting,et al.  Solution-based fabrication of high-entropy Ba(Ti,Hf,Zr,Fe,Sn)O3 films on fluorine-doped tin oxide substrates and their piezoelectric responses , 2021 .

[25]  E. Dagotto,et al.  Designing Magnetism in High Entropy Oxides , 2021, Advanced science.

[26]  K. Polychronopoulou,et al.  High entropy oxides-exploring a paradigm of promising catalysts: A review , 2021, Materials & Design.

[27]  D. Vinnik,et al.  Polysubstituted High-Entropy [LaNd](Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3 Perovskites: Correlation of the Electrical and Magnetic Properties , 2021, Nanomaterials.

[28]  A. Ievlev,et al.  Magnetic Texture in Insulating Single Crystal High Entropy Oxide Spinel Films. , 2021, ACS applied materials & interfaces.

[29]  J. Bassat,et al.  On the ionic conductivity of some zirconia-derived high-entropy oxides , 2021, Journal of the European Ceramic Society.

[30]  Yang Yang,et al.  New approach to enhance Sr-free cathode performance by high-entropy multi-component transition metal coupling , 2021, Ceramics International.

[31]  Guo‐Jun Zhang,et al.  High-entropy A2B2O7-type oxide ceramics: A potential immobilising matrix for high-level radioactive waste. , 2021, Journal of hazardous materials.

[32]  Saumen Mandal,et al.  Entropy stabilized multicomponent oxides with diverse functionality – a review , 2021, Critical Reviews in Solid State and Materials Sciences.

[33]  D. Mandrus,et al.  Synthesis method comparison of compositionally complex rare earth‐based Ruddlesden–Popper n  = 1 T′‐type cuprates , 2021 .

[34]  Zhibing Zhang,et al.  Achieved limit thermal conductivity and enhancements of mechanical properties in fluorite RE3NbO7 via entropy engineering , 2021 .

[35]  H. Yan,et al.  Multi elements substituted Aurivillius phase relaxor ferroelectrics using high entropy design concept , 2021 .

[36]  B. Lin,et al.  A novel facile strategy to suppress Sr segregation for high-entropy stabilized La0·8Sr0·2MnO3-δ cathode , 2021, Journal of Power Sources.

[37]  Yunhui Huang,et al.  Opportunities for High-Entropy Materials in Rechargeable Batteries , 2020, ACS Materials Letters.

[38]  R. Unocic,et al.  Probing the Local Site Disorder and Distortion in Pyrochlore High-Entropy Oxides. , 2020, Journal of the American Chemical Society.

[39]  Ruby Singh,et al.  High Entropy and Low Symmetry: Triclinic High-Entropy Molybdates. , 2020, Inorganic chemistry.

[40]  Shao‐hua Luo,et al.  Spinel-structured high entropy oxide (FeCoNiCrMn)3O4 as anode towards superior lithium storage performance , 2020 .

[41]  K. Berent,et al.  Stabilizing fluorite structure in ceria-based high-entropy oxides: Influence of Mo addition on crystal structure and transport properties , 2020 .

[42]  E. Quartarone,et al.  Multivariate curve resolution analysis of operando XAS data for the investigation of the lithiation mechanisms in high entropy oxides , 2020 .

[43]  H. Hahn,et al.  Lattice distortion and stability of (Co0.2Cu0.2Mg0.2Ni0.2Zn0.2)O high-entropy oxide under high pressure , 2020 .

[44]  F. Gao,et al.  Low-loss high entropy relaxor-like ferroelectrics with A-site disorder , 2020 .

[45]  T. Nagata,et al.  Exploring the First High-Entropy Thin Film Libraries: Composition Spread-Controlled Crystalline Structure. , 2020, ACS combinatorial science.

[46]  U. Anselmi-Tamburini,et al.  A new eight-cation inverse high entropy spinel with large configurational entropy in both tetrahedral and octahedral sites: Synthesis and cation distribution by X-ray absorption spectroscopy , 2020 .

[47]  D. Callegari,et al.  Lithiation Mechanism in High-Entropy Oxides as Anode Materials for Li-Ion Batteries: An Operando XAS Study , 2020, ACS applied materials & interfaces.

[48]  J. Yeh,et al.  In operando synchrotron X-ray studies of a novel spinel (Ni0.2Co0.2Mn0.2Fe0.2Ti0.2)3O4 high-entropy oxide for energy storage applications , 2020, Journal of Materials Chemistry A.

[49]  A. Deshpande,et al.  Structural and luminescent properties of Eu3+ doped multi-principal component Ce0.2Gd0.2Hf0.2La0.2Zr0.2O2 nanoparticles , 2020 .

[50]  Y. Wang,et al.  Design and synthesis of chemically complex ceramics from the perspective of entropy , 2020 .

[51]  Jeng‐Kuei Chang,et al.  High entropy spinel oxide nanoparticles for superior lithiation–delithiation performance , 2020, Journal of Materials Chemistry A.

[52]  M. Sikora,et al.  High-Entropy Perovskites as Multifunctional Metal Oxide Semiconductors: Synthesis and Characterization of (Gd0.2Nd0.2La0.2Sm0.2Y0.2)CoO3 , 2020, ACS applied electronic materials.

[53]  Manfred Martin,et al.  An innovative approach to design SOFC air electrode materials: high entropy La1−xSrx(Co,Cr,Fe,Mn,Ni)O3−δ (x = 0, 0.1, 0.2, 0.3) perovskites synthesized by the sol–gel method , 2020, Journal of Materials Chemistry A.

[54]  M. Gazda,et al.  Novel Class of Proton Conducting Materials—High Entropy Oxides , 2020 .

[55]  B. Chakoumakos,et al.  Crystal Growth and Elemental Homogeneity of the Multicomponent Rare-Earth Garnet (Lu1/6Y1/6Ho1/6Dy1/6Tb1/6Gd1/6)3Al5O12 , 2020 .

[56]  Jia Liu,et al.  Dielectric and energy storage properties of flash-sintered high-entropy (Bi0.2Na0.2K0.2Ba0.2Ca0.2)TiO3 ceramic , 2020, Ceramics International.

[57]  J. Heron,et al.  Oxides and the high entropy regime: A new mix for engineering physical properties , 2020, MRS Advances.

[58]  Ye Pan,et al.  Stabilizing oxygen vacancy in entropy-engineered CoFe2O4-type catalysts for co-prosperity of efficiency and stability in oxygen evolution reaction. , 2020, ACS applied materials & interfaces.

[59]  A. Navrotsky,et al.  Thermal Analysis of High Entropy Rare Earth Oxides , 2020, Materials.

[60]  W. Xu,et al.  High entropy (Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12: A novel high temperature stable thermal barrier material , 2020 .

[61]  G. Brennecka,et al.  Thin film growth effects on electrical conductivity in entropy stabilized oxides , 2020, 2006.14714.

[62]  C. Bridges,et al.  Predicting the Phase Stability of Multicomponent High-Entropy Compounds , 2020, Chemistry of Materials.

[63]  W. Xu,et al.  High-entropy (Y0.2Nd0.2Sm0.2Eu0.2Er0.2)AlO3: A promising thermal/environmental barrier material for oxide/oxide composites , 2020 .

[64]  Jinling Liu,et al.  Ultrafast synthesis of entropy-stabilized oxide at room temperature , 2020 .

[65]  P. Lu,et al.  Applying Configurational Complexity to the 2D Ruddlesden-Popper Crystal Structure. , 2020, ACS nano.

[66]  N. Usharani,et al.  Role of size, alio-/multi-valency and non-stoichiometry in the synthesis of phase-pure high entropy oxide (Co,Cu,Mg,Na,Ni,Zn)O. , 2020, Dalton transactions.

[67]  D. Brenner,et al.  Exchange interactions and long-range magnetic order in the (Mg,Co,Cu,Ni,Zn)O entropy-stabilized oxide: A theoretical investigation , 2020 .

[68]  M. Anik,et al.  Electrochemical performance of (MgCoNiZn)1-xLixO high entropy oxides in lithium ion batteries. , 2020, ACS applied materials & interfaces.

[69]  D. Vinnik,et al.  The new extremely substituted high entropy (Ba,Sr,Ca,La)Fe6-x(Al,Ti,Cr,Ga,In,Cu,W)xO19 microcrystals with magnetoplumbite structure , 2020 .

[70]  Ravi Kumar,et al.  Critical role of cationic local stresses on the stabilization of entropy‐stabilized transition metal oxides , 2020 .

[71]  R. Raj,et al.  Reactive flash sintering of the entropy-stabilized oxide Mg0.2Ni0.2Co0.2Cu0.2Zn0.2O , 2020 .

[72]  Yanchun Zhou,et al.  Theoretical prediction on thermal and mechanical properties of high entropy (Zr0.2Hf0.2Ti0.2Nb0.2Ta0.2)C by deep learning potential , 2020 .

[73]  P. Torelli,et al.  Stabilization by Configurational Entropy of the Cu(II) Active Site during CO Oxidation on Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O , 2020, The journal of physical chemistry letters.

[74]  Jiaqiang Yan,et al.  The emergent field of high entropy oxides: Design, prospects, challenges, and opportunities for tailoring material properties , 2020 .

[75]  Qianwen Zhang,et al.  Microstructure and dielectric properties of high entropy Ba(Zr0.2Ti0.2Sn0.2Hf0.2Me0.2)O3 perovskite oxides , 2020 .

[76]  E. Lara‐Curzio,et al.  On the elastic anisotropy of the entropy-stabilized oxide (Mg, Co, Ni, Cu, Zn)O compound , 2020, 2004.06613.

[77]  J. Mcmurray,et al.  Solid‐state synthesis of multicomponent equiatomic rare‐earth oxides , 2020, Journal of the American Ceramic Society.

[78]  B. S. Murty,et al.  Novel rare-earth and transition metal-based entropy stabilized oxides with spinel structure , 2020 .

[79]  Yiguang Wang,et al.  Multicomponent high-entropy zirconates with comprehensive properties for advanced thermal barrier coating , 2020 .

[80]  Aiqin Mao,et al.  Facile preparation of single phase high-entropy oxide nanocrystalline powders by solution combustion synthesis , 2020 .

[81]  Hong Chen,et al.  A new spinel high-entropy oxide (Mg0.2Ti0.2Zn0.2Cu0.2Fe0.2)3O4 with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries , 2020, RSC advances.

[82]  K. Kuramoto,et al.  A new class of spinel high-entropy oxides with controllable magnetic properties , 2020 .

[83]  K. Świerczek,et al.  Defect structure and transport properties of (Co,Cr,Fe,Mn,Ni)3O4 spinel-structured high entropy oxide , 2020 .

[84]  R. Brand,et al.  Role of intermediate 4f states in tuning the band structure of high entropy oxides , 2020, APL Materials.

[85]  L. Fu,et al.  Phase Engineering of High‐Entropy Alloys , 2020, Advanced materials.

[86]  T. Ishihara,et al.  Photocatalytic hydrogen evolution on a high-entropy oxide , 2020 .

[87]  Yanchun Zhou,et al.  High entropy (Yb0.25Y0.25Lu0.25Er0.25)2SiO5 with strong anisotropy in thermal expansion , 2020 .

[88]  R. Brand,et al.  Magnetic properties of rare-earth and transition metal based perovskite type high entropy oxides , 2020, Journal of Applied Physics.

[89]  Renkun Chen,et al.  Size disorder as a descriptor for predicting reduced thermal conductivity in medium- and high-entropy pyrochlore oxides , 2019, Scripta Materialia.

[90]  Meihong Fan,et al.  A high-entropy metal oxide as chemical anchor of polysulfide for lithium-sulfur batteries , 2019 .

[91]  Yanchun Zhou,et al.  (La0.2Ce0.2Nd0.2Sm0.2Eu0.2)PO4: A high-entropy rare-earth phosphate monazite ceramic with low thermal conductivity and good compatibility with Al2O3 , 2019 .

[92]  Qianwen Zhang,et al.  Dielectric properties and electrocaloric effect of high-entropy (Na0.2Bi0.2Ba0.2Sr0.2Ca0.2)TiO3 ceramic , 2019 .

[93]  R. Sisson,et al.  Exploration of high entropy ceramics (HECs) with computational thermodynamics - A case study with LaMnO3±δ , 2019, Materials & Design.

[94]  Shi-ze Yang,et al.  Room-temperature Synthesis of High-entropy Perovskite Oxide Nanoparticle Catalysts via Ultrasonication-based Method. , 2019, ChemSusChem.

[95]  S. Middey,et al.  Epitaxial stabilization of ultra thin films of high entropy perovskite , 2019, Applied Physics Letters.

[96]  P. Mayrhofer,et al.  High-entropy oxide thin films based on Al–Cr–Nb–Ta–Ti , 2019, Vacuum.

[97]  Hong Chen,et al.  Tunable pseudocapacitive contribution by dimension control in nanocrystalline-constructed (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O solid solutions to achieve superior lithium-storage properties , 2019, RSC advances.

[98]  K. Kuramoto,et al.  Solution combustion synthesis and magnetic property of rock-salt (Co0.2Cu0.2Mg0.2Ni0.2Zn0.2)O high-entropy oxide nanocrystalline powder , 2019, Journal of Magnetism and Magnetic Materials.

[99]  X. Ren,et al.  Equiatomic quaternary (Y1/4Ho1/4Er1/4Yb1/4)2SiO5 silicate: A perspective multifunctional thermal and environmental barrier coating material , 2019, Scripta Materialia.

[100]  M. Kunz,et al.  Stability and Compressibility of Cation-Doped High-Entropy Oxide MgCoNiCuZnO5 , 2019, The Journal of Physical Chemistry C.

[101]  Jia Liu,et al.  High-entropy environmental barrier coating for the ceramic matrix composites , 2019, Journal of the European Ceramic Society.

[102]  Z. Grzesik,et al.  Defect structure and transport properties in (Co,Cu,Mg,Ni,Zn)O high entropy oxide , 2019, Journal of the European Ceramic Society.

[103]  H. Hahn,et al.  On the homogeneity of high entropy oxides: An investigation at the atomic scale , 2019, Scripta Materialia.

[104]  Shi-ze Yang,et al.  Mechanochemical Synthesis of High Entropy Oxide Materials under Ambient Conditions: Dispersion of Catalysts via Entropy Maximization , 2019, ACS Materials Letters.

[105]  S. Holé,et al.  Charge compensation mechanisms in Li‐substituted high‐entropy oxides and influence on Li superionic conductivity , 2019, Journal of the American Ceramic Society.

[106]  Yanhua Cui,et al.  A high entropy oxide (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O) with superior lithium storage performance , 2019, Journal of Alloys and Compounds.

[107]  Qingsong Wang,et al.  High entropy oxides as anode material for Li-ion battery applications: A practical approach , 2019, Electrochemistry Communications.

[108]  H. Takagi,et al.  Long-range magnetic ordering in rocksalt-type high-entropy oxides , 2019, Applied Physics Letters.

[109]  Jiaqiang Yan,et al.  Long-Range Antiferromagnetic Order in a Rocksalt High Entropy Oxide , 2019, Chemistry of Materials.

[110]  J. Schoenung,et al.  Entropic phase transformation in nanocrystalline high entropy oxides , 2018, Materials Research Letters.

[111]  Stéphane Gorsse,et al.  About the Reliability of CALPHAD Predictions in Multicomponent Systems , 2018, Entropy.

[112]  Christina M. Rost,et al.  Charge‐Induced Disorder Controls the Thermal Conductivity of Entropy‐Stabilized Oxides , 2018, Advanced materials.

[113]  Q. Shen,et al.  Microstructural evolution and mechanical properties of (Mg,Co,Ni,Cu,Zn)O high‐entropy ceramics , 2018, Journal of the American Ceramic Society.

[114]  L. An,et al.  A five-component entropy-stabilized fluorite oxide , 2018, Journal of the European Ceramic Society.

[115]  J. Maria,et al.  Epitaxial entropy-stabilized oxides: growth of chemically diverse phases via kinetic bombardment , 2018, MRS Communications.

[116]  W. Chueh,et al.  The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting , 2018 .

[117]  Tyler J. Harrington,et al.  High-entropy fluorite oxides , 2018, Journal of the European Ceramic Society.

[118]  M. Chi,et al.  Entropy-stabilized metal oxide solid solutions as CO oxidation catalysts with high-temperature stability , 2018 .

[119]  Daniel B. Miracle,et al.  Development and exploration of refractory high entropy alloys—A review , 2018, Journal of Materials Research.

[120]  J. Maria,et al.  Evidence for Jahn-Teller compression in the (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxide: A DFT study , 2018 .

[121]  Manfred Martin,et al.  Synthesis and microstructure of the (Co,Cr,Fe,Mn,Ni) 3 O 4 high entropy oxide characterized by spinel structure , 2018 .

[122]  H. Hahn,et al.  Rare earth and transition metal based entropy stabilised perovskite type oxides , 2017 .

[123]  C. M. Handley,et al.  Phase stability and distortion in high-entropy oxides , 2017 .

[124]  H. Hahn,et al.  Multicomponent equiatomic rare earth oxides with a narrow band gap and associated praseodymium multivalency. , 2017, Dalton transactions.

[125]  J. Maria,et al.  Local structure of the MgxNixCoxCuxZnxO(x=0.2) entropy‐stabilized oxide: An EXAFS study , 2017 .

[126]  S. Franger,et al.  Controlled Jahn-Teller distortion in (MgCoNiCuZn)O-based high entropy oxides , 2017 .

[127]  P. Liaw,et al.  Cuckoo searching optimal composition of multicomponent alloys by molecular simulations , 2017 .

[128]  C. Kübel,et al.  Multicomponent equiatomic rare earth oxides , 2017 .

[129]  H. Hahn,et al.  Nanocrystalline multicomponent entropy stabilised transition metal oxides , 2017 .

[130]  D. Miracle,et al.  A critical review of high entropy alloys and related concepts , 2016 .

[131]  Cormac Toher,et al.  Charge compensation and electrostatic transferability in three entropy-stabilized oxides: Results from density functional theory calculations , 2016 .

[132]  S. Franger,et al.  Room temperature lithium superionic conductivity in high entropy oxides , 2016 .

[133]  S. Franger,et al.  Colossal dielectric constant in high entropy oxides , 2016, 1602.07842.

[134]  Jacob L. Jones,et al.  Entropy-stabilized oxides , 2015, Nature Communications.

[135]  G. Rossetti,et al.  Thermodynamics of Ferroelectric Solid Solutions with Morphotropic Phase Boundaries , 2014 .

[136]  M. Brunelli,et al.  Defect Structure of Y-Doped Ceria on Different Length Scales , 2013 .

[137]  M. Wong,et al.  Structure and properties of reactively-sputtered AlxCoCrCuFeNi oxide films , 2007 .

[138]  B. Cantor,et al.  Microstructural development in equiatomic multicomponent alloys , 2004 .

[139]  T. Shun,et al.  Nanostructured High‐Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes , 2004 .

[140]  S. Ranganathan,et al.  Alloyed pleasures: Multimetallic cocktails , 2003 .

[141]  Daniel F. Styer,et al.  Insight into entropy , 2000 .

[142]  J. Mauro.  Broken Ergodicity , 2021, Materials Kinetics.

[143]  A. Navrotsky,et al.  Thermodynamics of high entropy oxides , 2021 .

[144]  A. Salimi,et al.  One-step synthesis of single-phase (Co, Mg, Ni, Cu, Zn) O High entropy oxide nanoparticles through SCS procedure: Thermodynamics and experimental evaluation , 2021 .

[145]  A. Ghoshal,et al.  Sand corrosion, thermal expansion, and ablation of medium‐ and high‐entropy compositionally complex fluorite oxides , 2020 .

[146]  Chenglong Zhao,et al.  High-entropy chemistry stabilizing layered O3-type structure in Na-ion cathode. , 2019, Angewandte Chemie.

[147]  W. Kriven,et al.  High‐entropy, phase‐constrained, lanthanide sesquioxide , 2019, Journal of the American Ceramic Society.

[148]  Tyler J. Harrington,et al.  A new class of high-entropy perovskite oxides , 2018 .

[149]  Robert T. DeHoff,et al.  Thermodynamics in Materials Science , 1993 .