How to measure the isothermal compressibility of liquids accurately

A survey of published data on water and mercury has revealed that conventional methods of measuring compressibility are inaccurate. An analysis of the form of the discrepancies in the data has indicated that anisotropic distortion of the apparatus and air entrainment are the two principal sources of error. Means of eliminating these and other sources of error are described. By utilizing the principles of accurate measurement outlined in this paper, the isothermal compressibility of liquids can be measured several times more accurately than has been achieved before.

[1]  P. W. Bridgman The Pressure‐Volume‐Temperature Relations of the Liquid, and the Phase Diagram of Heavy Water , 1935 .

[2]  J. Boelhouwer PVT relations of five liquid n-alkanes , 1960 .

[3]  L. J. Hudleston Intermolecular forces of normal liquids , 1937 .

[4]  F. G. Keyes,et al.  The Volume of Unit Mass of Liqud Water and Their Correlation as a Function of Pressure and Temperature. Part III. Stem Research Program , 1934 .

[5]  A. Hayward Measuring the Extensibility Liquids , 1964, Nature.

[6]  L. Adams EQUILIBRIUM IN BINARY SYSTEMS UNDER PRESSURE. I. AN EXPERIMENTAL AND THERMODYNAMIC INVESTIGATION OF THE SYSTEM, NaCl-H2O, AT 25° , 1931 .

[7]  P. Carnazzi Influenza della pressione e della temperatura sul coefficiente di compressibilita del mercurio , 1903 .

[8]  M. L. Mcglashan,et al.  An apparatus for the measurement of the isothermal compressibility of liquids. The compressibility of mercury, of carbon tetrachloride, and of water , 1959 .

[9]  O. Anderson,et al.  The use of ultrasonic measurements under modest pressure to estimate compression at high pressure , 1966 .

[10]  P. W. Bridgman Thermodynamic Properties of Liquid Water to 80° and 12000 Kgm , 1912 .

[11]  A. Talbott XCVI.Velocity of waves in oil under pressure , 1935 .

[12]  G. Kennedy,et al.  Properties of water; Part III, Specific volume of liquid water to 100 degrees C and 1400 bars , 1958 .

[13]  A. Hayward Experimental Verification at High Pressure of the Relationship between Compression, Density and Sonic Velocity , 1969, Nature.

[14]  W. Webb,et al.  Study of the Compressions of Several High Molecular Weight Hydrocarbons , 1958 .

[15]  E. Whalley,et al.  The PVT properties of water , 1965, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

[16]  G. Tammann,et al.  Die Volumenisobaren des Wassers bis zur Schmelzkurve , 1928 .

[17]  J. Ross Macdonald,et al.  Some Simple Isothermal Equations of State , 1966 .

[18]  D. Tyrer CLXXXI.—Adiabatic and isothermal compressibilities of some liquids between one and two atmospheres pressure , 2022 .

[19]  Robert B. Gordon,et al.  Compression of Mercury at High Pressure , 1967 .

[20]  A T J Hayward,et al.  Compressibility equations for liquids: a comparative study , 1967 .

[21]  P. W. Bridgman Mercury, Liquid and Solid, under Pressure , 1911 .

[22]  H. Kramers,et al.  Collected scientific papers , 1956 .