Biodiesel production from Calophyllum inophyllum−palm mixed oil

ABSTRACT The objective of this study is to investigate the biodiesel production from Calophyllum inophyllum −palm mixed oil. The C. inophyllum–palm biodiesel (C. inophyllum palm oil methyl ester, CPME) is first produced by mixing the crude oils at an equal ratio of 50:50 vol%, followed by degumming, acid-catalyzed esterification, purification, and, last, alkaline-catalyzed transesterification. With this systematic procedure, the acid value of the CPME is 0.4 mg KOH/g, resulting in a significant enhancement of oxidation stability (114.21 h). The results indicate that the fatty acid methyl ester composition of the CPME may be the reason for its larger higher heating value (39.4 MJ/kg) and lower kinematic viscosity (4.15 mm2/s). In short, CPME satisfied the ASTM D6751 and EN 14214 standards as a promising alternative fuel in the future.

[1]  S. K. Awasthi,et al.  Antidyslipidemic and antioxidant activity of the constituents isolated from the leaves of Calophyllum inophyllum. , 2012, Phytomedicine : international journal of phytotherapy and phytopharmacology.

[2]  Gerhard Knothe,et al.  SOME ASPECTS OF BIODIESEL OXIDATIVE STABILITY , 2007 .

[3]  Georgi Hristov,et al.  Effect of commercially available antioxidants over biodiesel/diesel blends stability , 2009 .

[4]  U. Schuchardt,et al.  Transesterification of vegetable oils: a review , 1998 .

[5]  A. Demirbas,et al.  Relationships derived from physical properties of vegetable oil and biodiesel fuels , 2008 .

[6]  G. Kombe Re-esterification of high free fatty acid oils for biodiesel production , 2015 .

[7]  Z. Yaakob,et al.  A review on the oxidation stability of biodiesel , 2014 .

[8]  Bemgba Bevan Nyakuma,et al.  The challenges and prospects of palm oil based biodiesel in Malaysia , 2015 .

[9]  Abderrahim Bouaid,et al.  Long storage stability of biodiesel from vegetable and used frying oils , 2007 .

[10]  Antonio J. A. Meirelles,et al.  Flash points of mixtures containing ethyl esters or ethylic biodiesel and ethanol , 2012 .

[11]  Ee Sann Tan,et al.  Biodiesel for Gas Turbine Application — An Atomization Characteristics Study , 2013 .

[12]  M. Babu,et al.  Biodiesel development from high acid value polanga seed oil and performance evaluation in a CI engine , 2007 .

[13]  F. Mjalli,et al.  A Solid Organic Acid Catalyst for the Pretreatment of Low-Grade Crude Palm Oil and Biodiesel Production , 2014 .

[14]  许旱峤,et al.  Kirk-Othmer Encyclopedia of Chemical Technology数据库介绍及实例 , 2007 .

[15]  Folasegun A. Dawodu,et al.  Production of biodiesel from Calophyllum inophyllum oil using a cellulose-derived catalyst. , 2014 .

[16]  Aninidita Karmakar,et al.  Properties of various plants and animals feedstocks for biodiesel production. , 2010, Bioresource technology.

[17]  Choo Yuen May,et al.  The effect of natural and synthetic antioxidants on the oxidative stability of palm diesel , 2006 .

[18]  Idris A. Musa The effects of alcohol to oil molar ratios and the type of alcohol on biodiesel production using transesterification process , 2016 .

[19]  M. Hanna,et al.  Biodiesel production : a review , 1999 .

[20]  Hwai Chyuan Ong,et al.  Synthesis and optimization of Hevea brasiliensis and Ricinus communis as feedstock for biodiesel production: A comparative study , 2016 .

[21]  Hwai Chyuan Ong,et al.  Overview properties of biodiesel diesel blends from edible and non-edible feedstock , 2013 .

[22]  Tony E Grift,et al.  ffect of biodiesel on engine performances and emissions , 2010 .

[23]  K. Gopal,et al.  Effect of pongamia biodiesel on emission and combustion characteristics of DI compression ignition engine , 2015 .

[24]  Robert L. McCormick,et al.  Impact of Biodiesel Blends on Fuel System Component Durability , 2006 .

[25]  Hwai Chyuan Ong,et al.  Optimization of biodiesel production and engine performance from high free fatty acid Calophyllum inophyllum oil in CI diesel engine , 2014 .

[26]  R. McCormick,et al.  Long-term storage stability of biodiesel and biodiesel blends , 2014 .

[27]  Cynthia Ofori-Boateng,et al.  Feasibility study of microalgal and jatropha biodiesel production plants: Exergy analysis approach , 2012 .