Radikalische Trifluormethoxylierung aromatischer Verbindungen durch photochemische N‐O‐Bindungsaktivierung

[1]  F. Neese,et al.  Palladium-catalysed electrophilic aromatic C–H fluorination , 2018, Nature.

[2]  Huw M. L. Davies,et al.  Collective Approach to Advancing C–H Functionalization , 2017, ACS central science.

[3]  Pinhong Chen,et al.  Catalytic Oxidative Trifluoromethoxylation of Allylic C-H Bonds Using a Palladium Catalyst. , 2017, Angewandte Chemie.

[4]  M. Kärkäs Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications , 2017 .

[5]  Lihong Zhou,et al.  Oxidation of C-H Bonds , 2017 .

[6]  Liang Wang,et al.  Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent , 2017, Nature Chemistry.

[7]  F. Glorius,et al.  Visible-Light-Promoted Activation of Unactivated C(sp3)-H Bonds and Their Selective Trifluoromethylthiolation. , 2016, Journal of the American Chemical Society.

[8]  J. McCusker,et al.  The photophysics of photoredox catalysis: a roadmap for catalyst design. , 2016, Chemical Society reviews.

[9]  E. Meggers,et al.  Catalytic Asymmetric Csp3 -H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition. , 2016, Angewandte Chemie.

[10]  M. Májek,et al.  Mechanistic Perspectives on Organic Photoredox Catalysis for Aromatic Substitutions. , 2016, Accounts of chemical research.

[11]  Anis Tlili,et al.  Ansätze zur Synthese Trifluormethoxy‐substituierter Verbindungen , 2016 .

[12]  A. Tlili,et al.  Synthetic Approaches to Trifluoromethoxy-Substituted Compounds. , 2016, Angewandte Chemie.

[13]  P. Baran,et al.  Radicals: Reactive Intermediates with Translational Potential , 2016, Journal of the American Chemical Society.

[14]  K. P. Cole,et al.  Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale. , 2016, Chem.

[15]  Jinbo Hu,et al.  O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination. , 2016, Organic letters.

[16]  X. Pannecoucke,et al.  New entries toward the synthesis of OCF3-containing molecules , 2016 .

[17]  Lipeng Yan,et al.  A facile access to substituted cationic 12-azapyrene salts by rhodium( iii )-catalyzed C–H annulation of N -arylpyridinium salts , 2016 .

[18]  C. Stephenson,et al.  Visible Light Photocatalysis: Applications and New Disconnections in the Synthesis of Pharmaceutical Agents , 2016 .

[19]  Peng Liu,et al.  Mechanistic studies on intramolecular C-H trifluoromethoxylation of (hetero)arenes via OCF3-migration. , 2016, Organic & biomolecular chemistry.

[20]  T Gensch,et al.  Mild metal-catalyzed C-H activation: examples and concepts. , 2016, Chemical Society reviews.

[21]  Jing Zhang,et al.  Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp3)-H Functionalization under Mild Reaction Conditions. , 2016 .

[22]  Xiao-Qiang Hu,et al.  Visible light photoredox-controlled reactions of N-radicals and radical ions. , 2016, Chemical Society reviews.

[23]  Yusheng Wu,et al.  Regioselective Synthesis of N-Heteroaromatic Trifluoromethoxy Compounds by Direct O-CF3 Bond Formation. , 2016, Chemistry.

[24]  Shane W. Krska,et al.  The medicinal chemist's toolbox for late stage functionalization of drug-like molecules. , 2016, Chemical Society reviews.

[25]  Jing Zhang,et al.  Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp(3))-H Functionalization under Mild Reaction Conditions. , 2016, Angewandte Chemie.

[26]  Pinhong Chen,et al.  Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes. , 2015, Journal of the American Chemical Society.

[27]  Ming‐Yu Ngai,et al.  Synthesis of Trifluoromethoxylated (Hetero)Arenes via OCF3 Migration , 2015, Synlett.

[28]  Chengbo Zhan,et al.  Access to a new class of synthetic building blocks via trifluoromethoxylation of pyridines and pyrimidines , 2015, Chemical science.

[29]  F. Qing,et al.  Silver-Mediated Oxidative Trifluoromethylation of Alcohols to Alkyl Trifluoromethyl Ethers. , 2015, Organic letters.

[30]  F. Qing,et al.  Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers. , 2015, Angewandte Chemie.

[31]  K. P. Cole,et al.  A scalable and operationally simple radical trifluoromethylation , 2015, Nature Communications.

[32]  M. D. Hill,et al.  Applications of Fluorine in Medicinal Chemistry. , 2015, Journal of medicinal chemistry.

[33]  Megan A. Cismesia,et al.  Characterizing chain processes in visible light photoredox catalysis , 2015, Chemical science.

[34]  G. Filippini,et al.  Photochemical direct perfluoroalkylation of phenols , 2015 .

[35]  Q. Shen,et al.  Shelf-stable electrophilic reagents for trifluoromethylthiolation. , 2015, Accounts of chemical research.

[36]  D. Leznoff,et al.  A convenient route to tetraalkylammonium perfluoroalkoxides from hydrofluoroethers. , 2015, Angewandte Chemie.

[37]  A. Togni,et al.  Electrophilic trifluoromethylation by use of hypervalent iodine reagents. , 2015, Chemical reviews.

[38]  Chengbo Zhan,et al.  Trifluoromethoxylation of arenes: synthesis of ortho-trifluoromethoxylated aniline derivatives by OCF3 migration. , 2014, Angewandte Chemie.

[39]  Robert J. Phipps,et al.  Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions , 2014, Chemical reviews.

[40]  L. Sigrist,et al.  O‐Trifluoromethylation of N,N‐Disubstituted Hydroxylamines with Hypervalent Iodine Reagents , 2014 .

[41]  M. Sanford,et al.  N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes , 2014, Journal of the American Chemical Society.

[42]  M. Sansotera,et al.  Recent developments in the chemistry of organic perfluoro hypofluorites , 2013 .

[43]  L. Overman,et al.  Direct construction of quaternary carbons from tertiary alcohols via photoredox-catalyzed fragmentation of tert-alkyl N-phthalimidoyl oxalates. , 2013, Journal of the American Chemical Society.

[44]  Dmitry E. Polyansky,et al.  Mechanism of the quenching of the tris(bipyridine)ruthenium(II) emission by persulfate: implications for photoinduced oxidation reactions. , 2013, The journal of physical chemistry. A.

[45]  D. MacMillan,et al.  Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis. , 2013, Chemical reviews.

[46]  D. MacMillan,et al.  Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis , 2011, Nature.

[47]  G. Sammis,et al.  Photoinduced electron-transfer-promoted redox fragmentation of N-alkoxyphthalimides. , 2011, Organic letters.

[48]  Eunsung Lee,et al.  Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids. , 2011, Journal of the American Chemical Society.

[49]  G. Argüello,et al.  Co-thermolysis: a one-pot synthetic method for novel 2-substituted-5-(trifluoromethoxy)thiophenes , 2010 .

[50]  B. Langlois,et al.  A deeper insight into direct trifluoromethoxylation with trifluoromethyl triflate , 2010 .

[51]  A. Togni,et al.  Reactivity of a 10-I-3 hypervalent iodine trifluoromethylation reagent with phenols. , 2008, The Journal of organic chemistry.

[52]  A. Coop,et al.  Trifluoromethoxyl substituted phenylethylene diamines as high affinity sigma receptor ligands with potent anti-cocaine actions. , 2008, Journal of medicinal chemistry.

[53]  J. Vors,et al.  Trifluoromethyl ethers – synthesis and properties of an unusual substituent , 2008, Beilstein journal of organic chemistry.

[54]  P. Jeschke,et al.  alpha-fluorinated ethers as "exotic" entity in medicinal chemistry. , 2007, Mini reviews in medicinal chemistry.

[55]  F. Diederich,et al.  Fluorine in Pharmaceuticals: Looking Beyond Intuition , 2007, Science.

[56]  S. Ishihara,et al.  CF3 oxonium salts, O-(trifluoromethyl)dibenzofuranium salts: in situ synthesis, properties, and application as a real CF3+ species reagent. , 2007, The Journal of organic chemistry.

[57]  Michel Waroquier,et al.  Electrophilicity and nucleophilicity index for radicals. , 2007, Organic letters.

[58]  I. Gould,et al.  Density functional theory predicts the barriers for radical fragmentation in solution. , 2005, The Journal of organic chemistry.

[59]  M. Schlosser,et al.  Alpha-fluorinated ethers, thioethers, and amines: anomerically biased species. , 2005, Chemical reviews.

[60]  Martin Stahl,et al.  Fluorine in Medicinal Chemistry , 2004, Chembiochem : a European journal of chemical biology.

[61]  C. Hadad,et al.  Computational study of the halogen atom-benzene complexes. , 2003, Journal of the American Chemical Society.

[62]  I. Gould,et al.  Kinetics of reductive N-O bond fragmentation: the role of a conical intersection. , 2002, Journal of the American Chemical Society.

[63]  I. Gould,et al.  Energetics of Electron‐Transfer Reactions of Photoinitiated Polymerization: Dye‐Sensitized Fragmentation of N‐Alkoxypyridinium Salts , 2001 .

[64]  J. Olah,et al.  Aromatic substitution. 53. Electrophilic nitration, halogenation, acylation, and alkylation of (.alpha.,.alpha.,.alpha.-trifluoromethoxy)benzene , 1987 .

[65]  E. Mcbee,et al.  Halogen-containing substituents. II. Methoxy system. Reactivity parameters. Charge distribution and conformation of the anisoles , 1972 .

[66]  W. A. Sheppard The Effect of Fluorine Substitution on the Electronic Properties of Alkoxy, Alkylthio and Alkylsulfonyl Groups , 1963 .

[67]  J. Kochi,et al.  Time-resolved spectroscopy and charge-transfer photochemistry of aromatic EDA complexes with X-pyridinium cations , 1992 .