Ferrous Polycrystalline Shape-Memory Alloy Showing Huge Superelasticity

Ferrous Shape Memory Alloy So-called shape memory alloys “remember” the shape they are processed into, and can return to that shape after being deformed by heat. A limitation for most metal-based shape memory alloys is the extent to which they can be deformed elastically. Tanaka et al. (p. 1488; see the Perspective by Ma and Karaman) demonstrate an iron-based alloy that shows much higher levels of superelastic strain, surpassing the performance of nickel-titanium alloys. In addition to high superelastic strain, this ferrous shape memory alloy has much higher strength than NiTi and copper-based shape memory alloys and, consequently, a high-energy absorption capability. These properties may allow shape memory alloys to be exploited as strain sensors or energy dampers. A shape-memory alloy has been prepared with high mechanical energy absorption capability and reversible magnetization change. Shape-memory alloys, such as Ni-Ti and Cu-Zn-Al, show a large reversible strain of more than several percent due to superelasticity. In particular, the Ni-Ti–based alloy, which exhibits some ductility and excellent superelastic strain, is the only superelastic material available for practical applications at present. We herein describe a ferrous polycrystalline, high-strength, shape-memory alloy exhibiting a superelastic strain of more than 13%, with a tensile strength above 1 gigapascal, which is almost twice the maximum superelastic strain obtained in the Ni-Ti alloys. Furthermore, this ferrous alloy has a very large damping capacity and exhibits a large reversible change in magnetization during loading and unloading. This ferrous shape-memory alloy has great potential as a high-damping and sensor material.