An Experimental Investigation of Water Transport in PEMFCs The Role of Microporous Layers

This experimental study was undertaken to resolve the contrasting viewpoints on the role of a microporous layer (MPL), attached to carbon paper porous transport layer (PTL), on the net water transport in a polymer electrolyte membrane fuel cell (PEMFC). Experimental results on single cells with and without cathode MPL show no statistically significant change in the net drag coefficient that could be attributed to the presence of the MPL. In contrast to the two prevailing but contrasting viewpoints, our results indicate that the MPL on the cathode neither enhances back-diffusion nor increases water removal from the cathode catalyst layer to the PTL.

[1]  E. Ticianelli,et al.  Effects of the cathode gas diffusion layer characteristics on the performance of polymer electrolyte fuel cells , 2002 .

[2]  M. Hori,et al.  Novel gas diffusion layer with water management function for PEMFC , 2004 .

[3]  B. Wetton,et al.  Water Management in PEM Fuel Cells , 2004 .

[4]  Michael Eikerling,et al.  Water Management in Cathode Catalyst Layers of PEM Fuel Cells A Structure-Based Model , 2006 .

[5]  G.J.M. Janssen,et al.  Water transport in the proton-exchange-membrane fuel cell: measurements of the effective drag coefficient , 2001 .

[6]  A. Shukla,et al.  Diffusion layer parameters influencing optimal fuel cell performance , 2000 .

[7]  Jon G. Pharoah,et al.  On effective transport coefficients in PEM fuel cell electrodes: Anisotropy of the porous transport layers , 2006 .

[8]  J. Song,et al.  Optimal composition of polymer electrolyte fuel cell electrodes determined by the AC impedance method , 2001 .

[9]  M. Mench,et al.  Distributed Performance of Polymer Electrolyte Fuel Cells under Low-Humidity Conditions , 2005 .

[10]  J. Moreira Influence of the hydrophobic material content in the gas diffusion electrodes on the performance of a PEM fuel cell , 2003 .

[11]  G. Maggio,et al.  Influence of electrodic properties on water management in a solid polymer electrolyte fuel cell , 1992 .

[12]  Trung Van Nguyen,et al.  A Two-Dimensional Two-Phase Model of a PEM Fuel Cell , 2006 .

[13]  Chao-Yang Wang,et al.  Two-phase transport and the role of micro-porous layer in polymer electrolyte fuel cells , 2004 .

[14]  Jin Hyun Nam,et al.  Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium , 2003 .

[15]  Adam Z. Weber,et al.  Effects of Microporous Layers in Polymer Electrolyte Fuel Cells , 2005 .

[16]  Zhigang Qi,et al.  Enhancement of PEM fuel cell performance by steaming or boiling the electrode , 2002 .

[17]  Edson A. Ticianelli,et al.  Development and electrochemical studies of gas diffusion electrodes for polymer electrolyte fuel cells , 1996 .