Tetragonal phase of epitaxial room-temperature antiferromagnet CuMnAs

Recent studies have demonstrated the potential of antiferromagnets as the active component in spintronic devices. This is in contrast to their current passive role as pinning layers in hard disk read heads and magnetic memories. Here we report the epitaxial growth of a new high-temperature antiferromagnetic material, tetragonal CuMnAs, which exhibits excellent crystal quality, chemical order and compatibility with existing semiconductor technologies. We demonstrate its growth on the III-V semiconductors GaAs and GaP, and show that the structure is also lattice matched to Si. Neutron diffraction shows collinear antiferromagnetic order with a high Néel temperature. Combined with our demonstration of room-temperature-exchange coupling in a CuMnAs/Fe bilayer, we conclude that tetragonal CuMnAs films are suitable candidate materials for antiferromagnetic spintronics.

[1]  H. Fujimori,et al.  Crystal structure and magnetic properties of the compound FeN , 1993 .

[2]  T. Jungwirth,et al.  Theory of ferromagnetic (III, Mn) V semiconductors , 2006, cond-mat/0603380.

[3]  H. Schuster,et al.  Magnetic Properties of NaMnP, NaMnAs, NaMnSb, NaMnBi, LiMnAs, and KMnAs, Characterized by Neutron Diffraction Experiments. , 1987 .

[4]  Hans‐Uwe Schuster,et al.  Neue AMnX-verbindungen mit A ↔ Rb, Cs und X ↔ P, As, Sb, Bi: Struktur und Magnetismus , 1991 .

[5]  G. Schmidt,et al.  Tunneling anisotropic magnetoresistance: a spin-valve-like tunnel magnetoresistance using a single magnetic layer. , 2004, Physical review letters.

[6]  F. Missell,et al.  Magnetic properties of NdSb, GdSb, TbSb, DySb, HbSb and ErSb under hydrostatic pressure , 1977 .

[7]  J. Hayakawa,et al.  A spin-valve-like magnetoresistance of an antiferromagnet-based tunnel junction. , 2011, Nature materials.

[8]  T. Jungwirth,et al.  Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor , 2012 .

[9]  H. Schuster,et al.  Preparation and Crystal Structure of Compounds MnCuX (X: P, As, PxAs1- x). , 1992 .

[10]  Hans‐Uwe Schuster,et al.  Die magnetischen Eigenschaften der Alkalimetall‐Manganpnictide KMnP, RbMnP, CsMnP, RbMnAs, KMnSb, KMnBi, RbMnBi und CsMnBi – Neutronenbeugungsuntersuchungen und Suszeptibilitätsmessungen , 1999 .

[11]  D. Eigler,et al.  Bistability in Atomic-Scale Antiferromagnets , 2012, Science.

[12]  Jacek K. Furdyna,et al.  Evidence for reversible control of magnetization in a ferromagnetic material by means of spin–orbit magnetic field , 2008, 0812.3160.

[13]  J. Kuběna,et al.  X‐ray double and triple crystal diffractometry of mosaic structure in heteroepitaxial layers , 1993 .

[14]  F. Zeng,et al.  Room-temperature perpendicular exchange coupling and tunneling anisotropic magnetoresistance in an antiferromagnet-based tunnel junction. , 2012, Physical review letters.

[15]  J. Wunderlich,et al.  Tunneling anisotropic magnetoresistance in multilayer-(Co/Pt)/AlO_(x)/Pt structures. , 2008, Physical review letters.

[16]  E. Nagaev Ferromagnetic and antiferromagnetic semiconductors , 1975 .

[17]  P. Wachter,et al.  Electrical resistivity of antiferromagnetic GdP , 1975 .

[18]  C. T. Foxon,et al.  Demonstration of molecular beam epitaxy and a semiconducting band structure for I-Mn-V compounds , 2011 .

[19]  S. Députier,et al.  The ternary compound Fe3Ga2 − xAsx: a promising candidate for epitaxial and thermodynamically stable contacts on GaAs , 1997 .

[20]  Sigurd Wagner,et al.  New materials and structures for photovoltaics , 1993 .

[21]  H. Ohno,et al.  Making nonmagnetic semiconductors ferromagnetic , 1998, Science.

[22]  P. E. Clark,et al.  Magnetic ordering of interstitial iron in Fe1+xSb alloys , 1981 .

[23]  J. Wunderlich,et al.  Spin gating electrical current , 2012, 1203.2439.

[24]  J. Woolley,et al.  Magnetic, transport, X-ray diffraction and Mössbauer measurements on CuFeSe2 , 1992 .

[25]  Hans‐Uwe Schuster,et al.  Zur Charakterisierung der magnetischen Eigenschaften von NaMnP, NaMnAs, NaMnSb, NaMnBi, LiMnAs und KMnAs über Neutronenbeugungsexperimente , 1986 .

[26]  J. Wunderlich,et al.  Chapter 4 Transport Properties of Ferromagnetic Semiconductors , 2008 .

[27]  B. Carlsson,et al.  Magnetic Susceptibility Resistivity and Thermal Expansion Measurements on FeP , 1977 .

[28]  J. González,et al.  Mössbauer measurements in CuFeTe2 , 1998 .

[29]  E. Albisetti,et al.  Storing magnetic information in IrMn/MgO/Ta tunnel junctions via field-cooling , 2013 .

[30]  W Wegscheider,et al.  Tunneling anisotropic magnetoresistance and spin-orbit coupling in Fe/GaAs/Au tunnel junctions. , 2007, Physical review letters.

[31]  H. Schuster,et al.  Darstellung und Kristallstruktur der Verbindungen MnCuX (X = P, As, PxAs1-x) / Preparation and Crystal Structure of Compounds MnCuX (X = P, As, PxAs1-x) , 1992 .

[32]  A. Kjekshus,et al.  Magnetic Structure and Properties of FeAs. , 1972 .

[33]  J. Wunderlich,et al.  Spin-orbit coupling induced anisotropy effects in bimetallic antiferromagnets: A route towards antiferromagnetic spintronics , 2010, 1002.2151.

[34]  Zhaohao Wang,et al.  Spintronics , 2015, ACM J. Emerg. Technol. Comput. Syst..

[35]  T. Jungwirth,et al.  Room-temperature antiferromagnetism in CuMnAs , 2012 .

[36]  H. Yoshizawa,et al.  Successive magnetic ordering in CuFeO2 : a new type of partially disordered phase in a triangular lattice antiferromagnet , 1993 .

[37]  V. Holý,et al.  X-ray triple-crystal diffractometry of defects in epitaxic layers , 1994 .

[38]  D. A. Wheeler,et al.  Studies on the heusler alloys—III. The antiferro-magnetic phase in the Cu-Mn-Sb system , 1968 .

[39]  J. Hayakawa,et al.  Electrical measurement of antiferromagnetic moments in exchange-coupled IrMn/NiFe stacks. , 2011, Physical review letters.

[40]  K. Endō Magnetic Studies of Clb-Compounds CuMnSb, PdMnSb and Cu1-x (Ni or Pd)x MnSb , 1970 .

[41]  T. Jungwirth,et al.  Molecular beam epitaxy of LiMnAs , 2010, 1009.0699.

[42]  W. Kleemann,et al.  Successive antiferromagnetic phase transitions in α-MnS probed by the exchange bias effect , 2009 .

[43]  Kido,et al.  Magnetic behavior of stoichiometric and nonstoichiometric GdAs single crystals. , 1996, Physical review. B, Condensed matter.

[44]  J. Wunderlich,et al.  Coulomb blockade anisotropic magnetoresistance effect in a (Ga,Mn)As single-electron transistor. , 2006, Physical review letters.

[45]  G. Wastlbauer,et al.  Structural and magnetic properties of ultrathin epitaxial Fe films on GaAs(001) and related semiconductor substrates , 2005 .