Inverted-Rib Chalcogenide Waveguides by Solution Process

This paper studies the fabrication and characterization of solution-processed chalcogenide waveguides by a microtrench filling method. In this process, channels are etched on substrates and backfilled with solution-dissolved arsenic sulfide before being annealed. The waveguides are homogeneous in elemental composition and have good mode confinement. Both simulation and experimental measurements confirm a dominant fundamental mode covering 2.5–2.8 μm. We measure an optical loss of 1.87 dB/cm, which to our knowledge is the lowest among solution-processed waveguides.

[1]  Craig B. Arnold,et al.  Solution-processing of thick chalcogenide-chalcogenide and metal-chalcogenide structures by spin-coating and multilayer lamination , 2013 .

[2]  Annie Pradel,et al.  CHALCOGENIDE THIN FILMS DEPOSITED BY RADIO-FREQUENCY SPUTTERING , 2004 .

[3]  C. Arnold,et al.  Pore formation and removal in solution-processed amorphous arsenic sulfide films , 2013 .

[4]  M. Mikhailov,et al.  Mechanism for interaction of amine solutions with monolithic glasses and amorphous films in the As-S system , 1997 .

[5]  Craig B. Arnold,et al.  A review on solution processing of chalcogenide glasses for optical components , 2013 .

[6]  Candice Tsay,et al.  Solution-processed chalcogenide glass for integrated single-mode mid-infrared waveguides. , 2010, Optics express.

[7]  Trevor M. Benson,et al.  Study of mid-infrared laser action in chalcogenide rare earth doped glass with Dy3+, Pr3+ and Tb3+ , 2012 .

[8]  S. Mamedov On the macromolecular mechanism of dissolution of As2S3 films in organic solutions , 1993 .

[9]  J. Orava,et al.  Inverse opal photonic crystal of chalcogenide glass by solution processing. , 2011, Journal of colloid and interface science.

[10]  B. Eggleton,et al.  Influence of Annealing Conditions on the Optical and Structural Properties of Spin-coated as 2 S 3 Chalcogenide Glass Thin Films References and Links , 2022 .

[11]  David J. Moss,et al.  Chalcogenide glass photonic crystals: progress and prospects , 2010, OPTO.

[12]  A. E. Owen,et al.  Photo-induced structural and physico-chemical changes in amorphous chalcogenide semiconductors , 1985 .

[13]  Craig B. Arnold,et al.  Structural properties of solution processed Ge 23 Sb 7 S 70 glass materials , 2012 .

[14]  Juejun Hu,et al.  Development of chipscale chalcogenide glass based infrared chemical sensors , 2011, OPTO.

[15]  T. Wágner,et al.  Selective wet-etching and characterization of chalcogenide thin films in inorganic alkaline solutions , 2007 .

[16]  Juejun Hu,et al.  Cavity-Enhanced IR Absorption in Planar Chalcogenide Glass Microdisk Resonators: Experiment and Analysis , 2009, Journal of Lightwave Technology.

[17]  K. Petkov,et al.  Photoinduced changes in the linear and non-linear optical properties of chalcogenide glasses , 1999 .

[18]  Benjamin J Eggleton,et al.  Chalcogenide photonics: fabrication, devices and applications. Introduction. , 2010, Optics express.

[19]  Jacklyn Novak,et al.  Effect of annealing conditions on the physio-chemical properties of spin-coated As_2Se_3 chalcogenide glass films , 2012 .

[20]  Kathleen Richardson,et al.  Integrated chalcogenide waveguide resonators for mid-IR sensing: leveraging material properties to meet fabrication challenges. , 2010, Optics express.

[21]  Robert W. Eason,et al.  Pulsed laser deposition of Ga‐La‐S chalcogenide glass thin film optical waveguides , 1993 .

[22]  G. Chern,et al.  Spin coated amorphous chalcogenide films: Structural characterization , 1983 .

[23]  T. Wágner,et al.  All-chalcogenide middle infrared dielectric reflector and filter , 2011 .

[24]  Craig B. Arnold,et al.  Structural properties of solution processed Ge23Sb7S70 glass materials , 2012 .

[25]  Kathleen Richardson,et al.  Fabrication and testing of planar chalcogenide waveguide integrated microfluidic sensor. , 2007, Optics express.

[26]  M. Frumar,et al.  Spin-coated As33S67−xSex thin films: the effect of annealing on structure and optical properties , 2006 .

[27]  Christos Markos,et al.  Chalcogenide glass layers in silica photonic crystal fibers. , 2012, Optics express.

[28]  A. McGhie,et al.  Spin coated amorphous chalcogenide films: Thermal properties , 1983 .

[29]  Stephen Kozacik,et al.  Demonstration of high-Q mid-infrared chalcogenide glass-on-silicon resonators. , 2013, Optics letters.

[30]  Martin Richardson,et al.  PROGRESS ON THE FABRICATION OF ON-CHIP, INTEGRATED CHALCOGENIDE GLASS (CHG)-BASED SENSORS , 2010 .