Electrodialysis with notched ion exchange membranes: Experimental investigations and computational fluid dynamics simulations

Abstract Electrodialysis (ED), which equips ion exchange membranes (IEMs) in a direct current field, has widely been employed for desalination and separation of electrolytes. To date, IEMs for ED have commonly been plain, and should be stacked with spacers to provide water flow channels along membrane surface. This study reports a novel notched IEMs, which is a combination of a plain IEM and a spacer. Continuous-mode ED test has been performed to evaluate its desalination performance. Computational fluid dynamics (CFD) simulation of properties of the flowing solution gives an insight into advantages of the unique geometry of membrane surface. Particularly, results of CFD simulations are consistent with experimental investigations and conform that the notched membranes exhibit better performances than traditional plain ones for ED applications.

[1]  H. Isbell,et al.  EFFECT OF pH IN THE MUTAROTATION AND HYDROLYSIS OF GLYCOSYLAMINES , 1950 .

[2]  Chuanhui Huang,et al.  Electrodialysis‐based separation technologies: A critical review , 2008 .

[3]  Satish J. Parulekar,et al.  Optimal current and voltage trajectories for minimum energy consumption in batch electrodialysis , 1998 .

[4]  Jincheng Ding,et al.  Kinetics of esterification of acidified oil with different alcohols by a cation ion-exchange resin/polyethersulfone hybrid catalytic membrane. , 2012, Bioresource technology.

[5]  E. I. Belova,et al.  Intensive current transfer in membrane systems: modelling, mechanisms and application in electrodialysis. , 2010, Advances in colloid and interface science.

[6]  V. I. Zabolotskii,et al.  Electric mass transport through homogeneous and surface-modified heterogeneous ion-exchange membranes at a rotating membrane disk , 2009 .

[7]  K. Kikuchi,et al.  Separation of amino acids by electrodialysis with ion-exchange membranes , 1995 .

[8]  Andrea Achilli,et al.  Standard methodology for evaluating membrane performance in osmotically driven membrane processes , 2013 .

[9]  Gerhart Eigenberger,et al.  Ion-Exchange Membranes in the Chemical Process Industry , 2013 .

[10]  Jaewoo Lee,et al.  Preparation and application of patterned membranes for wastewater treatment. , 2012, Environmental science & technology.

[11]  J. Sanders,et al.  Separation of L‐aspartic acid and L‐glutamic acid mixtures for use in the production of bio‐based chemicals , 2012 .

[12]  O. Louisnard,et al.  Optimized design of an electrochemical filter-press reactor using CFD methods , 2011 .

[13]  Zhen Chen,et al.  Synthesis and properties of side-chain-type ion exchange membrane PEEK-g-StSO3Na for bipolar membranes , 2012 .

[14]  Desmond F. Lawler,et al.  Electrodialysis with spacers: Effects of variation and correlation of boundary layer thickness , 2011 .

[15]  Matthias Wessling,et al.  Towards spacer free electrodialysis , 2009 .

[16]  David F. Fletcher,et al.  A CFD study of unsteady flow in narrow spacer-filled channels for spiral-wound membrane modules , 2002 .

[17]  Herve Morvan,et al.  CFD simulations of flow and concentration polarization in spacer-filled channels for application to water desalination , 2008 .

[18]  P. Pfromm Low Effluent Processing in the Pulp and Paper Industry: Electrodialysis for Continuous Selective Chloride Removal , 1997 .

[19]  Walter Juda,et al.  COHERENT ION-EXCHANGE GELS AND MEMBRANES , 1950 .

[20]  J. S. Lee,et al.  Sulfonated resorcinol-formaldehyde polymer gels synthesized in Nafion ion clusters as nanoscale reactors for a filler of hybrid proton exchange membranes , 2012 .

[21]  Vítor Geraldes,et al.  Limiting current density in the electrodialysis of multi-ionic solutions , 2010 .

[22]  Matthias Wessling,et al.  Membrane with integrated spacer , 2010 .

[23]  B. Belaissaoui,et al.  Bipolar membrane electrodialysis and ion exchange hybridizing for dilute organic acid solutions treatment , 2013 .

[24]  John Hays Iowa's first electrodialysis reversal water treatment plant☆ , 2000 .

[25]  J. Norton,et al.  Separation of Monovalent Cations by Electrodialysis , 1994 .

[26]  Michele Ciofalo,et al.  CFD simulation of channels for direct and reverse electrodialysis , 2012 .