DIELECTRIC CONSTANT AND INDUCED DIPOLE MOMENT OF EDIBLE OILS SUBJECTED TO CONVENTIONAL HEATING

The frequency dependence of dielectric constant, dielectric loss factor and conductivity are studied for five edible oils in the frequency range 100 kHz to 13 MHz at different temperatures using frequency domain spectroscopy. The dielectric constant is found similar for all the samples and in agreement with the previous reports. The dielectric loss is low (<0.01) except for the virgin olive oil with value of 0.05. Dielectric loss peak frequency is at  4 MHz for corn oil and around 5.2 MHz for the others. At this frequency conductivity is of the order of 10 -7 -10 -9 S/cm, and decreases with temperature following the behavior of the dielectric losses. Refractive index, molar and orientation polarization are calculated for all types of oils using novel theory proposed by N. M. Putintsev and D. N. Putintsev [1]. Data show that the orientation polarization contributes to the observed dielectric constant at low temperatures and frequencies.  This indicates that the edible oils are not pure nonpolar dielectrics. Induced dipole moments of oils are calculated for 400 kHz and 10 MHz at 300 K and 318 K. The results are discussed and correlated as a function of temperature and frequency to establish their relationship.

[1]  Z. H. Shah,et al.  Dielectric Properties of Vegetable Oils , 2011 .

[2]  D. Putintsev,et al.  High-frequency dielectric permittivity of water and its components , 2011 .

[3]  F. F. Sousa,et al.  Dielectric Properties of Oleic Acid in Liquid Phase , 2009 .

[4]  A. Vaughan,et al.  Selection of a suitable vegetable oil for high voltage insulation applications , 2009 .

[5]  Suwarno,et al.  Dielectric properties of mixtures between mineral oil and natural ester , 2008, 2008 International Symposium on Electrical Insulating Materials (ISEIM 2008).

[6]  D. Putintsev,et al.  A method for predicting the polarization of substances , 2008 .

[7]  D. Putintsev,et al.  Deformation polarization of substances , 2007 .

[8]  D. Putintsev,et al.  The permittivity of polar dielectrics , 2007 .

[9]  D. Putintsev,et al.  The molar polarization and refraction of substances , 2006 .

[10]  E. Stauffer A review of the analysis of vegetable oil residues from fire debris samples: spontaneous ignition, vegetable oils, and the forensic approach. , 2005, Journal of forensic sciences.

[11]  D. Bhatnagar,et al.  Dielectric study of binary mixtures of edible unsaturated oils , 2005 .

[12]  Ricard Boqué,et al.  Rapid detection of olive–pomace oil adulteration in extra virgin olive oils from the protected denomination of origin “Siurana” using excitation–emission fluorescence spectroscopy and three-way methods of analysis , 2005 .

[13]  S. Aditama,et al.  Dielectric properties of palm oils as liquid insulating materials: effects of fat content , 2005, Proceedings of 2005 International Symposium on Electrical Insulating Materials, 2005. (ISEIM 2005)..

[14]  Frank D. Gunstone,et al.  The Chemistry of Oils and Fats: Sources, Composition, Properties, and Uses , 2004 .

[15]  Jay P. Gore,et al.  Authentication of Olive Oil Adulterated with Vegetable Oils Using Fourier Transform Infrared Spectroscopy , 2002 .

[16]  Francesco Addeo,et al.  1H and 13C NMR of virgin olive oil. An overview , 1997 .

[17]  Ali H. El-Hamdy,et al.  Detection of olive oil adulteration by measuring its authenticity factor using reversed-phase high-performance liquid chromatography , 1995 .

[18]  V. V. Shevlyakov Orientation polarization and dielectric dispersion characteristics of nonpolar liquid solutions , 1986 .

[19]  B. Caldwell,et al.  Dielectric Constant and Effective Dipole Moment of Drying Oils , 1941 .

[20]  J. Velevska,et al.  MEASURING FREQUENCY AND TEMPERATURE-DEPENDENT PERMITTIVITIES OF VEGETABLE OILS , 2011 .

[21]  Emanuele Piuzzi,et al.  On the use of dielectric spectroscopy for quality control of vegetable oils , 2009 .

[22]  R. Cimbala,et al.  DIELECTRIC ANALYSIS OF NATURAL OILS , 2007 .