Benchmarking, insights, and potential for improvement of Fischer–Tropsch-based biomass-to-liquid technology

Biomass is one of the renewable energy sources which can play an important role in reducing dependency on crude oil specifically transportation fuels while maintaining the current infrastructure. This study investigates the potential that biomass could offer in supporting the production of ultra-clean liquid transportation fuels via biomass gasification and Fischer–Tropsch synthesis. Various biomass-to-liquid (BTL) processes may be developed; however, prior to the detailed analysis, it is important to understand the overarching insights of the system and to determine performance benchmarks. The major focus of this study is to develop a process-integration approach to determine the “big-picture” targets and to evaluate the role of certain variables (e.g., biomass source, composition, and processing) on potential liquid fuel yield. This assessment takes into consideration the major challenges facing BTL technology, and identifies areas for potential improvement. Several routes are synthesized and compared.

[1]  Gary C. Young,et al.  Municipal Solid Waste to Energy Conversion Processes: Economic, Technical, and Renewable Comparisons , 2010 .

[2]  Ben J. Stuart.  Liquid Transportation Fuels from Coal and Biomass: Technological Status, Costs, and Environmental Impacts , 2008 .

[3]  Anthony V. Bridgwater,et al.  Renewable fuels and chemicals by thermal processing of biomass , 2003 .

[4]  Chunshan Song,et al.  Hydrogen and Syngas Production and Purification Technologies , 2010 .

[5]  Maarten van der Burgt,et al.  Gasification. 2nd. ed. , 2008 .

[6]  E. Steen,et al.  Fischer‐Tropsch Catalysts for the Biomass‐to‐Liquid (BTL)‐Process , 2008 .

[7]  J. Azevedo,et al.  Estimating the higher heating value of biomass fuels from basic analysis data , 2005 .

[8]  Matthew J. De Kam,et al.  Biomass Integrated Gasification Combined Cycle for Heat and Power at Ethanol Plants , 2008 .

[9]  A. Faaij,et al.  Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification , 2002 .

[10]  America's Energy Future Panel on Alternative Liquid Transpor Fuels.  Liquid Transportation Fuels from Coal and Biomass: Technological Status, Costs, and Environmental Impacts , 2010 .

[11]  Prasant Kumar Rout,et al.  Production of first and second generation biofuels: A comprehensive review , 2010 .

[12]  Anoop Singh,et al.  Production of liquid biofuels from renewable resources , 2011 .

[13]  Thore Berntsson,et al.  Hydrogen production from biomass gasification in the oil refining industry – A system analysis , 2012 .

[14]  J. H. Gregor,et al.  Fischer-Tropsch products as liquid fuels or chemicals , 1990 .

[15]  S. Phillips.  Technoeconomic Analysis of a Lignocellulosic Biomass Indirect Gasification Process To Make Ethanol via Mixed Alcohols Synthesis , 2007 .

[16]  Ralph P. Overend,et al.  Biomass and renewable fuels , 2001 .

[17]  Toshiaki Hanaoka,et al.  Effect of woody biomass components on air-steam gasification , 2005 .

[18]  L. Lynd,et al.  Beneficial Biofuels—The Food, Energy, and Environment Trilemma , 2009, Science.

[19]  M. Aznar,et al.  Biomass gasification in atmospheric and bubbling fluidized bed: effect of the type of gasifying agent on the product distribution , 1999 .

[20]  M. Dry.  High quality diesel via the Fischer–Tropsch process – a review , 2002 .

[21]  Jan Brandin,et al.  The technical feasibility of biomass gasification for hydrogen production , 2005 .

[22]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[23]  M. El‐Halwagi,et al.  Simulation, integration, and economic analysis of gas-to-liquid processes , 2010 .

[24]  T. A. Milne,et al.  Biomass Gasifier "Tars": Their Nature, Formation, and Conversion , 1998 .

[25]  M. Holtzapple,et al.  Carboxylate Platform: The MixAlco Process Part 1: Comparison of Three Biomass Conversion Platforms , 2009, Applied biochemistry and biotechnology.

[26]  André Faaij,et al.  Production of FT transportation fuels from biomass; technical options, process analysis and optimisation, and development potential , 2004 .

[27]  Gerrit Brem,et al.  Review of Catalysts for Tar Elimination in Biomass Gasification Processes , 2004 .

[28]  André Faaij,et al.  Outlook for advanced biofuels , 2006 .

[29]  Nimir O. Elbashir,et al.  Advancement of Fischer‐Tropsch synthesis via utilization of supercritical fluid reaction media , 2009 .

[30]  A. Demirbas,et al.  Progress and recent trends in biodiesel fuels , 2009 .

[31]  H. Hofbauer,et al.  Biomass steam gasification--an extensive parametric modeling study. , 2001, Bioresource technology.

[32]  Nimir O. Elbashir,et al.  A Method to Design an Advanced Gas-to-Liquid Technology Reactor for Fischer-Tropsch Synthesis , 2010 .

[33]  Ke Liu,et al.  Comprar Hydrogen and Syngas Production and Purification Technologies | Warren Strober | 9780471719755 | Wiley , 2010 .

[34]  Maria Sudiro,et al.  Production of synthetic gasoline and diesel fuel by alternative processes using natural gas and coal: Process simulation and optimization , 2009 .

[35]  Peter McKendry,et al.  Energy production from biomass (Part 2): Conversion technologies. , 2002, Bioresource technology.

[36]  Mahmoud M. El-Halwagi,et al.  An Approach to the Design of Advanced Fischer-Tropsch Reactor for Operation in Near-Critical and Supercritical Phase Media , 2009 .

[37]  J. Jechura,et al.  Biomass to Hydrogen Production Detailed Design and Economics Utilizing the Battelle Columbus Laboratory Indirectly-Heated Gasifier , 2005 .