Recent progresses on solution-processed silver nanowire based transparent conducting electrodes for organic solar cells

Abstract Organic photovoltaics (OPVs) are considered as a future alternative for conventional silicon based solar cells, owing to their low cost, ease of production and high-throughput. The transparent conducting electrode (TCE) is a fundamental component of OPVs. Traditionally, indium tin oxide (ITO) has been mainly utilized as a TCE in OPV applications due to its relatively high transparency and low sheet resistance. However, increasing demand for the optoelectronic devices has led to large fluctuations in ITO prices in the past decade and ITO is known to account more than 50% of the total cost of OPV devices. Thus, it is believed that development of solution-processable alternative materials is of great importance in reducing the cost of OPVs. Numerous materials, including silver nanowires, carbon nanotubes, graphene and conducting polymers, have been offered as replacements for ITO. This article reviews recent progress on fabrication of TCE via solution based coating techniques of silver nanowires (Ag NWs). In addition, performance of the Ag NWs based TCE in OPVs is summarized. Finally, we explore the future outlook for Ag NWs based TCE at the end of the review.

[1]  Zhongai Hu,et al.  Large-scale synthesis of defect-free silver nanowires by electrodeless deposition , 2007 .

[2]  Derya Baran,et al.  Fully solution-processing route toward highly transparent polymer solar cells. , 2014, ACS applied materials & interfaces.

[3]  P. Charbonneau,et al.  The effect of nanowire length and diameter on the properties of transparent, conducting nanowire films. , 2012, Nanoscale.

[4]  Ning Han,et al.  Low-temperature growth of highly crystalline β-Ga2O3 nanowires by solid-source chemical vapor deposition , 2014, Nanoscale Research Letters.

[5]  Yi Cui,et al.  Solution-processed metal nanowire mesh transparent electrodes. , 2008, Nano letters.

[6]  Peter Peumans,et al.  Smooth Nanowire/Polymer Composite Transparent Electrodes , 2011, Advanced materials.

[7]  Younan Xia,et al.  Crystalline Silver Nanowires by Soft Solution Processing , 2002 .

[8]  S. H. Park,et al.  Template-free and filamentary growth of silver nanowires: application to anisotropic conductive transparent flexible electrodes. , 2013, Nanoscale.

[9]  K. Stevenson,et al.  Photoinitiated growth of sub-7 nm silver nanowires within a chemically active organic nanotubular template. , 2010, Journal of the American Chemical Society.

[10]  K. Suganuma,et al.  Fabrication of silver nanowire transparent electrodes at room temperature , 2011 .

[11]  Jian-Rong Zhang,et al.  Synthesis of silver nanowires by a sonoelectrochemical method , 2002 .

[12]  Hong Liang,et al.  Photochemical formation of electrically conductive silver nanowires on polymer scaffolds. , 2010, Journal of colloid and interface science.

[13]  Seok‐In Na,et al.  Cost-effective ITO-free organic solar cells with silver nanowire–PEDOT:PSS composite electrodes via a one-step spray deposition method , 2014 .

[14]  F. Bozon-Verduraz,et al.  One-step construction of silver nanowires in hexagonal mesoporous silica using the polyol process , 2003 .

[15]  Zhibin Yu,et al.  Silver Nanowire‐Polymer Composite Electrodes for Efficient Polymer Solar Cells , 2011, Advanced materials.

[16]  Younan Xia,et al.  Large‐Scale Synthesis of Uniform Silver Nanowires Through a Soft, Self‐Seeding, Polyol Process , 2002 .

[17]  Karl Leo,et al.  Combined alternative electrodes for semi-transparent and ITO-free small molecule organic solar cells , 2012 .

[18]  Bernardino Ruiz,et al.  Rapid synthesis of ultra-long silver nanowires for tailor-made transparent conductive electrodes: proof of concept in organic solar cells , 2015, Nanotechnology.

[19]  S. Ko,et al.  Highly Stretchable and Highly Conductive Metal Electrode by Very Long Metal Nanowire Percolation Network , 2012, Advanced materials.

[20]  D. Bellet,et al.  Flexible transparent conductive materials based on silver nanowire networks: a review , 2013, Nanotechnology.

[21]  Y. Yamauchi,et al.  Soft-Chemical Approach of Noble Metal Nanowires Templated from Mesoporous Silica (SBA-15) through Vapor Infiltration of a Reducing Agent , 2010 .

[22]  K. Suganuma,et al.  Transparent electrodes fabricated via the self-assembly of silver nanowires using a bubble template. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[23]  Shiyao Wu,et al.  Seed-mediated synthesis of silver nanostructures and polymer/silver nanocables by UV irradiation , 2004 .

[24]  Jun Wang,et al.  Facile synthesis of very-long silver nanowires for transparent electrodes , 2014 .

[25]  Şahin Coşkun,et al.  Polyol Synthesis of Silver Nanowires: An Extensive Parametric Study , 2011 .

[26]  Zhifeng Ren,et al.  Flexible transparent conductors based on metal nanowire networks , 2015 .

[27]  B. Wiley,et al.  Solution-processed flexible polymer solar cells with silver nanowire electrodes. , 2011, ACS applied materials & interfaces.

[28]  M. Nath,et al.  Metal nanowires and intercalated metal layers in single-walled carbon nanotube bundles , 2000 .

[29]  Gil Markovich,et al.  Transparent metal nanowire thin films prepared in mesostructured templates. , 2009, Nano letters.

[30]  Frederik C. Krebs,et al.  Economic assessment of solar electricity production from organic-based photovoltaic modules in a domestic environment , 2011 .

[31]  Yiying Wu,et al.  Templated Synthesis of Highly Ordered Mesostructured Nanowires and Nanowire Arrays , 2004 .

[32]  Hongyuan Chen,et al.  Photochemical synthesis of Au and Ag nanowires on a porous aluminum oxide template , 2003 .

[33]  T. Soga Fundamentals of Solar Cell , 2006 .

[34]  Yi Cui,et al.  Scalable coating and properties of transparent, flexible, silver nanowire electrodes. , 2010, ACS nano.

[35]  Franklin Kim,et al.  Graphene Oxide: Surface Activity and Two‐Dimensional Assembly , 2010, Advanced materials.

[36]  L. Qi,et al.  Formation of Silver Nanowires in Aqueous Solutions of a Double-Hydrophilic Block Copolymer , 2001 .

[37]  Y. Kim,et al.  Transparent, dip-coated silver nanowire electrodes for small molecule organic solar cells , 2013 .

[38]  Wilfried Lövenich,et al.  Solution-deposited PEDOT for transparent conductive applications , 2011 .

[39]  S. Banerjee,et al.  Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils , 2009, Science.

[40]  Eunkyoung Kim,et al.  Fabrication of silver nanowire transparent electrodes using electrohydrodynamic spray deposition for flexible organic solar cells , 2013 .

[41]  S. Ko,et al.  Very long Ag nanowire synthesis and its application in a highly transparent, conductive and flexible metal electrode touch panel. , 2012, Nanoscale.

[42]  S. Ko,et al.  Large-Scale Synthesis and Characterization of Very Long Silver Nanowires via Successive Multistep Growth , 2012 .

[43]  Han‐Ki Kim,et al.  Mechanical integrity of flexible Ag nanowire network electrodes coated on colorless PI substrates for flexible organic solar cells , 2012 .

[44]  D. Bradley,et al.  Efficient Organic Solar Cells with Solution‐Processed Silver Nanowire Electrodes , 2011, Advanced materials.

[45]  Wei Lin,et al.  Silver Nanowires: From Scalable Synthesis to Recyclable Foldable Electronics , 2011, Advanced materials.

[46]  G. Markovich,et al.  Formation of gold-silver nanowires in thin surfactant solution films. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[47]  Xin-xin Zhang,et al.  Synthesis of confined Ag nanowires within mesoporous silica via double solvent technique and their catalytic properties. , 2011, Journal of Colloid and Interface Science.

[48]  Tahmina Akter,et al.  Reversibly stretchable transparent conductive coatings of spray-deposited silver nanowires. , 2012, ACS applied materials & interfaces.

[49]  Younan Xia,et al.  Uniform Silver Nanowires Synthesis by Reducing AgNO3 with Ethylene Glycol in the Presence of Seeds and Poly(Vinyl Pyrrolidone) , 2002 .

[50]  D. H. Fatmehsari,et al.  Effect of AgNO3 addition rate on aspect ratio of CuCl2–mediated synthesized silver nanowires using response surface methodology , 2014 .

[51]  Hee‐Tae Jung,et al.  Recent advances in hybrids of carbon nanotube network films and nanomaterials for their potential applications as transparent conducting films. , 2011, Nanoscale.

[52]  S. Han,et al.  Electrostatic spray deposition of highly transparent silver nanowire electrode on flexible substrate. , 2013, ACS applied materials & interfaces.

[53]  Bo Li,et al.  Synthesis and optical properties of silver nanowire arrays embedded in anodic alumina membrane , 2004 .

[54]  Younan Xia,et al.  Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence , 2003 .

[55]  S. Behrens,et al.  Silver Nanoparticle and Nanowire Formation by Microtubule Templates , 2004 .

[56]  Sujie Chen,et al.  Annealing-Free Solution-Processed Silver Nanowire-Polymer Composite Transparent Electrodes and Flexible Device Applications , 2015, IEEE Transactions on Nanotechnology.

[57]  Yu-Lee Hsueh,et al.  The concentration effect of capping agent for synthesis of silver nanowire by using the polyol method , 2014 .

[58]  K. Vijayamohanan,et al.  Synthesis of silver nanowires inside mesoporous MCM-41 host , 2004 .

[59]  Han‐Ki Kim,et al.  Brush painting of transparent PEDOT/Ag nanowire/PEDOT multilayer electrodes for flexible organic solar cells , 2013 .

[60]  Seok‐In Na,et al.  Effect of sheet resistance of Ag-nanowire-based electrodes on cell-performances of ITO-free organic solar cells , 2013 .

[61]  M. Fuhrer,et al.  Extraordinary Mobility in Semiconducting Carbon Nanotubes , 2004 .

[62]  R. Lennox,et al.  Polymer Templated Synthesis of AgCN and Ag Nanowires , 2009 .

[63]  Han‐Ki Kim,et al.  Simple brush-painting of flexible and transparent Ag nanowire network electrodes as an alternative ITO anode for cost-efficient flexible organic solar cells , 2012 .

[64]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.

[65]  Michael Krueger,et al.  Sequence-Specific Molecular Lithography on Single DNA Molecules , 2002, Science.

[66]  M. Layani,et al.  Transparent conductors composed of nanomaterials. , 2014, Nanoscale.

[67]  Hua Zhang,et al.  Organic photovoltaic devices using highly flexible reduced graphene oxide films as transparent electrodes. , 2010, ACS nano.

[68]  F. Krebs,et al.  Flexible ITO‐free polymer solar cells , 2013 .

[69]  Huanting Wang,et al.  Nanowire Arrays Electrodeposited from Liquid Crystalline Phases , 2002 .

[70]  Y. Qian,et al.  Oleate vesicle template route to silver nanowires , 2001 .

[71]  Lanlan Liu,et al.  Green synthesis of silver nanowires via ultraviolet irradiation catalyzed by phosphomolybdic acid and their antibacterial properties , 2013 .

[72]  Yi Cui,et al.  Metal nanogrids, nanowires, and nanofibers for transparent electrodes , 2011 .

[73]  C. Niu Carbon nanotube transparent conducting films , 2011 .

[74]  R. Kaner,et al.  Solution-processed transparent electrodes , 2011 .

[75]  Yugang Sun,et al.  Silver nanowires--unique templates for functional nanostructures. , 2010, Nanoscale.

[76]  M. Mazur Electrochemically prepared silver nanoflakes and nanowires , 2004 .

[77]  Liangbing Hu,et al.  Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures , 2011, Advanced materials.

[78]  Kwang S. Kim,et al.  Large-scale pattern growth of graphene films for stretchable transparent electrodes , 2009, Nature.

[79]  Jin Young Kim,et al.  Highly controllable transparent and conducting thin films using layer-by-layer assembly of oppositely charged reduced graphene oxides , 2011 .

[80]  Tong Zhang,et al.  Investigation on the role of the molecular weight of polyvinyl pyrrolidone in the shape control of high-yield silver nanospheres and nanowires , 2014, Nanoscale Research Letters.

[81]  Dekker,et al.  High-field electrical transport in single-wall carbon nanotubes , 1999, Physical review letters.

[82]  Chang Su Kim,et al.  Highly Efficient and Bendable Organic Solar Cells with Solution‐Processed Silver Nanowire Electrodes , 2013 .

[83]  Christoph J. Brabec,et al.  Solution‐Processed Metallic Nanowire Electrodes as Indium Tin Oxide Replacement for Thin‐Film Solar Cells , 2011 .

[84]  A. Ferrari,et al.  Graphene Photonics and Optoelectroncs , 2010, CLEO 2012.

[85]  K. Shinozaki,et al.  High-intensity pulse light sintering of silver nanowire transparent films on polymer substrates: the effect of the thermal properties of substrates on the performance of silver films. , 2013, Nanoscale.

[86]  Han‐Ki Kim,et al.  Brush-painted flexible organic solar cells using highly transparent and flexible Ag nanowire network electrodes , 2014 .

[87]  Younan Xia,et al.  Rapid synthesis of silver nanowires through a CuCl- or CuCl2-mediated polyol process , 2008 .

[88]  Shijun Jia,et al.  Polymer–Fullerene Bulk‐Heterojunction Solar Cells , 2009, Advanced materials.

[89]  Chongwu Zhou,et al.  Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics. , 2010, ACS nano.

[90]  C. J. M. Emmott,et al.  Environmental and economic assessment of ITO-free electrodes for organic solar cells , 2012 .