Ultrathin-Walled Bi2 S3 Nanoroll/MXene Composite toward High Capacity and Fast Lithium Storage.

It is extremely important to develop a high energy density power source with rapid charge-discharge rate to meet people's growing needs. Hence, the development of advanced electrode materials is the top priority. Herein, a simple yet elaborate vacuum-assisted room-temperature phase transfer method is reported to transform MXene nanosheets from water into organic solution. Subsequently, an in-situ growth strategy is employed to deposit ultrathin-walled bismuth sulfide (Bi2 S3 ) nanorolls on MXene surface to prepare Bi2 S3 /MXene composite as an efficient and high-performance anode material for lithium-ion batteries. Attributed to the unique nanoroll-like structure and the strong synergistic effect, the Bi2 S3 /MXene-10 composite can deliver the high discharge capacities of 849 and 541 mAh g-1 at 0.1 and 5 A g-1 , respectively. The Bi2 S3 /MXene-10 electrode can deliver a high specific capacity of 541 mAh g-1 even after 600 cycles at a large current density of 1 A g-1 , proving the superb cycling stability of the Bi2 S3 /MXene-10 composite. Additionally, the simple vacuum-assisted room-temperature phase transfer strategy can enlighten researchers to expand the potential application of MXene. Furthermore, the formation mechanism of Bi2 S3 nanorolls is also proposed, which may open a new avenue to design and fabricate other nanoroll-like structures.

[1]  C. Shu,et al.  Suppressing dendrite growth and side reactions on Zn metal anode via guiding interfacial anion/cation/H2O distribution by artificial multi-functional interface layer , 2021, Energy Storage Materials.

[2]  R. A. Soomro,et al.  Advances in the Synthesis of 2D MXenes , 2021, Advanced materials.

[3]  Quan-hong Yang,et al.  Reassembly of MXene Hydrogels into Flexible Films towards Compact and Ultrafast Supercapacitors , 2021, Advanced Functional Materials.

[4]  K. Ye,et al.  Versatile Interfacial Self-Assembly of Ti3C2Tx MXene Based Composites with Enhanced Kinetics for Superior Lithium and Sodium Storage. , 2021, ACS nano.

[5]  Qiang Zhang,et al.  High‐Capacity and Kinetically Accelerated Lithium Storage in MoO3 Enabled by Oxygen Vacancies and Heterostructure , 2021, Advanced Energy Materials.

[6]  Seung‐Taek Myung,et al.  Promising sodium storage of bismuthinite by conversion chemistry , 2021, Energy Storage Materials.

[7]  Zhongti Sun,et al.  Boron doping and high curvature in Bi nanorolls for promoting photoelectrochemical nitrogen fixation , 2021 .

[8]  Y. Gogotsi,et al.  Mechanisms of the Planar Growth of Lithium Metal Enabled by the 2D Lattice Confinement from a Ti3C2Tx MXene Intermediate Layer , 2021, Advanced Functional Materials.

[9]  Se Hyun Kim,et al.  Engineering Aggregation‐Resistant MXene Nanosheets As Highly Conductive and Stable Inks for All‐Printed Electronics , 2021, Advanced Functional Materials.

[10]  Qianqian Wang,et al.  3D Porous Oxidation‐Resistant MXene/Graphene Architectures Induced by In Situ Zinc Template toward High‐Performance Supercapacitors , 2021, Advanced Functional Materials.

[11]  Wei Guo,et al.  Energy Accumulation Enabling Fast Synthesis of Intercalated Graphite and Operando Decoupling for Lithium Storage , 2021, Advanced Functional Materials.

[12]  Yuzheng Guo,et al.  Blowing Iron Chalcogenides into Two-Dimensional Flaky Hybrids with Superior Cyclability and Rate Capability for Potassium-Ion Batteries. , 2021, ACS nano.

[13]  Qiang Zhang,et al.  Review on Li Deposition in Working Batteries: From Nucleation to Early Growth , 2021, Advanced materials.

[14]  Qiao Ni,et al.  Reversible Insertion of I–Cl Interhalogen in a Graphite Cathode for Aqueous Dual-Ion Batteries , 2021 .

[15]  Z. Wen,et al.  Rational construction of heterostructured core-shell Bi2S3@Co9S8 complex hollow particles toward high-performance Li- and Na-ion storage , 2020, Energy Storage Materials.

[16]  Tongtao Li,et al.  Molecular Ligand-Mediated Assembly of Multicomponent Nanosheet Superlattices for Compact Capacitive Energy Storage. , 2020, Angewandte Chemie.

[17]  Qiang Sun,et al.  Biomimetic Sn4P3 Anchored on Carbon Nanotubes as an Anode for High-Performance Sodium-Ion Batteries. , 2020, ACS nano.

[18]  X. Yang,et al.  Electrostatic self-assembly of MXene and edge-rich CoAl layered double hydroxide on molecular-scale with superhigh volumetric performances , 2020, Journal of Energy Chemistry.

[19]  Tongchao Liu,et al.  Durian-Inspired Design of Bismuth-Antimony Alloy Arrays for Robust Sodium Storage. , 2020, ACS nano.

[20]  Xiaodong Chen,et al.  Mechanically Reinforced Localized Structure Design to Stabilize Solid-Electrolyte Interface of the Composited Electrode of Si Nanoparticles and TiO2 Nanotubes. , 2020, Small.

[21]  Jinkui Feng,et al.  Hierarchical Microcables Constructed by CoP@C⊂Carbon Framework Intertwined with Carbon Nanotubes for Efficient Lithium Storage , 2020, Advanced Energy Materials.

[22]  Xianfu Wang,et al.  Heterostructured NiS2/ZnIn2S4 Realizing Toroid-Like Li2O2 Deposition in Lithium-Oxygen Batteries with Low-Donor-Number Solvents. , 2020, ACS nano.

[23]  Shenglin Xiong,et al.  Metal-Semiconductor Phase Twinned Hierarchical MoS2 Nanowires with Expanded Interlayers for Sodium-Ion Batteries with Ultralong Cycle Life. , 2019, Small.

[24]  K. Kang,et al.  Nanoscale Phenomena in Lithium-Ion Batteries. , 2019, Chemical reviews.

[25]  Yuqing Liu,et al.  Yolk–Shell Structured FeP@C Nanoboxes as Advanced Anode Materials for Rechargeable Lithium‐/Potassium‐Ion Batteries , 2019, Advanced Functional Materials.

[26]  Yizhe Liu,et al.  Hierarchical “nanoroll” like MoS2/Ti3C2Tx hybrid with high electrocatalytic hydrogen evolution activity , 2019, Applied Catalysis B: Environmental.

[27]  Meilin Liu,et al.  Mechanistic Origin of the High Performance of Yolk@Shell Bi2S3@N-Doped Carbon Nanowire Electrodes. , 2018, ACS nano.

[28]  Yun Wang,et al.  Coordination Polymer Derived NiS@g-C3N4 Composite Photocatalyst for Sulfur Vacancy and Photothermal Effect Synergistic Enhanced H2 Production , 2018, ACS Sustainable Chemistry & Engineering.

[29]  Jingyu Sun,et al.  Nanostructured Bi2S3 encapsulated within three-dimensional N-doped graphene as active and flexible anodes for sodium-ion batteries , 2018, Nano Research.

[30]  Qiang Zhang,et al.  Nanostructured Metal Oxides and Sulfides for Lithium–Sulfur Batteries , 2017, Advanced materials.

[31]  Gang Chen,et al.  Carbon coated flower like Bi2S3 grown on nickel foam as binder-free electrodes for electrochemical hydrogen and Li-ion storage capacities , 2015 .

[32]  Chenglin Yan,et al.  Strongly Coupled Bi2S3@CNT Hybrids for Robust Lithium Storage , 2014 .

[33]  J. Xie,et al.  Reduced graphene oxide-induced recrystallization of NiS nanorods to nanosheets and the improved Na-storage properties. , 2014, Inorganic chemistry.

[34]  Xinggui Zhou,et al.  Bi2S3 nanostructures: A new photocatalyst , 2010 .

[35]  Jin-Song Hu,et al.  Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices , 2008 .

[36]  Benxia Li,et al.  Vanadium pentoxide nanobelts and nanorolls: from controllable synthesis to investigation of their electrochemical properties and photocatalytic activities , 2006, Nanotechnology.

[37]  S. Tolbert,et al.  The Relationship Between Nanoscale Structure and Electrochemical Properties of Vanadium Oxide Nanorolls , 2004 .