Hyper-Spectral Acquisition on Historically Accurate Reconstructions of Red Organic Lakes

Our cultural heritage is constituted by irreplaceable artworks that must be known and preserved. Their study and documentation should be in principle carried out using non-invasive approaches. The technological advances in spectroscopic imaging acquisition devices made it possible to apply this methodology to such purpose. In this context, the present paper discusses a particularly challenging task within the conservation field, which is the identification of red lake pigments in artworks, applying Vis-NIR hyper-spectral imaging spectroscopy. The latter was used to characterize and discriminate between historically accurate paint reconstructions of brazilwood (vegetal) and cochineal (animal) lake pigments. The same paints were also analyzed with Fiber Optic Reflectance Spectroscopy to validate the data obtained with the imaging method. The requirements for a successful identification of these pigments are addressed, and future research is suggested in order to increase the usefulness of the technique’s application.

[1]  Cristiana Lofrumento,et al.  SERS detection of red organic dyes in Ag-agar gel , 2013 .

[2]  Ioanna Kakoulli,et al.  Multispectral and hyperspectral imaging technologies in conservation: current research and potential applications , 2006 .

[3]  Paola Ricciardi,et al.  Use of Imaging Spectroscopy and in situ Analytical Methods for the Characterization of the Materials and Techniques of 15th Century Illuminated Manuscripts , 2013 .

[4]  Vincent van Gogh,et al.  Van Gogh's studio practice , 2013 .

[5]  Marco Leona,et al.  Nondestructive identification of natural and synthetic organic colorants in works of art by surface enhanced Raman scattering. , 2011, Analytical chemistry.

[6]  Mathieu Thoury,et al.  Visible and Infrared Imaging Spectroscopy of Picasso's Harlequin Musician: Mapping and Identification of Artist Materials in Situ , 2010, Applied spectroscopy.

[7]  Marcello Picollo,et al.  A Spectroscopic Study of Brazilwood Paints in Medieval Books of Hours , 2014, Applied spectroscopy.

[8]  Vanessa Otero Matias Historically accurate reconstructions and characterisation of chrome yellow pigments , 2010 .

[9]  M. Melo,et al.  History of Natural Dyes in the Ancient Mediterranean World , 2009 .

[10]  M. Bacci,et al.  UV-VIS-NIR REFLECTANCE SPECTROSCOPY OF RED LAKES IN PAINTINGS , 2008 .

[11]  Marcello Picollo,et al.  Open issues in hyperspectral imaging for diagnostics on paintings: when high-spectral and spatial resolution turns into data redundancy , 2011, Optical Metrology.

[12]  Tatiana Mendes Vitorino,et al.  A closer look at brazilwood and its lake pigments , 2012 .

[13]  Mathieu Thoury,et al.  Use of visible and infrared reflectance and luminescence imaging spectroscopy to study illuminated manuscripts: pigment identification and visualization of underdrawings , 2009, Optical Metrology.

[14]  Costanza Miliani,et al.  Colouring materials of pre-Columbian codices: non-invasive in situ spectroscopic analysis of the Codex Cospi , 2012 .