Toward a description of contact line motion at higher capillary numbers

The surface of a liquid near a moving contact line is highly curved owing to diverging viscous forces. Thus, microscopic physics must be invoked at the contact line and matched to the hydrodynamic solution farther away. This matching has already been done for a variety of models, but always assuming the limit of vanishing speed. This excludes phenomena of the greatest current interest, in particular the stability of contact lines. Here we extend perturbation theory to arbitrary order and compute finite speed corrections to existing results. We also investigate the impact of different contact line models on the large-scale shape of the interface.

[1]  Kinetic Slip Condition, van der Waals Forces, and Dynamic Contact Angle , 2000, physics/0005065.

[2]  R. G. Cox The dynamics of the spreading of liquids on a solid surface. Part 1. Viscous flow , 1986, Journal of Fluid Mechanics.

[3]  L. M. Hocking THE SPREADING OF A THIN DROP BY GRAVITY AND CAPILLARITY , 1983 .

[4]  O. Voinov Hydrodynamics of wetting , 1976 .

[5]  P. Gennes Deposition of Langmuir-Blodgett layers , 1986 .

[6]  R. G. Cox The dynamics of the spreading of liquids on a solid surface. Part 2. Surfactants , 1986, Journal of Fluid Mechanics.

[7]  Françoise Brochard-Wyart,et al.  Dynamics of partial wetting , 1992 .

[8]  S. Orszag,et al.  Advanced Mathematical Methods For Scientists And Engineers , 1979 .

[9]  L. M. Hocking Rival contact-angle models and the spreading of drops , 1992, Journal of Fluid Mechanics.

[10]  L. Scriven,et al.  Hydrodynamic Model of Steady Movement of a Solid / Liquid / Fluid Contact Line , 1971 .

[11]  L. M. Hocking Meniscus draw-up and draining , 2001, European Journal of Applied Mathematics.

[12]  T. Blake,et al.  Kinetics of displacement , 1969 .

[13]  J. Eggers Hydrodynamic theory of forced dewetting. , 2003, Physical review letters.

[14]  Characteristic lengths at moving contact lines for a perfectly wetting fluid: the influence of speed on the dynamic contact angle , 2002, Journal of Fluid Mechanics.

[15]  Brian Duffy,et al.  A third-order differential equation arising in thin-film flows and relevant to Tanner's Law , 1997 .

[16]  P. Gennes,et al.  Dynamics of wetting: local contact angles , 1990, Journal of Fluid Mechanics.