论文信息 - Efficient panchromatic sensitization of nanocrystalline TiO2 films by a black dye based on a trithiocyanato-ruthenium complex

Efficient panchromatic sensitization of nanocrystalline TiO2 films by a black dye based on a trithiocyanato-ruthenium complex

A black trithiocyanato–ruthenium(II) terpyridyl complex where the terpyridyl ligand is substituted by three carboxyl groups in 4,4′,4″-positions achieves very efficient panchromatic sensitization of nanocrystalline TiO 2 solar cells over the whole visible range extending into the near-IR region up to 920 nm.

Michael Grätzel | Peter Pechy | M. Grätzel | P. Péchy | Md. K. Nazeeruddin

[1] Page E. Sebring,et al. Synthesis and Catalytic Activity of Transition Metal Polymers Containing Alkane‐Linked Bipyridine and Terpyridine Ligands , 1995 .

[2] Y. Wada,et al. Importance of binding states between photosensitizing molecules and the TiO2 surface for efficiency in a dye-sensitized solar cell , 1995 .

[3] Mohammad Khaja Nazeeruddin,et al. Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes , 1993 .

[4] V. Balzani,et al. Complexes of the Ruthenium(II)-2,2':6',2''-terpyridine Family. Effect of Electron-Accepting and -Donating Substituents on the Photophysical and Electrochemical Properties , 1995 .