Scaling laws for the reduction of threading dislocation densities in homogeneous buffer layers

In the heteroepitaxial growth of films with large misfit with the underlying substrate (linear mismatch strains in excess of 1%–2%) the generation of misfit dislocations and threading dislocations (TDs) is ubiquitous for thicknesses well in excess of the equilibrium critical thickness. Experimental data suggest that the TD density in relaxed homogeneous buffer layers can be divided into three regimes: (i) an entanglement region near the film/substrate interface corresponding to TD densities of ∼1010–1012 cm−2; (ii) a falloff in TD density that is inversely proportional to the film thickness h, applicable to densities in the range ∼107–109 cm−2; and (iii) saturation or weak decay of the TD density with further increase in film thickness. Typical saturation densities are on the order of ∼106–107 cm−2. In this article, we show that the TD reduction may be described in terms of effective lateral motion of TDs with increasing film thickness. An analytic model is developed that successfully predicts both the 1/...

[1]  L. B. Freund,et al.  A criterion for arrest of a threading dislocation in a strained epitaxial layer due to an interface misfit dislocation in its path , 1990 .

[2]  Eugene A. Fitzgerald,et al.  Nucleation mechanisms and the elimination of misfit dislocations at mismatched interfaces by reduction in growth area , 1989 .

[3]  N. Hayafuji,et al.  Effectiveness of AlGaAs/GaAs superlattices in reducing dislocation density in GaAs on Si , 1988 .

[4]  J. Tsao,et al.  Materials Fundamentals of Molecular Beam Epitaxy , 1992 .

[5]  M. Yamaguchi,et al.  Film thickness dependence of dislocation density reduction in GaAs‐on‐Si substrates , 1990 .

[6]  L. Freund,et al.  On the Nucleation of Dislocations at a Crystal Surface , 1993 .

[7]  T. Nishimura,et al.  Effect of Employing Positions of Thermal Cyclic Annealing and Strained-Layer Superlattice on Defect Reduction in GaAs-on-Si , 1990 .

[8]  L. Freund Dislocation Mechanisms of Relaxation in Strained Epitaxial Films , 1992 .

[9]  V. Vladimirov,et al.  The Theory of Dynamic Annihilation of Dislocations , 1986 .

[10]  Jens Lothe John Price Hirth,et al.  Theory of Dislocations , 1968 .

[11]  J. Hirth,et al.  Theory of Dislocations (2nd ed.) , 1983 .

[12]  H. Okamoto,et al.  Dislocation Reduction in GaAs on Si by Thermal Cycles and InGaAs/GaAs Strained-Layer Superlattices , 1987 .

[13]  J. Willis,et al.  A line-integral representation for the stresses due to an arbitrary dislocation in an isotropic half-space , 1994 .

[14]  B. G. Yacobi,et al.  Dislocation density reduction through annihilation in lattice-mismatched semiconductors grown by molecular-beam epitaxy , 1988 .