Whither the statistical theory of mass spectra

[1]  William H. Miller Dynamics of Molecular Collisions , 1976 .

[2]  J. Beauchamp,et al.  Efficient multiphoton dissociation of CF3I+ in the metastable X̃ 2E1/2 excited state using cw infrared laser radiation , 1981 .

[3]  R. Levine,et al.  On the separation of time scales in the exploration of phase space of an isolated molecule , 1990 .

[4]  W. Miller,et al.  Eigenstate‐resolved unimolecular reaction dynamics: Ergodic character of S0 formaldehyde at the dissociation threshold , 1990 .

[5]  H. W. Schranz,et al.  Comparisons of statistical and nonstatistical behavior for bond fission reactions in 1,2‐difluoroethane, disilane, and the 2‐chloroethyl radical , 1991 .

[6]  M. Child,et al.  Local and normal stretching vibrational states of H2O , 1981 .

[7]  J. Lorquet Basic questions in mass spectrometry , 1981 .

[8]  H. Krause,et al.  Multiphoton mass spectrometry of clusters: Dissociation pathways and energetics of heterogeneous van der Waals cluster ions , 1991 .

[9]  S. Hammerum Distonic radical cations in gaseous and condensed phase , 1988 .

[10]  C. Lifshitz,et al.  Some Observations Concerning the Positive Ion Decomposition of C2F6 and C3F8 in the Mass Spectrometer1 , 1965 .

[11]  William F. Polik,et al.  Dissociation rates for individual eigenstates of S0 formaldehyde: Fluctuations and barrier height , 1986 .

[12]  S. Klippenstein,et al.  The fragmentation pattern of 1,4-dioxane ion , 1993 .

[13]  P. Burgers,et al.  Fragmentation rate constants and appearance energies for reactions having a large kinetic shift and the energy partitioning in their metastable decomposition , 1984 .

[14]  W. Kieffer Specialist Periodical Reports , 1975 .

[15]  M. Hubin-franskin,et al.  Intramolecular dynamics by photoelectron spectroscopy. I. Application to N+2, HBr+, and HCN+ , 1982 .

[16]  T. Morton Gas phase analogues of solvolysis reactions , 1982 .

[17]  R. Locht,et al.  The appearance of C2H+3 ions from C2H3F by non-resonant photoionization. A translational energy surprisal analysis , 1993 .

[18]  W. Habenicht,et al.  Memory effects in molecular fragmentation induced by site-specific core excitation using a reflection time-of-flight mass spectrometer , 1991 .

[19]  F. Rowland,et al.  Non-RRKM decomposition in a chemical activation system: thermal atomic fluorine plus tetraallyl tin , 1982 .

[20]  J. Toennies,et al.  Time-of-flight measurements of high-overtone mode-selective vibrational excitation of methane, tetrafluoromethane, and sulfur hexafluoride in collisions with proton, deuterium(1+), and lithium(1+) ions at energies between 4 and 10 eV , 1982 .

[21]  S. Rice,et al.  Unimolecular fragmentation rate theory revisited: An improved classical theory , 1992 .

[22]  F F Crim,et al.  State- and Bond-Selected Unimolecular Reactions , 1990, Science.

[23]  Eugene P. Wigner,et al.  Calculation of the Rate of Elementary Association Reactions , 1937 .

[24]  T. Baer The Dissociation Dynamics of Energy‐Selected Ions , 1986 .

[25]  E. Heller Photofragmentation of symmetric triatomic molecules: Time dependent picture , 1978 .

[26]  D. C. Tardy,et al.  Theory of Unimolecular Reactions , 1973 .

[27]  J. M. Farrar,et al.  A low energy crossed beam study of the reactions of C+ with CH4 , 1985 .

[28]  G. Voth,et al.  Vibrational energy redistribution across a heavy atom , 1989 .

[29]  R. Marcus Statistical Theory of Unimolecular Reactions and Intramolecular Dynamics , 1983 .

[30]  E. Heller,et al.  Quantum Ergodicity and Spectral Chaos , 1984 .

[31]  C. Lifshitz Intramolecular energy redistribution in polyatomic ions , 1983 .

[32]  R. Marcus,et al.  RRKM and non-RRKM behavior in chemical activation and related studies , 1984 .

[33]  A. Narita,et al.  Chaotic behavior of a classical coupled morse system around the escape energy region , 1983 .

[34]  J. Lorquet The electronic structure of ionized molecules , 1966 .

[35]  E. Thiele Comparison of the Classical Theories of Unimolecular Reactions , 1962 .

[36]  S. Rice,et al.  A quantum ergodic theory approach to unimolecular fragmentation , 1975 .

[37]  G. Herzberg,et al.  Infrared and Raman spectra of polyatomic molecules , 1946 .

[38]  Donald G. Truhlar,et al.  Criterion of minimum state density in the transition state theory of bimolecular reactions , 1979 .

[39]  V. Pavlov-Verevkin,et al.  Intramolecular vibrational energy relaxation seen as expansion in phase space. I. Some experimental results for H2O+(X̃ 2B1), C2H+4(X̃ 2B3), and HCN+(B̃ 2∑+) , 1990 .

[40]  P. Longevialle Ion–neutral complexes in the unimolecular reactivity of organic cations in the gas phase , 1992 .

[41]  J. Futrell,et al.  Ion–molecule reaction mechanisms: Thermal energy gas phase reactions of 12C+ and 13C+ ions with CH4, C2H4, C2H6, C3H6, C3H8, and CD3CH2CD3 , 1976 .

[42]  N. Coggeshall Ionization of n‐Paraffin Molecules , 1959 .

[43]  J. L. Kinsey,et al.  State‐specific rates of H2CO(S0)→H2+CO at energies near the top of barrier: A violation of RRKM theory? , 1985 .

[44]  R. Tolman,et al.  The Principles of Statistical Mechanics. By R. C. Tolman. Pp. xix, 661. 40s. 1938. International series of monographs on physics. (Oxford) , 1939, The Mathematical Gazette.

[45]  H. W. Schranz,et al.  Intramolecular energy transfer and mode‐specific effects in unimolecular reactions of disilane , 1991 .

[46]  F. Remacle,et al.  Quantum effects in competitive unimolecular reactions , 1991 .

[47]  J. Hynes,et al.  Dissociation of remote bonds by overtone excitation: a model study of heavy-atom blocking , 1989 .

[48]  William F. Polik,et al.  Stark level‐crossing spectroscopy of S0 formaldehyde eigenstates at the dissociation threshold , 1990 .

[49]  R. Bombach,et al.  The fragmentation of formaldehyde molecular cations: energetics of the dissociation X2CO+(Ã2B1)→CO+(2Σ+)+X2(1Σg+) (X = H,D) , 1980 .

[50]  R. Arakawa,et al.  Time-dependent mass spectra and breakdown graphs. 6. Slow unimolecular dissociation of bromobenzene ions at near threshold energies , 1985 .

[51]  Eugene P. Wigner,et al.  The transition state method , 1938 .

[52]  T. Morton The reorientation criterion and positive ion-neutral complexes , 1992 .

[53]  B. C. Garrett,et al.  Current status of transition-state theory , 1983 .

[54]  R. D. Levine,et al.  INFORMATION THEORY APPROACH TO MOLECULAR REACTION DYNAMICS , 1978 .

[55]  R. D. Levine,et al.  Kinetics of Unimolecular Breakdown. I. The Formal Solution , 1966 .

[56]  R. Levine,et al.  On the unimolecular dissociation of large molecules , 1989 .

[57]  D. McAdoo,et al.  The effect of ion size on rate of dissociation: RRKM calculations on model large polypeptide ions , 1993, Journal of the American Society for Mass Spectrometry.

[58]  K. Honma,et al.  A tpepico study of dissociative photoionization of C2H2D2 isomers , 1989 .

[59]  Frances Dunkle Coffin Production of Atoms by a Glow Discharge in Dry Hydrogen , 1959 .

[60]  W. Miller,et al.  A transition state theory‐based statistical distribution of unimolecular decay rates with application to unimolecular decomposition of formaldehyde , 1990 .

[61]  William H. Green,et al.  Transition States and Rate Constants for Unimolecular Reactions , 1992 .

[62]  D. F. Kelley,et al.  An RRKM approach to vibrational predissociation of van der Waals clusters , 1986 .

[63]  A. Schmelzer,et al.  A photoelectron—photoion coincidence study of vinylfluoride , 1979 .

[64]  B. Bederson,et al.  Atom—Molecule Collision Theory: A Guide for the Experimentalist , 1980 .

[65]  H. W. Schranz,et al.  Statistical and nonstatistical effects in bond fission reactions of SiH2 and Si2H6 , 1991 .

[66]  J. Lorquet The electronic structure of ionized molecules: II. Alkanes , 1965 .

[67]  C. Lifshitz,et al.  Kinetic energy release distributions (KERDs) for the dissociation of metastable enol ions , 1983 .

[68]  Michael J. Davis,et al.  Bottlenecks to unimolecular reactions and an alternative form for classical RRKM theory , 1986 .

[69]  D. McAdoo Ion‐neutral complexes in unimolecular decompositions , 1988 .

[70]  R. Frey,et al.  Unimolecular dissociations and internal conversions of methyl halide ions , 1976 .

[71]  C. Lecomte,et al.  Unimolecular reaction paths of electronically excited species. III. Production of CH+3 ions from CH3OH+ as an example of isolated state dissociation , 1982 .

[72]  E. Heller The semiclassical way to molecular spectroscopy , 1981 .

[73]  R. Levine,et al.  The sequential exploration of phase space in selectively excited polyatomic molecules , 1993 .

[74]  C. Lifshitz,et al.  Time-dependent mass spectra and breakdown graphs. 7. Time-resolved photoionization mass spectrometry of iodobenzene. The heat of formation of phenyl cation , 1986 .

[75]  N. Heinrich,et al.  Competing reactions of the acetone cation radical: RRKM−QET calculations on an ab initio potential energy surface , 1988 .

[76]  J. Dannacher The study of ionic fragmentation by photoelectron‐photoion coincidence spectroscopy , 1984 .

[77]  J. Weiner,et al.  Dynamics of unimolecular dissociation of sodium cluster ions , 1989 .

[78]  E. Heller Quantum corrections to classical photodissociation models , 1978 .

[79]  William H. Miller,et al.  Beyond transition-state theory: A rigorous quantum theory of chemical reaction rates , 1993 .

[80]  T. Matsushita,et al.  Mass dependence of the Kolmogorov—Arnold—Moser stability and low-order resonances in the kinetically coupled two-degree-of-freedom morse system , 1983 .

[81]  G. G. Hall,et al.  The healing effect in the dissociation of the paraffin hydrocarbons , 1970 .

[82]  E. Teller,et al.  The Role of Free Radicals in Elementary Organic Reactions , 1938 .

[83]  A. Peres,et al.  Motion of wave packets in regular and chaotic systems , 1983 .

[84]  R. Levine,et al.  Mode Selective Chemistry , 1991 .

[85]  S. Bauer,et al.  Intramolecular conversions over low barriers. VII. The aziridine inversion—Intrinsically non‐RRKM , 1986 .

[86]  X. Chapuisat,et al.  A weak-mode representation of floppy molecules: III. Theoretical assignment of spectroscopic states , 1994 .

[87]  R. Bombach,et al.  Fragmentation of formaldehyde molecular cations , 1981 .

[88]  R. Levine Quantal Fluctuations in Unimolecular Rate Constants , 1988 .

[89]  F. Remacle,et al.  Extracting laws of decay in the femto–picosecond range from autocorrelation functions , 1989 .

[90]  R. Levine,et al.  Transition State Theory and Beyond — A Constrained Phase Space Approach , 1982 .

[91]  J. Futrell,et al.  Collisional activation and dissociation of polyatomic ions , 1993 .

[92]  R. Bombach,et al.  The fragmentation of formaldehyde molecular cations: the lifetime of CD2O+(Ã 2B1) , 1981 .

[93]  C. Lifshitz Time-resolved appearance energies, breakdown graphs, and mass spectra: The elusive “kinetic shift”† , 1982 .

[94]  W. Hase Variational unimolecular rate theory , 1983 .

[95]  Michael J. Davis,et al.  Unimolecular reactions and phase space bottlenecks , 1986 .

[96]  C. Lifshitz,et al.  Time‐dependent mass spectra and breakdown graphs: 15—toluene‐d8 , 1992 .

[97]  H. Taylor,et al.  Mode localization in highly excited vibrational states: Fundamentals of structure in overtone and multiphoton spectra , 1984 .

[98]  E. Jaynes Information Theory and Statistical Mechanics , 1957 .

[99]  S. Rice,et al.  Unimolecular reactions revisited , 1990 .

[100]  R. Levine,et al.  The reactivity–selectivity principle: The derivation of bounds and a computational study , 1980 .

[101]  Sean C. Smith,et al.  Theory of Unimolecular and Recombination Reactions , 1990 .

[102]  T. Takeuchi,et al.  Nonadiabatic unimolecular reactions. 4. Isolated state decay in the fragmentation of the formaldehyde cation , 1990 .

[103]  Heller Quantum localization and the rate of exploration of phase space. , 1987, Physical review. A, General physics.

[104]  B. C. Garrett,et al.  Variational Transition State Theory , 1980 .

[105]  K. Honma,et al.  State selected ion–molecule reactions by the TESICO technique. XIII. Vibrational state dependence of the cross sections in the reaction C2D+2(ν2)+H2 , 1984 .

[106]  Raphael D. Levine,et al.  A Measure of the Phase Space Accessed by a Probe in Quantum-Algebraic Systems , 1987 .

[107]  A. Pross The Reactivity—Selectivity Principle and its Mechanistic Applications , 1977 .

[108]  E. Teller,et al.  Corrections to Paper ``The Role of Free Radicals in Elementary Organic Reactions'' , 1939 .

[109]  R. Levine,et al.  Role of Energy in Reactive Molecular Scattering: An in Form a Tion-Theoretic Approach , 1976 .

[110]  F. Kaufman,et al.  The thermal rate constant of elementary reactions: Does specificity of energy disposal require a concomitant lowering of its magnitude?☆ , 1978 .

[111]  H. Krause,et al.  Multiphoton ionization and dissociation of mixed van der Waals clusters in a linear reflectron time-of-flight mass spectrometer , 1990 .

[112]  J. R. Peterson,et al.  Infrared photodissociation of polyatomic ions , 1980 .