Liquid Immiscibility and Evolution of Basaltic Magma: Reply to S. A. Morse, A. R. McBirney and A. R. Philpotts

INTRODUCTION We are pleased that our experimental study (Veksler et al., 2007) received critical comments from three of the best experts on silicate liquid immiscibility and gabbroic intrusions. Our disagreements are less important than the shared belief that studies of layered intrusions need a new impulse, and existing ideas a thorough revision. This discussion is a good opportunity to emphasize and clarify the key points, better formulate current problems and disagreements, and touch upon some topics that were mentioned only briefly or not at all in our original publication. We continue experimental work on silicate liquid immiscibility (Veksler et al., 2009), and will mention here some new results that are relevant for the discussion. Like Roedder 30 years ago (Roedder & Weiblen, 1970; Roedder, 1978), we stumbled upon liquid immiscibility by serendipity. Our interest in magma unmixing was sparked by unsought and unexpected melt inclusions in apatite from the Skaergaard intrusion (Jakobsen et al., 2005). These inclusions were impossible to miss.We realized that, surprisingly, some important features of Skaergaard rocks had been overlooked or dismissed by numerous researchers before us. As we continued our work and established close collaboration with experts on the Skaergaard intrusion in Denmark and the UK (see the Acknowledgements) our experimental study became a part of a broader petrographic and geochemical project.This discussion primarily deals with experimental evidence and therefore we will mention petrographic and geochemical observations only briefly. However, those other types of evidence are certainly important and hopefully they will be covered soon by our colleagues in their upcoming publications. We do realize that the idea of early immiscibility in the Skaergaard intrusion is at odds with broadly accepted views, and admit that the concerns expressed by our opponents are fair and well based. We started to consider the immiscibility hypothesis seriously only as the last resort, because everything else (including the compositional convection model advocated by Professor Morse) failed to explain some conflicting facts about the Skaergaard intrusion that were briefly outlined in our original paper and are further discussed below. In this paper, we would also like to point out some possible tests and promising directions for future research.

[1]  I. Veksler Extreme iron enrichment and liquid immiscibility in mafic intrusions: Experimental evidence revisited , 2009 .

[2]  D. Dingwell,et al.  Liquid unmixing kinetics and the extent of immiscibility in the system K2O-CaO-FeO-Al2O3-SiO2 , 2008 .

[3]  M. Toplis,et al.  Plagioclase in the Skaergaard intrusion. Part 1: Core and rim compositions in the layered series , 2008 .

[4]  D. Dingwell,et al.  Liquid Immiscibility and the Evolution of Basaltic Magma , 2007 .

[5]  P. Thy,et al.  Experimental constraints on the Skaergaard liquid line of descent , 2006 .

[6]  I. Veksler,et al.  Immiscible iron- and silica-rich melts in basalt petrogenesis documented in the Skaergaard intrusion , 2005 .

[7]  T. Nielsen The Shape and Volume of the Skaergaard Intrusion, Greenland: Implications for Mass Balance and Bulk Composition , 2004 .

[8]  L. Dickson,et al.  The formation of plagioclase chains during convective transfer in basaltic magma , 2000, Nature.

[9]  B. Reynard,et al.  Temperature and time-dependent changes of structure in phosphorus containing aluminosilicate liquids and glasses: in situ Raman spectroscopy at high temperature , 2000 .

[10]  A. McBirney The Skaergaard Layered Series. Part VI. Excluded Trace Elements , 1998 .

[11]  M. Toplis,et al.  An Experimental Study of the Influence of Oxygen Fugacity on Fe-Ti Oxide Stability, Phase Relations, and Mineral—Melt Equilibria in Ferro-Basaltic Systems , 1995 .

[12]  R. Larsen,et al.  Origin and Evolution of Gabbroic Pegmatites in the Skaergaard Intrusion, East Greenland , 1994 .

[13]  T. Grove Corrections to expressions for calculating mineral components in “Origin of calc-alkaline series lavas at medicine lake volcano by fractionation, assimilation and mixing” and “Experimental petrology of normal MORB near the kane fracture zone: 22°-25°N, mid-atlantic ridge” , 1993 .

[14]  T. Nielsen,et al.  A discussion of Hunter and Sparks (Contrib Mineral Petrol 95:451–461) , 1990 .

[15]  A. McBirney,et al.  The differentiation of the Skaergaard Intrusion , 1990 .

[16]  A. McBirney,et al.  The Skaergaard Layered Series: I. Structure and Average Compositions , 1989 .

[17]  J. Longhi,et al.  A Reconnaisance Study of Phase Boundaries in Low-Alkali Basaltic Liquids , 1988 .

[18]  R. Sparks,et al.  The differentiation of the Skaergaard intrusion , 1987 .

[19]  H. Naslund Petrology of the Upper Border Series of the Skaergaard Intrusion , 1984 .

[20]  A. Philpotts,et al.  Effect of magma oxidation state on the extent of silicate liquid immiscibility in a tholeiitic basalt , 1983 .

[21]  M. Rutherford,et al.  Plagiogranites as late-stage immiscible liquids in ophiolite and mid-ocean ridge suites - An experimental study , 1979 .

[22]  A. Philpotts Silicate Liquid Immiscibility in Tholeiitic Basalts , 1979 .

[23]  E. Roedder Silicate liquid immiscibility in magmas and in the system K2O-FeO-AI2O3-SiO2: an example of serendipity , 1978 .

[24]  W. Vogel Phase separation in glass , 1977 .

[25]  A. K. V. Groos,et al.  Liquid immiscibility in K2O-FeO-Al2O3-SiO2 (reply) , 1977, Nature.

[26]  E. Roedder Liquid immiscibility in K2O-FeO-Al2O3-SiO2 , 1977, Nature.

[27]  I. Freestone,et al.  Liquid immiscibility in K2O-FeO-Al2O3-SiO2 (reply) , 1977, Nature.

[28]  A. K. V. Groos,et al.  Liquid immiscibility in K2O–FeO–Al2O3–SiO2 , 1976, Nature.

[29]  A. McBirney,et al.  Differentiation of the Skaergaard Intrusion , 1975, Nature.

[30]  O. Moller Proceedings of the Apollo 11 lunar science conference: LEVINSON, A.A. ed. (1970): 3 Vols. set, 5.420 pp., figs., tables, illustr. Oxford: Pergamon Press. £ 15.00; US$ 40.00; DM 148,-. , 1972 .

[31]  E. Roedder,et al.  Lunar petrology of silicate melt inclusions, Apollo 11 rocks , 1970 .

[32]  G. M. Brown,et al.  Layered Igneous Rocks , 1967 .

[33]  I. Carmichael The Petrology of Thingmuli, a Tertiary Volcano in Eastern Iceland , 1964 .

[34]  G. Kennedy Equilibrium between volatiles and iron oxides in igneous rocks , 1948 .