High‐temperature infrared and dielectric properties of large sapphire crystal for seeker dome application

In this paper, large-sized (∅230 mm × 210 mm, 27.5 kg) sapphire was successfully grown by SAPMAC (sapphire growth technique with micro-pulling and shoulder-expanding at cooled center) method; and hemisphere dome (140 mm diameter, 5 mm thickness) was fabricated from as-grown boule. Also, its high temperature infrared transmission (2∼7 µm, 20–800°C) and microwave dielectric properties (8–16.5 GHz, 30–1300°C) were investigated. The experimental results show that sapphire crystal exhibits high infrared transmittance (3 μm, 80–86%), essentially negligible dielectric loss (4.9×10-5–3.7×10-4), but fairly high dielectric constants (e=9.4–12.5) in the temperature range of 30–1300°C. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

[1]  M. Thomas Optical properties of IR materials , 1991 .

[2]  Songhe Meng,et al.  Temperature field design, process analysis and control of SAPMAC method for the growth of large size sapphire crystals , 2007 .

[3]  James C. Kirsch,et al.  Tri-mode seeker dome considerations , 2005, SPIE Defense + Commercial Sensing.

[4]  M. Zhang,et al.  Investigation on Large-Sized Sapphire Crystalline Perfection by X-Ray Double-Crystal Diffraction Method , 2007 .

[5]  D. Gillespie,et al.  Transmittance of Optical Materials at High Temperatures in the 1-μ to 12-μ Range , 1965 .

[6]  Daniel C. Harris,et al.  Infrared window and dome materials , 1992 .

[7]  S. P. Lin,et al.  The effect of annealing, precipitation-strengthening, and compressive coating processes on sapphire strength , 2006 .

[8]  Joel Askinazi Large-aperture broadband sapphire windows for common aperture, target acquisition, tracking, and surveillance systems , 1997, Defense, Security, and Sensing.

[9]  J. Savage Preparation and properties of hard crystalline materials for optical applications — a review , 1991 .

[10]  Michael E. Thomas,et al.  Windows and domes: past, present, and future , 2003, SPIE Defense + Commercial Sensing.

[11]  B. Bendow,et al.  Multiphonon absorption in highly transparent semiconducting crystals , 1977 .

[12]  G. Russell,et al.  Coupled Aeroheating/Ablation Analysis for Missile Configurations , 2002 .

[14]  I. Kityk,et al.  Influence of Non-Stoichiometric Defects on Optical Properties in LiNbO3 , 2001 .

[15]  J. Krupka Developments in techniques to measure dielectric properties of low-loss materials at frequencies of 1–50 GHz , 2003 .

[16]  W. Low,et al.  Paramagnetic Resonance and Optical Absorption Spectra of Cr3+ in MgO , 1957 .

[17]  W. W. Ho Millimeter-Wave Dielectric Properties Of Infrared Window Materials , 1987, Photonics West - Lasers and Applications in Science and Engineering.

[18]  E. E. Havinga,et al.  Temperature Dependence of Dielectric Constants of Cubic Ionic Compounds , 1963 .

[19]  Daniel C. Harris,et al.  Durable 3-5 μm transmitting infrared window materials , 1998 .