Comparison of ozone retrievals from the Pandora spectrometer system and Dobson spectrophotometer in Boulder, Colorado

Abstract. A comparison of retrieved total column ozone (TCO) amounts between the Pandora #34 spectrometer system and the Dobson #061 spectrophotometer from direct-sun observations was performed on the roof of the Boulder, Colorado, NOAA building. This paper, part of an ongoing study, covers a 1-year period starting on 17 December 2013. Both the standard Dobson and Pandora TCO retrievals required a correction, TCOcorr = TCO (1 + C(T)), using a monthly varying effective ozone temperature, TE, derived from a temperature and ozone profile climatology. The correction is used to remove a seasonal difference caused by using a fixed temperature in each retrieval algorithm. The respective corrections C(TE) are CPandora = 0.00333(TE-225) and CDobson = -0.0013(TE-226.7) per degree K. After the applied corrections removed most of the seasonal retrieval dependence on ozone temperature, TCO agreement between the instruments was within 1 % for clear-sky conditions. For clear-sky observations, both co-located instruments tracked the day-to-day variation in total column ozone amounts with a correlation of r2 = 0.97 and an average offset of 1.1 ± 5.8 DU. In addition, the Pandora TCO data showed 0.3 % annual average agreement with satellite overpass data from AURA/OMI (Ozone Monitoring Instrument) and 1 % annual average offset with Suomi-NPP/OMPS (Suomi National Polar-orbiting Partnership, the nadir viewing portion of the Ozone Mapper Profiler Suite).

[1]  Jennifer A. Logan,et al.  Ozone climatological profiles for satellite retrieval algorithms , 2007 .

[2]  G. M. B. Dobson,et al.  Forty years' research on atmospheric ozone at oxford: a history. , 1968, Applied optics.

[3]  J. Brion,et al.  Ozone UV spectroscopy. II. Absorption cross-sections and temperature dependence , 1995 .

[4]  P. Bhartia,et al.  A comparison of 40 years of SBUV measurements of column ozone with data from the Dobson/Brewer network , 2013 .

[5]  R. Cebula,et al.  Solar Irradiance Reference Spectra , 2013 .

[6]  John P. Burrows,et al.  High spectral resolution ozone absorption cross-sections - Part 2: Temperature dependence , 2013 .

[7]  J. Brion,et al.  High-resolution laboratory absorption cross section of O3. Temperature effect , 1993 .

[8]  W. Cleveland,et al.  Locally Weighted Regression: An Approach to Regression Analysis by Local Fitting , 1988 .

[9]  Richard D. McPeters,et al.  Climatology 2011: An MLS and sonde derived ozone climatology for satellite retrieval algorithms , 2012 .

[10]  W. Komhyr,et al.  Dobson spectrophotometer total ozone measurement errors caused by interfering absorbing species such as SO2, NO2, and photochemically produced O3 in polluted air , 1980 .

[11]  Michael E. VanHoosier Solar ultraviolet spectral irradiance data with increased wavelength and irradiance accuracy , 1996, Optics & Photonics.

[12]  R. J. Paur,et al.  The ultraviolet cross-sections of ozone. I. The measurements. II - Results and temperature dependence , 1985 .

[13]  J. Deluisi,et al.  A new Umkehr inversion algorithm , 1992 .

[14]  Jay R. Herman,et al.  Measurements of O3, SO2, NO2 and HCHO column amounts using a Brewer spectrometer , 2005, SPIE Optics + Photonics.

[15]  J. Brion,et al.  Absorption Spectra Measurements for the Ozone Molecule in the 350–830 nm Region , 1998 .

[16]  Pawan K. Bhartia,et al.  A correction for total ozone mapping spectrometer profile shape errors at high latitude , 1997 .

[17]  Glenn E. Shaw,et al.  Genesis of sun photometry , 2007 .

[18]  Maria Tzortziou,et al.  High precision, absolute total column ozone measurements from the Pandora spectrometer system: Comparisons with data from a Brewer double monochromator and Aura OMI , 2012 .

[19]  W. Komhyr,et al.  Effective Bass‐Paur 1985 ozone absorption coefficients for use with Dobson ozone spectrophotometers , 1993 .

[20]  R. Evans,et al.  Evaluation of the use of five laboratory-determined ozone absorption cross sections in Brewer and Dobson retrieval algorithms , 2013 .

[21]  Maria Tzortziou,et al.  NO2 column amounts from ground‐based Pandora and MFDOAS spectrometers using the direct‐sun DOAS technique: Intercomparisons and application to OMI validation , 2009 .

[22]  Oksana A. Tarasova,et al.  WORLD METEOROLOGICAL ORGANIZATION GLOBAL ATMOSPHERE WATCH , 2011 .

[23]  G. Labow,et al.  Bias in Dobson total ozone measurements at high latitudes due to approximations in calculations of ozone absorption coefficients and air mass , 2005 .

[24]  C. Long,et al.  Performance of the Ozone Mapping and Profiler Suite (OMPS) products , 2014 .

[25]  Charles R. Booth,et al.  Version 2 data of the National Science Foundation's Ultraviolet Radiation Monitoring Network: South Pole , 2004 .